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Deep eutectic solvent containing 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol immobilized on magnetic graphene oxide as a selective sorbent for dispersive micro-solid phase extraction of cadmium ions

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Abstract

A sorbent with high selectivity and capacity for cadmium ions was prepared through immobilization of deep eutectic solvent (DES) of ChCl- glycerol containing the ligand 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol (acacapyrH2) on the magnetic graphene oxide. A dispersive micro-solid phase extraction was designed, and the separated/preconcentrated cadmium ion was determined by flow injection flame atomic absorption spectrometry. After the optimization of effective parameters, the method showed linearity in the concentration range of 0.25–15 µg L−1 with the coefficient of determination (r2) of 0.9991 and enhancement factor of 195 for cadmium. The method was very sensitive with the detection limit (defined as 3Sb/m) of 0.06 µg L−1. The method was successfully applied to the determination of Cd(II) in water (drinking and river), fruit (lemon, apricot, and peach) and meat (fish, chicken, and cow meat) samples.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Yazd University, 89195-741, Yazd, Iran

    Mehdi Karimi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani & Rasoul Vafazadeh

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  1. Mehdi Karimi
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  2. Shayessteh Dadfarnia
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  3. Ali Mohammad Haji Shabani
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  4. Rasoul Vafazadeh
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Correspondence to Shayessteh Dadfarnia.

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Karimi, M., Dadfarnia, S., Haji Shabani, A. et al. Deep eutectic solvent containing 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol immobilized on magnetic graphene oxide as a selective sorbent for dispersive micro-solid phase extraction of cadmium ions. J IRAN CHEM SOC 18, 1311–1319 (2021). https://doi.org/10.1007/s13738-020-02113-8

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