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A novel method for synthesis of nano-γ-Al2O3: study of adsorption behavior of chromium, nickel, cadmium and lead ions

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Abstract

Nano-γ-Al2O3 adsorbent was synthesized by the novel sol–gel method. The adsorbent was characterized by transmission electron microscope, Fourier transform infrared and X-ray powder diffraction. The effects of several variables such as, adsorbent weight, pH and contact time on adsorption of chromium (Cr6+), nickel (Ni2+), cadmium (Cd2+) and lead (Pb2+) ions were studied in batch experiments. The results showed that the synthesized nano-γ-Al2O3 had a good capacity to adsorb Cr and Pb. The kinetic data were described with pseudo-first- and pseudo-second-order models. Three isotherm models, namely Freundlich, Langmuir and Tempkin, were used for analysis of equilibrium data, and results showed that Langmuir and Freundlich models were suitable for describing the equilibrium data of Cr6+, Cd2+, Ni2+ and Pb2+. Using Langmuir isotherm, the maximum sorption capacities of Cr6+, Pb2+, Cd2+ and Ni2+ were estimated to be 13.3, 6, 1.1 and 0.33 (mg/g) at 25 °C, respectively. The sorption capacity did not change remarkably after reuse of sorbent for sorption–desorption cycle. The selectivity order of Cr6+, Pb2+, Cd2+ and Ni2+ sorption onto the adsorbent was Cr6+ > Pb2+ > Cd2+ > Ni2+.

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References

  • Ahmedna M, Marshall WE, Husseiny AA, Rao RM, Goktepe I (2004) The use of nutshell carbons in drinking water filters for removal of trace metal. Water Res 38(4):1062–1068

    Article  CAS  Google Scholar 

  • Ahn CK, Park D, Woo SH, Park JM (2009) Removal of cationic heavy metal from aqueous solution by activated carbon impregnated with anionic surfactants. J Hazard Mater 164:1130–1136

    Article  CAS  Google Scholar 

  • Ai ZH, Chen Y, Zhang LZ, Qiu JR (2008) Efficient removal of Cr(VI) from aqueous solution with Fe@Fe2O3 core–shell nanowires. J Environ Sci Technol 42:6955–6960

    Article  CAS  Google Scholar 

  • Aksu Z (2002) Determination of the equilibrium, kinetic and thermodynamic parameters of the batch biosorption of nickel(II) ions onto Chlorella vulgaris. Prog Biochem. 38(1):89–99

    Article  CAS  Google Scholar 

  • Asencios YJO, S-Kou MR (2012) Synthesis of high surface γ- Al2O3 from aluminum scrap and its use for the adsorption of metals: Pb(II), Cd(II) and Zn(II). Appl Surf Sci 258:10002–10011

    Article  CAS  Google Scholar 

  • Aydin FA, Soylak M (2010) Separation, pre concentration and inductively coupled plasma-mass spectrometric (ICP-MS) determination of thorium (IV), titanium (IV), iron (III), lead (II) and chromium (III) on 2-nitroso-1-naphthol Impregnated MCI GEL CHP20P resin. J Hazard Mater 173:669–674

    Article  CAS  Google Scholar 

  • Aziz HA, Adlan MN, Ariffin KS (2008) Heavy metals (Cd, Pb, Zn, Ni, Cu and Cr(III)) removal from water in Malaysia: post treatment by high quality limestone. Bioresour Technol 99:1578–1583

    Article  CAS  Google Scholar 

  • Baybaş D, Ulusoy U (2011) The use of polyacrylamide-aluminosilicate composites for thorium adsorption. J Appl Clay Sci 5:138–146

    Google Scholar 

  • Chandramouli V, Anthonysamy S, Vasudeva Rao PR, Divakar R (1996) PVA aided microwave synthesis: a novel route for the production of nanocrystalline thoria powder. J Nucl Mater 231:213–220

    Article  CAS  Google Scholar 

  • Debnah S, Ghosh UC (2009) Nano structured hydrous titanium (IV) oxide: synthesis, characterization and Ni (II) adsorption behavior. J Chem Eng 152:480–491

    Article  Google Scholar 

  • El-Kamash AM (2008) Evaluation of zeolite A for the sorptive removal of Cs+ and Sr2+ ions from aqueous solutions using batch and fixed bed column operations. J Hazard Mater 151:432–445

    Article  CAS  Google Scholar 

  • Frost RL, Scholz R, Lopes A, Xi Y, Gobac ZI (2013) LFC. Horta, Raman and infrared spectroscopic characterization of the phosphate mineral paravauxite Fe2+Al2(PO4)2(OH)2_8H2O. Spectrochim Acta A 116:491–496

    Article  CAS  Google Scholar 

  • Goncharuk VV, Kornilovich BY, Pavlenko VM, Babak MI, Pshinko GN, Pysmennyi BV, Kovalchuk IA, Safronova VG (2001) Uranium compounds purification from water and wastewater. J Water Chem Technol 23:44–50

    Google Scholar 

  • Gurgel LVA, Melo JCPD, De Lena JC, Gil LF (2009) Adsorption of chromium (VI) ion from aqueous solution by succinylated mercerized cellulose functionalized with quaternary ammonium groups. J Bioresour Technol 100(13):3214–3220

    Article  CAS  Google Scholar 

  • Hikmet S, Turan U (2014) Removal of heavy metal ions from aqueous medium using Kuluncak(Malatya) vermiculites and effect of precipitation on removal. J Appl Clay Sci 95:1–8

    Article  Google Scholar 

  • Ibrahim DM, Abu-Ayana YM (2009) Preparation of nano alumina via resin synthesis. Mater Chem Phys 113(2–3):579–586

    Article  CAS  Google Scholar 

  • Kaltchev M, Tysoe WT (1999) An infrared spectroscopic investigation of thin alumina films: measurement of acid sites and surface reactivity. J Surf Sci 430:29–36

    Article  CAS  Google Scholar 

  • Kornilovich BY, Kovalchuk IA, Pshinko GN, Tsapyuk EA, Krivoruchko AP (2000) Water purification of uranium by the method of ultrafiltration. J Water Chem Technol 22:43–47

    Google Scholar 

  • Langmuir I (1916) The constitution and fundamental properties of solids and liquids. Part I. Solids. J Am Chem Soc 38(11):2221–2295

    Article  CAS  Google Scholar 

  • Ma MG, Zhu JF (2009) A facile solvo thermal route to synthesis of γ-alumina with bundle-like and flower-like morphologies. Mater Lett 63:881–883

    Article  CAS  Google Scholar 

  • Mahapatra A, Mishra BG, Hota G (2013) Electrospun Fe2O3–Al2O3 nanocomposite fibers as efficient adsorbent for removal of heavy metal ions from aqueous solution. J Hazard Mater 258–259:116–123

    Article  Google Scholar 

  • Mohamed Mahmoud E, Mohamed Abdelwahab S, Fathallah ME (2013) Design of novel nano-sorbents based on nano-magnetic iron oxide–bound-nano-silicon oxide–immobilized-triethylenetetramine for implementation in water treatment of heavy metals. Chem Eng J 223:318–327

    Article  Google Scholar 

  • Mallakpoura Sh, Baratia A (2011) Efficient preparation of hybrid nanocomposite coatings based on poly (vinyl alcohol) and silane coupling agent modified TiO2 nanoparticles. Prog Org Coat 71:391–398

    Article  Google Scholar 

  • Neghlani PK, Rafizadeh M, Taromi FA (2011) Preparation of aminated-polyacrilonitril nano fiber membranes for the adsorption of metal ions: comparison with microfiber. J Hazard Mater 186:182–189

    Article  CAS  Google Scholar 

  • Nero MD, Galindo C, Barillon RI, Halter E, Made B (2010) Surface reactivity of α-Al2O3 and mechanisms of phosphate sorption: in situ ATR–FTIR spectroscopy and potential studies. J Colloid Interface Sci 342:437–444

    Article  Google Scholar 

  • Ngomsik AF, Bee A, Draye M, Cote G, Cabuil V (2005) Magnetic nano- and microparticles for metal removal and environmental applications. J Comput Ren Chem 8(6–7):963–970

    Article  CAS  Google Scholar 

  • Nilchi A, Saberi R, Azizpour H, Moradi M, Zarghami R, Naushad M (2012) Adsorption of caesium from aqueous solution using cerium molybdate–pan composite. Chem Ecol 28(2):169–185

    Article  CAS  Google Scholar 

  • Okada AK, Otsuka N, Somiya S (1991) Review of mullite synthesis routes in Japan. Am Ceram Soc Bull 70:1633–1640

    CAS  Google Scholar 

  • Padmaja P, Anilkumar GM, Mukindan P, Aruldhas G, Warrier KGK (2001) Characterization of stoichiometric sol–gel mullite by Fourier transform infrared spectroscopy. Int J Inorg Mater 3:693–698

    Article  CAS  Google Scholar 

  • Parida KM, Pradhan AC, Das J, Sahu N (2009) Synthesis and characterization of nanosized porous gamma-alumina by control precipitation method. J Mater Chem Phys 113:244–248

    Article  CAS  Google Scholar 

  • Prakash A, McCormick AV, Zachariah MR (2004) Aero-sol-gel synthesis of nano porous iron-oxide particles: a potential oxidizer for nano energetic materials. J Chem Mater 16:1466–1471

    Article  CAS  Google Scholar 

  • Rahmani A, Mousavi HZ, Fazli M (2010) Effect of nanostructure alumina on adsorption of heavy metals. J Desalin 253:94–100

    Article  CAS  Google Scholar 

  • Resterna AB, Cierpiszewski R, Prochaska K (2010) Kinetic and equilibrium studies of the removal of cadmium ions from acidic chloride solutions by hydrophobic pyridinecarboxamide extractants. J Hazard Mater 179:828–833

    Article  Google Scholar 

  • Rodriguez M, Sifontes AB, Mendez FJ, Diaz Y, Izalesb EC, Brito JL (2013) Template synthesis and characterization of mesoporous γ-Al2O3 hollow nano rods using Stevia rebaudiana leaf aqueous extract. J Ceram Int 39:4499–4506

    Article  CAS  Google Scholar 

  • Sen TK, Sarzali MV (2008) Removal of cadmium metal ion (Cd2+) from its aqueous solution by aluminium oxide (Al2O3): a kinetic and equilibrium study. Chem Eng J 142:256–262

    Article  CAS  Google Scholar 

  • Sharma P, Tamar R (2008) Synthesis and application of an analogue of desolate for the removal of Uranium (VI), Thorium(IV), and europium(III) from aqueous waste. Micropor Mesopor Mater 116:641–652

    Article  CAS  Google Scholar 

  • Shiri-Yekta Z, Yaftian MR, Nilchi A (2013) Silica nanoparticles modified with a Schiff base ligand: an efficient adsorbent for Th(IV), U(VI) and Eu(III) ions. Korean J Chem Eng 30(8):1644–1651

    Article  CAS  Google Scholar 

  • Shoushtari AM, Zargaran M, Abdouss M (2006) Preparation and characterization of high efficiency ionexchange cross linked acrylic fibers. J Appl Polym Sci 101:2202–2209

    Article  CAS  Google Scholar 

  • Shu-Huei H, Jao-Jia H (2007) Adsorption behavior of heavy metal ions by carbon nanotube qrown on microsized Al2O3 particles. J Univ Sci Technol B 14(1):77–84

    Article  Google Scholar 

  • Soylak M, Erdogan ND (2006) Copper (II)–rubeanic acid co precipitation system for separation–preconcentration of trace metal ions in environmental samples for their flame atomic absorption spectrometric determinations. J Hazard Mater 137:1035–1041

    Article  CAS  Google Scholar 

  • Sung Lee J, Soo Kim H, Su Lee J, Park NK, Lee TJ, Kang M (2012) Synthesis of a-Al2O3 at mild temperatures by controlling aluminum precursor, pH, and ethylene diamine chelating additive. Ceram Int 38:6685–6691

    Article  CAS  Google Scholar 

  • Uluozlu OD, Tuzen M, Mendil D, Soylak M (2010) Co-precipitation of trace elements with Ni2+/2-nitroso-1-naphthol-4-sulfonic acid and their determination by flame atomic absorption spectrometry. J Hazard Mater 176:032–1037

    Article  Google Scholar 

  • Veriansyah B, Susanti RF, Nugroho A, Min BK, Kim J (2011) Continuous synthesis of high-surface-area aluminum hydroxide methoxide nano- and microparticles in supercritical methanol and their conversion into γ-Al2O3. Mater Lett 65:772–774

    Article  CAS  Google Scholar 

  • Wijnja H, Schulthess CP (1999) ATR–FTIR and DRIFT spectroscopy of carbonate species at the aged γ-Al2O3: water interface. Spectrochim Acta A 55:861–872

    Article  Google Scholar 

  • Wu Sh, Li F, Wang H, Fu L, Zhang B, Li G (2010a) Effects of poly (vinyl alcohol) (PVA) content on preparation of novel thiol-functionalized mesoporous PVA/SiO2 composite nanofiber membranes and their application for adsorption of heavy metal ions from aqueous solution. Polymer 51:6203–6211

    Article  CAS  Google Scholar 

  • Wu Sh, Li F, Xu R, Wei Sh, Wang H (2010b) Preparation of poly (vinyl alcohol)/silica composite nanofibers membrane functionalized with mercapto groups by electrospinning. Mater Lett 64:1295–1298

    Article  CAS  Google Scholar 

  • Xiadong X, Qin W, Jian Y, Liangguo Y, Rui F, Guodong C, Bin D, He L (2012) Highly efficient removal of heavy metal ions by amine-functionalized mesoporousFe3O4 nanoparticles. Chem Eng J 184:132–140

    Article  Google Scholar 

  • Yoo YS, Park KY, Jung KY, Cho SB (2009) Preparation of α-alumina nanoparticles via vapor-phase hydrolysis of AlCl3. Mater Lett 63:1844–1846

    Article  CAS  Google Scholar 

  • Zhang J, Shi F, Lin J, Wei SY, Chen D, Gao JM, Huang Z, Ding XX, Tang C (2008) Nanoparticles assembly of boehmite nanofibers without surfactant. Mater Res Bull 43:1709–1715

    Article  CAS  Google Scholar 

  • Zhou SX, Antonietti M, Niederberger M (2007) Low-temperature synthesis of γ-alumina nanocrystals from aluminum acetylacetonate in non aqueous media. Small 3(5):763–767

    Article  CAS  Google Scholar 

  • Zhou LM, Wang YP, Liu ZR, Huang QW (2009) Characteristics of equilibrium, kinetics studies for adsorption of Hg(II), Cu(II), and Ni(II) ions by thiourea-modified magnetic chitosan microspheres. J Hazard Mater 161:995–1002

    Article  CAS  Google Scholar 

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Acknowledgments

The authors wish to extend their sincere gratitude to all who supported this work.

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Authors and Affiliations

  1. Department of Environmental Science, Graduate School of the Environment and Energy, Science and Research Branch, Islamic Azad University, Tehran, Iran

    A. Shokati Poursani, A. H. Hassani, M. Shariat & J. Nouri

  2. NSTRI, P.O. Box 11365-8486, Tehran, Iran

    A. Nilchi

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  1. A. Shokati Poursani
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  2. A. Nilchi
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  3. A. H. Hassani
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  4. M. Shariat
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  5. J. Nouri
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Correspondence to A. H. Hassani.

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Shokati Poursani, A., Nilchi, A., Hassani, A.H. et al. A novel method for synthesis of nano-γ-Al2O3: study of adsorption behavior of chromium, nickel, cadmium and lead ions. Int. J. Environ. Sci. Technol. 12, 2003–2014 (2015). https://doi.org/10.1007/s13762-014-0740-7

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  • DOI: https://doi.org/10.1007/s13762-014-0740-7

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