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Bifunctional Salen-Cu(II) complex as efficient catalyst for N-arylation of imidazoles and Suzuki-Miyaura coupling reactions

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Abstract

Bifunctional Salen-Cu(II) complex catalyzed cross-coupling reactions of aryl halids with imidazoles or phenylboronic acid reagents have been developed as practical methods for C―N and C―C bond formation. The procedure tolerates aryl halides with various functional groups(such as methoxy, acetyl, nitrile, fluoro and nitro groups) and gives the corresponding coupling products in moderate to high yields. The catalyst remained active after five successive catalytic runs without loss in performance.

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming, 650500, P. R. China

    Yi Wang, Jingyi Gao, Mengdan Zhao & Jiamei Li

Authors
  1. Yi Wang
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  2. Jingyi Gao
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  3. Mengdan Zhao
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  4. Jiamei Li
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Corresponding author

Correspondence to Yi Wang.

Additional information

Supported by the National Natural Science Foundation of China(No.20672054) and the Scientific Research Fund of Yunnan Provincial Department of Education, China(No.22012Z020).

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Wang, Y., Gao, J., Zhao, M. et al. Bifunctional Salen-Cu(II) complex as efficient catalyst for N-arylation of imidazoles and Suzuki-Miyaura coupling reactions. Chem. Res. Chin. Univ. 31, 549–552 (2015). https://doi.org/10.1007/s40242-015-4437-3

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  • DOI: https://doi.org/10.1007/s40242-015-4437-3

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