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X-ray-induced hydrothermal process of hydroxyapatite nanostructures

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Abstract

Herein, we report an X-ray-induced hydrothermal process for synthesizing hydroxyapatite (HA) nanostructures at 25 °C and atmospheric pressure. Synchrotron white X-rays were used as light sources. We found that X-rays can facilitate photoinduced hydrothermal processes when irradiated in aqueous solutions containing Ca2+ and HPO42− precursors. At pH 7, a mixture of thin HA nanoplates and nanorods was formed, and as pH increased to 10, nanorods were mainly formed. HA nanostructures have poor crystallinity with high-density grain boundaries and domain size of approximately 55 Å because the reaction occurred at 25 °C. The elemental ratio of Ca and P atoms was estimated to be 64:36, which is close to the bulk values of 62.5% and 37.5%, respectively. We successfully demonstrated the feasibility of coating a porous HA film comprising nanorods onto Ti disks and Au/sapphire substrates using an X-ray-induced hydrothermal process.

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Acknowledgements

This work was supported by research funds from Chosun University (2020).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Chosun University, Gwangju, 61452, Republic of Korea

    Daseul Ham, Su Yeon Cha & Hyon Chol Kang

  2. Pohang Accelerator Laboratory, POSTECH, Pohang, 37673, Republic of Korea

    Daseul Ham & Su Yong Lee

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  1. Daseul Ham
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  2. Su Yeon Cha
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Ham, D., Cha, S.Y., Lee, S.Y. et al. X-ray-induced hydrothermal process of hydroxyapatite nanostructures. J. Korean Phys. Soc. 80, 484–489 (2022). https://doi.org/10.1007/s40042-022-00449-3

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