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Assessment of potential groundwater contamination by ground source heat pump operation using solute transport models

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Abstract

Globally, over the past few decades, there has been a rapid increase in the use of ground source heat pump (GSHP) systems for heating and cooling purposes. Although these systems are more energy efficient than conventional air source heat pump systems, their association with potential groundwater contamination risks, e.g., the leakage of heat exchanger fluids like glycol, is a major concern. In this study, HYDRUS software was used to simulate the transportation of fluids from such systems into an aquifer. To better understand the transport environment, a geological survey was conducted and a > 50 m deep observation well was dug close to the GSHP installation site. To determine the physical properties of the soil, core samples were collected and analyzed; to determine the flow rate of the groundwater as well as the hydrological properties of the aquifer, measurements were conducted using a velocimeter that was installed in the borehole of the observation well. A laboratory column containing aquifer soil was used to determine drainage breakthrough curves. The hydrological parameters of the soil and the solute were used for the simulation under a virtual groundwater environment. The flow of groundwater resulted in the dispersion of the contaminant from its source, and its concentration was significantly reduced owing to degradation presumedly by biological activity. Additionally, two methods for the elimination of the contaminant from aquifers (enforced biodegradation and decontamination by pumping) were identified.

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References

  1. Lund, J.W., Boyd, T.L.: Direct utilization of geothermal energy; 2015 worldwide review. Geothermics 60, 66–93 (2016)

    Article  Google Scholar 

  2. You, T., Wu, W., Shi, W., Wang, B., Li, X.: An overview of the problems and solutions of soil thermal imbalance of ground-coupled heat pumps in cold regions. Appl. Energy 177, 515–536 (2016)

    Article  Google Scholar 

  3. EPA: Preliminary data summary: airport deicing operations (revised). Office of Water, Washington (2000). (EPA-821-R-00-016)

    Google Scholar 

  4. Clark, C.R., Marshall, T.C., Merickel, B.S., Sanchez, A., Brownstein, D.G., Hobbs, C.H.: Toxicological assessment of heat transfer fluids proposed for use in solar energy applications. Toxicol. Appl. Pharmacol. 51(3), 529–535 (1979)

    Article  Google Scholar 

  5. US Department of Health and Human Services.: Public Health Service Agency for Toxic Substances and Disease Registry. Toxicological profile for propylene glycol. https://www.atsdr.cdc.gov/ToxProfiles/tp189.pdf (1997). Accessed 3 Oct 2020

  6. Kent, R.A., Andersen, D., Caux, P.Y., Teed, S.: Canadian water quality guidelines for glycols—an ecotoxicological review of glycols and associated aircraft anti-icing and deicing fluids. Environ. Toxicol. 14(5), 481–522 (1999)

    Article  Google Scholar 

  7. Klotzbücher, T., Kappler, A., Straub, K.L., Haderlein, S.B.: Biodegradability and groundwater pollutant potential of organic anti-freeze liquids used in borehole heat exchangers. Geothermics 36(4), 348–361 (2007)

    Article  Google Scholar 

  8. Jaesche, P., Totsche, K.U., Kögel-Knabner, I.: Transport and anaerobic biodegradation of propylene glycol in gravel-rich soil materials. J. Contam. Hydrol. 85(3–4), 271–286 (2006)

    Article  Google Scholar 

  9. Thuyet, D.Q., Saito, H., Saito, T., Moritani, S., Kohgo, Y., Komatsu, T.: Multivariate analysis of trace elements in shallow groundwater in Fuchu in western Tokyo Metropolis. Jpn. Environ. Earth Sci. 75(7), 559 (2016). https://doi.org/10.1007/s12665-015-5170-4

    Article  Google Scholar 

  10. Simunek, J., van Genuchten, M.T., Šejna, M.: The Hydrus software package for simulating the two- and three-dimensional movement of water, heat, and multiple solutes in variably-saturated porous media, technical manual, version 2.0, pp. 1–258 (2012). https://scholar.google.com/scholar_lookup?title=The%20HYDRUS-2D%20Software%20Package&author=J.%20%C5%A0im%C5%AFnek&publication_year=1999

  11. GSI Environmental Inc. https://www.gsi-net.com/en/publications/gsi-chemical-database/single/469-CAS-57556.html. Accessed 3 Oct 2020

  12. Singhal, B.B.S., Gupta, R.P.: Applied hydrogeology of fractured rocks. Springer, Dordrecht (2010)

    Book  Google Scholar 

  13. Seok, J., Komisar, S.J.: Regulatory role of n-propanol in propylene glycol biomethanization under overload. Water Res. 37(7), 1515–1526 (2003)

    Article  Google Scholar 

  14. Schoenberg, T., Veltman, S., Switzenbaum, M.: Kinetics of anaerobic degradation of glycol-based Type I aircraft deicing fluids. Biodegradation 12(1), 59–68 (2001)

    Article  Google Scholar 

  15. French, H.K., Van der Zee, S.E., Leijnse, A.: Transport and degradation of propyleneglycol and potassium acetate in the unsaturated zone. J. Contam. Hydrol. 49(1–2), 23–48 (2001)

    Article  Google Scholar 

  16. Saito, T., Hamamoto, S., Ueki, T., Ohkubo, S., Moldrup, P., Kawamoto, K.K., Komatsu, T.: Temperature change affected groundwater quality in a confined marine aquifer during long-term heating and cooling. Water Res. 94, 120–127 (2016)

    Article  Google Scholar 

  17. Thorne, D., Langevin, C.D., Sukop, M.C.: Addition of simultaneous heat and solute transport and variable fluid viscosity to SEAWAT. Comput. Geosci. 32(10), 1758–1768 (2006)

    Article  Google Scholar 

  18. Khattab, I.S., Bandarkar, F., Khoubnasabjafari, M., Jouyban, A.: Density, viscosity, surface tension, and molar volume of propylene glycol + water mixtures from 293 to 323 K and correlations using the Jouyban–Acree model. Arab. J. Chem. 10(1), S71–S75 (2017)

    Article  Google Scholar 

  19. Abdulagatov, I.M., Azizov, N.D.: Viscosity of aqueous calcium chloride solutions at high temperatures and high pressures. Fluid Phase Equilib. 240(2), 204–219 (2006)

    Article  Google Scholar 

  20. Simunek, J.M., van Genuchten, M.T., Sejna, T., Toride, N., Leij, F.J.: The STANMOD computer software for evaluating solute transport in porous media using analytical solutions of the convection-dispersion equation. US Salinity laboratory. USDA/ARS, Riverside (2003)

    Google Scholar 

  21. Radcliffe, D., Simunek, J.: Soil physics with HYDRUS: modeling and applications, p. 373. CRC Press, Boca Raton (2010)

    Google Scholar 

  22. Bureau of Environment.: Tokyo Metropolitan Government: The condition of groundwater pumping in Tokyo metropolitan in 2016-(Subtitle) the report of investigation on groundwater pumping. In: Japanese, title is translated into English), p. 47, document No. 29064 (2016)

  23. Saito, T., Spadini, L., Saito, H., Martins, J.M.F., Oxarango, L., Takemura, T., Hamamoto, S., Moldrup, P., Kawamoto, K., Komatsu, T.: Characterization and comparison of groundwater quality and redox conditions in the Arakawa Lowland and Musashino Upland, southern Kanto Plain of the Tokyo Metropolitan area. Jpn. Sci. Total Environ. 722, 137783 (2020)

    Article  Google Scholar 

  24. Williams, J.H., Paillet, F.L.: Using flowmeter pulse tests to define hydraulic connections in the subsurface: a fractured shale example. J. Hydrol. 265(1–4), 100–117 (2002). https://doi.org/10.1016/S0022-1694(02)00092-6

    Article  Google Scholar 

  25. Sterling, S.N., Parker, B.L., Cherry, J.A., Williams, J.H., Lane Jr., J.W., Haeni, F.P.: Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone. Groundwater 43(4), 557–573 (2005). https://doi.org/10.1111/j.1745-6584.2005.0087.x

    Article  Google Scholar 

  26. Le Borgne, T.L., Bour, O., Paillet, F.L., Caudal, J.-P.: Assessment of preferential flow path connectivity and hydraulic properties at single-borehole and cross-borehole scales in a fractured aquifer. J. Hydrol. 328(1–2), 347–359 (2006)

    Article  Google Scholar 

  27. Peeter, E.P., Parker, B.L., Cherry, J.A., Greenhouse, J.P.: The potential for compromised interpretations when based on open borehole geophysical data in fractured rock. In: NGWA/US EPA fractured rock conference: State of the science and measuring success in remediation. Geology. (2007). https://clu-in.org/products/siteprof/2007fracrock/004Pehme,%20P.pdf. Accessed 3 Oct 2020

  28. Santi, P.M., Mccray, J.E., Martens, J.L.: Investigating cross-contamination of aquifers. Hydrogeol. J. 14(1–2), 51–68 (2006). https://doi.org/10.1007/s10040-004-0403-8

    Article  Google Scholar 

  29. Chatelier, M., Ruelleu, S., Bour, O., Porel, G., Delay, F.: Combined fluid temperature and flow logging for the characterization of hydraulic structure in a fractured karst aquifer. J. Hydrol. 400(3–4), 377–386 (2011)

    Article  Google Scholar 

  30. Gas Field Commission.: Groundwater aquifer connectivity in Queensland, Australia technical communication. Unconventional Gas Mining Submission 121, Attachments 33, pp. 1–20 (2014)

  31. Akinwumiju, A.S., Olorunfemi, M.O.: Development of a conceptual groundwater model for a complex basement aquifer system: the case of Osun drainage basin in southwestern Nigeria. J. Afr. Earth Sci. 159, 103574 (2019). https://doi.org/10.1016/j.jafrearsci.2019.103574

    Article  Google Scholar 

  32. Hashimoto, I., Deshpande, K.B., Thomas, H.C.: Peclet numbers and retardation factors for ion exchange columns. Ind. Eng. Chem. Fund. 3(3), 213–218 (1964)

    Article  Google Scholar 

  33. van Genuchten, M.T., Wierenga, P.J.: Mass transfer studies in sorbing porous media I. Analytical solutions. SSSAJ 40(4), 473–480 (1976)

    Article  Google Scholar 

  34. Jury, W.A., Horton, R.: Soil physics. Wiley, Hoboken (2004)

    Google Scholar 

  35. Ohkubo, S., Saito, T., Azad, M.A.K., Kawai, H., Suda, W., Kore-eda, S., Hamamoto, S., Saito, H., Takemura, T., Komatsu, T., Ohnishi, J.I.: Microbial community structures in terrestrial subsurface sediments from the Southern Kanto Plain, Japan. Geomicrobiol. J. 37, 1–8 (2020). https://doi.org/10.1080/01490451.2020.1743390

    Article  Google Scholar 

  36. Appelo, C.A.J., Postma, D.: Temperature change affected groundwater quality in a confined marine aquifer during long-term heating and cooling. Geochemistry, groundwater and pollution, 2nd edn. A. A. Balkema Publishers, Rotterdam (2005)

    Google Scholar 

  37. Bielefeldt, A.R., Illangasekare, T., Uttecht, M., LaPlante, R.: Biodegradation of propylene glycol and associated hydrodynamic effects in sand. Water Res. 36(7), 1707–1714 (2002)

    Article  Google Scholar 

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Acknowledgements

This research was supported by grants from Core Research for Evolutionary Science and Technology (CREST) which is funded by the Japan Science and Technology Agency (JST). It was also partially supported by KAKENHI from the Japanese Society for the Promotion of Science (Grant number 18K05895). The authors deeply appreciate Dr. Takeshi Saito for providing guidance and analyzing the chemicals in groundwater and Dr. Ayako Funabiki for supporting the geological survey. The authors also appreciate Dr. Toshiko Komatsu, Dr. Takato Takemura, and Dr. Shoichiro Hamamoto for providing valuable counsel regarding this research project. Finally, the authors also appreciate Mr. Hiromu Muto and Mr. Hirokiyo Minamino for supporting the sampling and analysis of groundwater and soil samples.

Funding

This research was supported by grants from Core Research for Evolutionary Science and Technology (CREST) which is funded by the Japan Science and Technology Agency (JST). It was also partially supported by KAKENHI from the Japanese Society for the Promotion of Science (Grant number 18K05895).

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Correspondence to Shigeoki Moritani.

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Moritani, S., Saito, H., Win, P.W. et al. Assessment of potential groundwater contamination by ground source heat pump operation using solute transport models. Int J Energy Environ Eng 12, 1–10 (2021). https://doi.org/10.1007/s40095-020-00360-2

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