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Vortex-assisted solid phase extraction on MIL-101(Cr) of parabens in waters and cosmetics by HPLC–DAD

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Abstract

In this study, metal organic framework MIL-101 (Cr) was used as an adsorbent in the solid phase extraction of parabens before chromatographic analysis. Analytical parameters including pH, adsorption–desorption time, amount of adsorbent, elution solvents, desorption volume and salt effect were optimized. Optimum adsorbent amount and total adsorption and desorption time for determination of parabens were found to be 15 mg and only 10 min. The recovery values obtained with this method are in the range of 90.78–104.89% for water matrix and 85.19–108.35% for cosmetics. The detection limits of the HPLC method for methyl, ethyl, propyl, and butyl parabens are 0.0387, 0.0322, 0.0299, and 0.0339 ug/mL, respectively. Prior to HPLC analysis, a new, fast, inexpensive, and environmentally friendly solid phase extraction method based on vortex-assisted MIL-101 (Cr) adsorption was developed. This proposed VA-SPE-HPLC procedure was used for the extraction and determination of four different parabens from water and cosmetic samples.

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Acknowledgements

The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Erciyes University (FYL-2021-11170). The authors also thank to ERU-TAUM for instrumental facilities. The authors also thank to Ege University Central Research Testing and Analysis Laboratory Research and Application Center (EGE-MATAL) and also Ege University, Faculty of Pharmacy, Pharmaceutical Sciences Research Centre (FABAL).

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Authors and Affiliations

  1. Faculty of Pharmacy, Department of Pharmaceutical Chemistry, Ege University, 35100, Izmir, Turkey

    Cigdem Yengin

  2. Central Research Testing and Analysis Laboratory Research and Application Center (EGE-MATAL), Ege University, 35100, Izmir, Turkey

    Zinar Pinar Gumus & Raif Ilktac

  3. Faculty of Science, Department of Chemistry, Ege University, 35040, Izmir, Turkey

    Aydan Elci

  4. Faculty of Sciences, Department of Chemistry, Erciyes University, 38039, Kayseri, Turkey

    Mustafa Soylak

  5. Technology Research and Application Center (ERU-TAUM), Erciyes University, 38039, Kayseri, Turkey

    Mustafa Soylak

  6. Turkish Academy of Sciences (TUBA), Cankaya, Ankara, Turkey

    Mustafa Soylak

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  1. Cigdem Yengin
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Yengin, C., Gumus, Z.P., Ilktac, R. et al. Vortex-assisted solid phase extraction on MIL-101(Cr) of parabens in waters and cosmetics by HPLC–DAD. J IRAN CHEM SOC 20, 1383–1393 (2023). https://doi.org/10.1007/s13738-023-02763-4

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