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Synthesis and electrochemical properties of a novel poly(ether sulfone) with oligoaniline pendants

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Abstract

A novel poly(ether sulfone) with oligoaniline pendants(PESOP) was prepared by K2CO3-mediated nucleophilic polycondensation and characterized with Fourier-transform infrared spectrometry(FTIR), 1H nuclear magnetic resonance(1H NMR) and gel permeation chromatography(GPC). The cyclic voltammetry(CV) curve of PESOP reveals the reversible electroactivity. In the electrochromism study, PESOP film exhibited good electrochromic properties with a high contrast value, moderate switching time and acceptable coloration efficiency. After running 1000 cycles, the PESOP/indium-tin oxide(ITO) electrochromic device remained unchanged except for the drifting of base line, which certified its good electro-photo stability of the fabricated electrochromic device. Moreover, the polarization technique and electrochemical impedance spectroscopy(EIS) were used to study the anticorrosion performance of PESOP coatings on the cold rolled steel(CRS) in a 5%(mass fraction) NaCl solution. All the results indicate that the obtained PESOP is a competitive candidate as anticorrosion material.

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Authors and Affiliations

  1. State Key Laboratory of Superhard Materials, Jilin University, Changchun, 130012, P. R. China

    Fangfei Li & Jiayu Wang

  2. College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Mingjuan Zhou, Xincai Liu, Ce Wang & Danming Chao

Authors
  1. Fangfei Li
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  2. Jiayu Wang
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  3. Mingjuan Zhou
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  4. Xincai Liu
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  5. Ce Wang
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  6. Danming Chao
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Corresponding author

Correspondence to Danming Chao.

Additional information

Supported by the National Natural Science Foundation of China(No.21104024), the Jilin Province Science and Technology Department Project, China(No.20130522139JH), the Functional Research Funds for the Central Universities, China(No. JCKY-QKJC07) and the Open Project of State Key Laboratory of Superhard Materials(Jilin University), China(No.201403).

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Li, F., Wang, J., Zhou, M. et al. Synthesis and electrochemical properties of a novel poly(ether sulfone) with oligoaniline pendants. Chem. Res. Chin. Univ. 31, 1066–1071 (2015). https://doi.org/10.1007/s40242-015-5149-4

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  • DOI: https://doi.org/10.1007/s40242-015-5149-4

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