Abstract
The influence of temperature on calcareous deposits formed under galvanostatic polarization mode was studied. The deposition was monitored by electrochemical impedance spectrum, and a supplementary loop in Nyquist diagram at high frequency was found to be an indicator of deposits precipitation with sufficient protection at above 20 °C. An exponential increase of protectiveness with temperature was observed, which was quantified by linear polarization resistance technique. Observation by scanning electron microscope and X-ray diffraction analyses demonstrated that the critical temperature of calcium carbonate crystal form transition ranged from 15 to 20 °C. Calcite formed below 15 °C, while aragonite precipitated at above 20 °C.
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This work was financially supported by the National Science and Technology Major Project of China (No. 2011ZX05027-004-06).
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Li, C., Du, M., Qiu, J. et al. Influence of Temperature on the Protectiveness and Morphological Characteristics of Calcareous Deposits Polarized by Galvanostatic Mode. Acta Metall. Sin. (Engl. Lett.) 27, 131–139 (2014). https://doi.org/10.1007/s40195-013-0010-6
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DOI: https://doi.org/10.1007/s40195-013-0010-6