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Decorated palladium nanoparticles on mesoporous organosilicate as an efficient catalyst for Sonogashira coupling reaction

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Abstract

Reforming mesoporous silica was provided by the reaction of SBA‐15 with (3-aminopropyl)triethoxysilane, the product of which was treated with furfural to give SBA-propyl-imine-furan. In the next step, palladium chloride was attached to the functionalized SBA‐15, so Pd nanoparticles immobilized on the mentioned catalyst for providing an applicable catalyst to use in the Sonogashira cross-coupling reaction. The high stability and performance of functionalized heterogeneous hybrid catalyst of Pd@SBA-Pr-imine-furan in overall were highly essential. The nano-structured Pd@SBA-Pr-imine-furan catalyst was studied for Sonogashira cross-coupling reaction by phenylacetylene and various aryl halides under reflux conditions with a small amount of catalyst. In comparison with the earlier reports, this paper offered several benefits such as short reaction times, high yields of products, catalyst stability, quick recovery, and catalytic activity for at least seven continuous runs.

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Acknowledgement

We are grateful for financial support from the Research Council of Alzahra University and Tehran University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Physics and Chemistry, University of Alzahra, Tehran, Iran

    Fatemeh Mohajer & Ghodsi Mohammadi Ziarani

  2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Badiei

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  1. Fatemeh Mohajer
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  2. Ghodsi Mohammadi Ziarani
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  3. Alireza Badiei
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Correspondence to Ghodsi Mohammadi Ziarani.

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Mohajer, F., Mohammadi Ziarani, G. & Badiei, A. Decorated palladium nanoparticles on mesoporous organosilicate as an efficient catalyst for Sonogashira coupling reaction. J IRAN CHEM SOC 18, 589–601 (2021). https://doi.org/10.1007/s13738-020-02044-4

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