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Application of response surface method for removal of Cr(VI) from aqueous solutions using foam fractionation process

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Abstract

Discharge of heavy metals into the environment by wastewater from production and application processes is nowadays getting more and more serious due to the rapid development of such processes. Produced water during oil production and wastewater form metal plating and ore dressing are few examples to mention. In this research, removal of chromium ions from aqueous solutions has been studied by foam fractionation process using cetyl trimethyl ammonium bromide as surfactant. Effect of processing time, gas flow rate, initial surfactant concentration, and initial pH on removal efficiency has been investigated. Preliminary screening tests were performed, and initial surfactant concentration and processing time were recognized as the variables with a significant effect on removal efficiency. Response surface methodology based on central composite design as a design of experiment method was employed to design experiments to study the effect of important variables more precisely. Five levels for each significant variable were considered and design of experiment. An accurate correlative model is developed for the estimation of removal efficiency under different operating conditions in foam fractionation process with a maximum relative error of 1.674%. Four sets of validation tests were also conducted, and the results of validation tests were shown to be in accordance with those obtained on tests dictated by design of experiment. Optimum operating conditions were found to be with an initial surfactant concentration of 175 ppm and 45 min of processing time that yielded 97.74% removal of Cr(VI) from a solution of 10 ppm initial concentration.

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References

  • Amooey AA, Ghasemi S, Mirsoleimani-azizi SM, Gholaminezhad Z, Chaichi MJ (2014) Removal of Diazinon from aqueous solution by electrocoagulation process using aluminum electrodes. Korean J Chem Eng 31:1016–1020

    Article  CAS  Google Scholar 

  • Arulmozhi M, Begum KMS, Anantharaman N (2007) Foam separation of copper(II) from aqueous solutions. J Environ Res Dev 2:217–225

    CAS  Google Scholar 

  • Brito F, Ascanio J, Mateo S, Hernández C, Araujo L, Gili P, Martín-Zarza P, Domínguez S, Mederos A (1997) Equilibria of chromate(VI) species in acid medium and ab initio studies of these species. Polyhedron 16:3835–3846

    Article  CAS  Google Scholar 

  • Cheballah K, Sahmoune A, Messaoudi K, Drouiche N, Lounici H (2015) Simultaneous removal of hexavalent chromium and COD from industrial wastewater by bipolar electrocoagulation. Chem Eng Process 96:94–99

    Article  CAS  Google Scholar 

  • Chen H-R, Chen C-C, Reddy AS, Chen C-Y, Li WR, Tseng M-J, Liu H-T, Pan W, Maity JP, Atla SB (2011) Removal of mercury by foam fractionation using surfactin, a biosurfactant. Int J Mol Sci 12:8245–8258

    Article  CAS  Google Scholar 

  • Cheng Q, Wang C, Doudrick K, Chan CK (2015) Hexavalent chromium removal using metal oxide photocatalysts. Appl Catal B 176:740–748

    Article  CAS  Google Scholar 

  • Czitrom V (1999) One-factor-at-a-time versus designed experiments. Am Stat 53:126–131

    Google Scholar 

  • Dekhil A, Hannachi Y, Ghorbel A, Boubaker T (2011) Removal of lead and cadmium ions from aqueous solutions using dried marine green macroalga (Caulerpa racemosa). Int J Environ Res 5:725–732

    CAS  Google Scholar 

  • Gerken BM, Nicolai A, Linke D, Zorn H, Berger RG, Parlar H (2006) Effective enrichment and recovery of laccase C using continuous foam fractionation. Sep Purif Technol 49:291–294

    Article  CAS  Google Scholar 

  • Ghosh R, Sahu A, Pushpavanam S (2019) Removal of trace hexavalent chromium from aqueous solutions by ion foam fractionation. J Hazard Mater 367:589–598

    Article  CAS  Google Scholar 

  • Heidmann I, Calmano W (2008) Removal of Cr(VI) from model wastewaters by electrocoagulation with Fe electrodes. Sep Purif Technol 61:15–21

    Article  CAS  Google Scholar 

  • Jiang C, Wu Z, Li R, Liu Q (2011) Technology of protein separation from whey wastewater by two-stage foam separation. Biochem Eng J 55:43–48

    Article  CAS  Google Scholar 

  • Kinoshita T, Ishigaki Y, Shibata N, Yamaguchi K, Akita S, Kitagawa S, Kondou H, Nii S (2011) Selective recovery of gallium with continuous counter-current foam separation and its application to leaching solution of zinc refinery residues. Sep Purif Technol 78:181–188

    Article  CAS  Google Scholar 

  • Kongsricharoern N, Polprasert C (1996) Chromium removal by a bipolar electro-chemical precipitation process. Water Sci Technol 34:109–116

    Article  CAS  Google Scholar 

  • Lazarova V, Levine B, Sack J, Cirelli G, Jeffrey P, Muntau H, Salgot M, Brissaud F (2001) Role of water reuse for enhancing integrated water management in Europe and Mediterranean countries. Water Sci Technol 43:25–33

    Article  CAS  Google Scholar 

  • Liu Y, Wu Z, Zhao B, Li L, Li R (2013) Enhancing defoaming using the foam breaker with perforated plates for promoting the application of foam fractionation. Sep Purif Technol 120:12–19

    Article  CAS  Google Scholar 

  • Lu K, Zhang X-L, Zhao Y-L, Wu Z-L (2010) Removal of color from textile dyeing wastewater by foam separation. J Hazard Mater 182:928–932

    Article  CAS  Google Scholar 

  • Lu J, Li Y, Zhang S, Sun Y (2015) Removal of trace Cd2+ from aqueous solution by foam fractionation. J Hazard Mater 286:466–473

    Article  CAS  Google Scholar 

  • Mahmoud MR, Lazaridis NK (2015) Simultaneous removal of nickel (II) and chromium (VI) from aqueous solutions and simulated wastewaters by foam separation. Sep Sci Technol 50:1421–1432

    Article  CAS  Google Scholar 

  • Matsuoka K, Miura H, Karima S, Taketaka C, Ouno S, Moroi Y (2018) Removal of alkali metal ions from aqueous solution by foam separation method. J Mol Liq 263:89–95

    Article  CAS  Google Scholar 

  • Mella B, Glanert AC, Gutterres M (2015) Removal of chromium from tanning wastewater and its reuse. Process Saf Environ Prot 95:195–201

    Article  CAS  Google Scholar 

  • Merz J, Burghoff B, Zorn H, Schembecker G (2011) Continuous foam fractionation: performance as a function of operating variables. Sep Purif Technol 82:10–18

    Article  CAS  Google Scholar 

  • Miller JN, Miller JC (2005) Statistics and chemometrics for analytical chemistry. Pearson Education, London

    Google Scholar 

  • Mirsoleimani-azizi SM, Amooey AA, Ghasemi S, Salkhordeh-panbechouleh S (2015) Modeling the removal of endosulfan from aqueous solution by electrocoagulation process using artificial neural network (ANN). Ind Eng Chem Res 54:9844–9849

    Article  CAS  Google Scholar 

  • Mirsoleimani-azizi SM, Setoodeh P, Zeinali S, Rahimpour MR (2018) Tetracycline antibiotic removal from aqueous solutions by MOF-5: adsorption isotherm, kinetic and thermodynamic studies. J Environ Chem Eng 6:6118–6130

    Article  CAS  Google Scholar 

  • Mishra S, Bharagava RN (2016) Toxic and genotoxic effects of hexavalent chromium in environment and its bioremediation strategies. J Environ Sci Health Part C 34:1–32

    Article  CAS  Google Scholar 

  • Montgomery DC (2017) Design and analysis of experiments. Wiley, Hoboken

    Google Scholar 

  • Moussavi M, Javidnejad M (2007) Separation of Hg(II) by foam fractionation in the acidic range: effect of complexation. J Hazard Mater 144:187–193

    Article  CAS  Google Scholar 

  • Pagana A, Sklari S, Kikkinides E, Zaspalis V (2008) Microporous ceramic membrane technology for the removal of arsenic and chromium ions from contaminated water. Microporous Mesoporous Mater 110:150–156

    Article  CAS  Google Scholar 

  • Peykar S, Anvaripour B, Motavassel M, Jadidi N (2013) Mercury removal from wastewater by batch foam fractionation. Int Res J Appl Basic Sci 4:3198–3203

    CAS  Google Scholar 

  • Qu Y-H, Zeng G-M, Huang J-H, Xu K, Fang Y-Y, Li X, Liu H-L (2008) Recovery of surfactant SDS and Cd2+ from permeate in MEUF using a continuous foam fractionator. J Hazard Mater 155:32–38

    Article  CAS  Google Scholar 

  • Qu Y, Zhang X, Xu J, Zhang W, Guo Y (2014) Removal of hexavalent chromium from wastewater using magnetotactic bacteria. Sep Purif Technol 136:10–17

    Article  CAS  Google Scholar 

  • Rengaraj S, Yeon K-H, Moon S-H (2001) Removal of chromium from water and wastewater by ion exchange resins. J Hazard Mater 87:273–287

    Article  CAS  Google Scholar 

  • Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Asghari A (2014) Optimization of the ultrasonic assisted removal of methylene blue by gold nanoparticles loaded on activated carbon using experimental design methodology. Ultrason Sonochem 21:242–252

    Article  CAS  Google Scholar 

  • Sereshti H, Farahani MV, Baghdadi M (2016) Trace determination of chromium (VI) in environmental water samples using innovative thermally reduced graphene (TRG) modified SiO2 adsorbent for solid phase extraction and UV–vis spectrophotometry. Talanta 146:662–669

    Article  CAS  Google Scholar 

  • Shadmehr J, Mirsoleimani-azizi S, Zeinali S, Setoodeh P (2018) Electrocoagulation process for propiconazole elimination from wastewater: experimental design for correlative modeling and optimization. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-018-1891-8

    Article  Google Scholar 

  • Shah M, Pathak K (2010) Development and statistical optimization of solid lipid nanoparticles of simvastatin by using 23 full-factorial design. AAPS PharmSciTech 11:489–496

    Article  CAS  Google Scholar 

  • Stevenson P (2007) Hydrodynamic theory of rising foam. Miner Eng 20:282–289

    Article  CAS  Google Scholar 

  • Tadakamalla K, Marathe K (2011) Hydrodynamic study and optimization strategy for the surfactant recovery from aqueous solutions. Desalination 266:98–107

    Article  CAS  Google Scholar 

  • Venkateswaran P, Palanivelu K (2004) Solvent extraction of hexavalent chromium with tetrabutyl ammonium bromide from aqueous solution. Sep Purif Technol 40:279–284

    Article  CAS  Google Scholar 

  • Yan J, Wu Z, Zhao Y, Jiang C (2011) Separation of tea saponin by two-stage foam fractionation. Sep Purif Technol 80:300–305

    Article  CAS  Google Scholar 

  • Yang Q-W, Wu Z-L, Zhao Y-L, Wang Y, Li R (2011) Enhancing foam drainage using foam fractionation column with spiral internal for separation of sodium dodecyl sulfate. J Hazard Mater 192:1900–1904

    Article  CAS  Google Scholar 

  • Yuan X, Meng Y, Zeng G, Fang Y, Shi J (2008) Evaluation of tea-derived biosurfactant on removing heavy metal ions from dilute wastewater by ion flotation. Colloids Surf A 317:256–261

    Article  CAS  Google Scholar 

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Acknowledgements

The authors wish to thank all who assisted in conducting this work.

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Authors and Affiliations

  1. Department of Chemical Engineering, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz, 71345, Iran

    S. Piri, N. Mehranbod, M. Moussavi & S. M. Mirsoleimani-azizi

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  1. S. Piri
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  2. N. Mehranbod
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  3. M. Moussavi
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  4. S. M. Mirsoleimani-azizi
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Correspondence to N. Mehranbod.

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Editorial responsibility: J Aravind.

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Piri, S., Mehranbod, N., Moussavi, M. et al. Application of response surface method for removal of Cr(VI) from aqueous solutions using foam fractionation process. Int. J. Environ. Sci. Technol. 17, 321–332 (2020). https://doi.org/10.1007/s13762-019-02349-9

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  • DOI: https://doi.org/10.1007/s13762-019-02349-9

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