Skip to main content
Log in

Smoothing of fast assembled layer-by-layer films by adjusting assembly conditions

  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

To prepare layer-by-layer(LbL) multilayers in time-efficient manners by the dipping method is highly appealing. However, the fast LbL assembly produces multilayers with high surface roughness. In our attempt to smooth the surface morphologies of LbL multilayers obtained by fast assembly(5 s dipping), we studied the influence of the assembly conditions on the surface morphologies. The study shows that by properly adjusting the assembly conditions, such as washing duration, water annealing period, and drying with nitrogen flow, LbL multilayers with enhanced surface smoothness could be obtained through fast LbL assembly.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Siqueira J. R. Jr., Molinnus D., Beging S., Schoning M. J., Anal. Chem., 2014, 86, 5370

    Article  CAS  Google Scholar 

  2. Shao M. F., Xu X. Y., Han J. B., Zhao J. W., Shi W. Y., Kong X. G., Wei M., Evans D. J., Duan X., Langmuir, 2011, 27, 8233

    Article  CAS  Google Scholar 

  3. Ma Y., Zhang Y. Y., Wu B. S., Sun W. P., Li Z. G., Sun J. Q., Angew. Chem. Int. Ed., 2011, 28, 6254

    Article  Google Scholar 

  4. Cheng M. J., Shi F., Li J. S., Lin Z. F., Jiang C., Xiao M., Zhang L. Q., Yang W. T., Nishi T., Adv. Mater., 2014, 26, 3009

    Article  CAS  Google Scholar 

  5. Chen X., Sun J., Shen J., Langmuir, 2009, 25, 3316

    Article  CAS  Google Scholar 

  6. Zhou Y., Cheng M. J., Zhu X. Q., Zhang Y. J., An Q., Shi F., ACS Appl. Mater. Interfaces, 2013, 5, 8308

    Article  CAS  Google Scholar 

  7. Zhou Y., Cheng M. J., Zhu X. Q., Zhang Y. J., An Q., Shi F., J. Mater. Chem. A, 2013, 1, 11329

    Article  CAS  Google Scholar 

  8. Cheng M. J., Liu Q., Xian Y. M., Shi F., ACS Appl. Mater. Interfaces, 2014, 6, 7572

    Article  CAS  Google Scholar 

  9. Yu Y. J., Zhou Y., Li Q. S., Yang Y., Shi J. G., Li M. Y., Yao W. G., Wang J. N., Dong W. F., Qi Z. M., Chem. Res. Chinese Universities, 2013, 29(6), 1219

    Article  CAS  Google Scholar 

  10. Wang X. L., Gong C. H., Qu Y., Liu G. C., Zhang J. W., Chem. Res. Chinese Universities, 2014, 30(5), 709

    Article  Google Scholar 

  11. Zhang Y., Chen L., Ju W. W., Xu Y., Chem. Res. Chinese Universities, 2014, 30(2), 194

    Article  CAS  Google Scholar 

  12. Seo J., Lee H., Jeon J., Jang Y., Kim R., Char K., Nam J., Biomacromolecules, 2009, 10, 2254

    Article  CAS  Google Scholar 

  13. Matsuzawa A., Matsusaki M., Akashi M., Langmuir, 2013, 29, 7362

    Article  CAS  Google Scholar 

  14. Sauma M. K., Wang W. F., Han B., Madhavan L., Han L., Lee D., Wells R. G., Langmuir, 2014, 30, 5481

    Article  Google Scholar 

  15. Li Y., Wang X., Sun J. Q., Chem. Soc. Rev., 2012, 41, 5998

    Article  CAS  Google Scholar 

  16. Kiel M., Mitzscherling S., Leitenberger W., Santer S., Tiersch B., Sievers T. K., Möhwald H., Bargheer M., Langmuir, 2010, 26(23), 18499

    Article  CAS  Google Scholar 

  17. Kharlampieva E., Kozlovskaya V., Chan J., Ankner J. F., Tsukruk V. V., Langmuir, 2009, 25(24), 14017

    Article  CAS  Google Scholar 

  18. Izquierdo A., Ono S. S., Voegel J. C., Schaaf P., Decher G., Langmuir, 2005, 21, 7558

    Article  CAS  Google Scholar 

  19. Nogueira G. M., Banerjee D., Cohen R. E., Rubner M. F., Langmuir, 2011, 27, 7860

    Article  CAS  Google Scholar 

  20. Sung C., Hearn K., Reid D. K., Vidyasagar A., Lutkenhaus J. L., Langmuir, 2013, 29, 8907

    Article  CAS  Google Scholar 

  21. Seo J., Lutkenhaus J. L., Kim J., Hammond P. T., Char K., Macromolecules, 2007, 40, 4028

    Article  CAS  Google Scholar 

  22. Mermut O., Barrett C. J., J. Phys. Chem. B, 2003, 107, 2525

    Article  CAS  Google Scholar 

  23. Shiratori S. S., Rubner M. F., Macromolecules, 2000, 33, 4213

    Article  CAS  Google Scholar 

  24. Fu Y., Li S. J., Xu J., Yang M., Zhang J. D., Jiao Y. H., Zhang J. C., Zhang K., Jia Y. G., Langmuir, 2011, 27w(2), 672

    Article  Google Scholar 

  25. Dubas S. T., Schlenoff J. B., Langmuir, 2001, 17, 7725

    Article  CAS  Google Scholar 

  26. McAloney R. A., Dudnik V., Goh M. C., Langmuir, 2003, 19, 3947

    Article  CAS  Google Scholar 

  27. Tedeschi C., Mo1hwald H., Kirstein S., J. Am. Chem. Soc., 2001, 123, 954

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Qi An or Yihe Zhang.

Additional information

Supported by the National Natural Science Foundation of China(No.21303169), the Fundamental Research Funds for the Central Universities, China(No.2652013115), the Beijing Nova Program, China(No.Z141103001814064), the Beijing Specific Project to Foster Elitist, China(No.2013D009015000001), the Open Project of State Key Laboratory of Chemical Resource Engineering, China(No.CRE-2013-C-201), the National High Technology Research and Development Program of China (No.2012AA06A109) and the Special co-Construction Project of Beijing City Education Committee, China.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Duan, Y., An, Q., Zhang, Q. et al. Smoothing of fast assembled layer-by-layer films by adjusting assembly conditions. Chem. Res. Chin. Univ. 31, 674–679 (2015). https://doi.org/10.1007/s40242-015-4414-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-015-4414-x

Keywords

Navigation