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Facile and eco-friendly synthesis of TiO2 NPs using extracts of Verbascum thapsus plant: an efficient photocatalyst for reduction of Cr(VI) ions in the aqueous solution

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Abstract

In this study, a fast and green synthesis of TiO2 nanoparticles (TiO2 NPs) is investigated using Verbascum thapsus (V. thapsus) plant aqueous extract as a reducing and stabilizing agent at room temperature. The TiO2 NPs formation and the optical properties were followed by the absorption spectra in ultraviolet–visible spectroscopy. This spectrum showed a strong absorption peak of around 356 nm. Moreover, the green synthesized TiO2 NPs were characterized by different techniques, for example, X-ray powder diffraction was used to analyze the phase and crystal structure, Fourier-transform infrared spectroscopy was conducted to know the functional groups involved in the NPs TiO2, and transmission electron microscopy was carried out to determine the morphology and size. The results showed a successful synthesis and anatase phase with spherical shape and smaller than 13 nm and also the presence of a few phytochemicals of the extracts around the synthesized TiO2 NPs, which acted as stabilizing the NPs. X-ray photoelectron spectroscopy analysis was carried out to characterize TiO2 NPs for evaluating the chemical states of the elements. The catalytic activity of the green synthesized TiO2 NPs was examined on photoreduction of Cr(VI) ions in the aqueous solution. The found conditions are as follows: [TiO2 NPs] = 750 mg/L, pH = 3.5, T = 25 °C and after 120 min of reaction photocatalytic reduction of Cr(VI) ions, 79.6% reduction efficacy (RE) was achieved. It was found that the reduction kinetic fitted the pseudo-first-order model. Finally, the photocatalyst reusability was investigated after five times of recovery; RE was reduced to 78.1%.

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References

  1. K. Vidhya, M. Saravanan, G. Bhoopathi, V.P. Devarajan, S. Subanya, Appl. Nanosci. 5, 235–243 (2015)

    CAS  Google Scholar 

  2. G. Zhang, X. Shen, Y. Yang, J. Phys. Chem. C 115, 7145–7152 (2011)

    CAS  Google Scholar 

  3. M. Sundrarajan, K. Bama, M. Bhavani, S. Jegatheeswaran, S. Ambika, A. Sangili, P. Nithya, R. Sumathi, J. Photochem. Photobiol. 171, 117–124 (2017)

    CAS  Google Scholar 

  4. D. Mukherjee, S. Ghosh, S. Majumdar, K. Annapurna, J. Environ. Chem. Eng. 4, 639–650 (2016)

    CAS  Google Scholar 

  5. D.S. Bhatkhande, V.G. Pangarkar, A.A. Beenackers, J. Chem. Technol. Biotechnol. 77, 102–116 (2001)

    Google Scholar 

  6. M. Nasrollahzadeh, S.M. Sajadi, Ceram. Int. 41, 14435–14439 (2015)

    CAS  Google Scholar 

  7. M.R. Hoffmann, S.T. Martin, W. Choi, D.W. Bahnemann, Chem. Rev. 95, 69–96 (1995)

    CAS  Google Scholar 

  8. G. Centi, P. Ciambelli, S. Perathoner, P. Russo, Catal. Today 75, 3–15 (2002)

    CAS  Google Scholar 

  9. S.S. Muniandy, N.H. Mohd Kaus, Z.-T. Jiang, M. Altarawneh, H.L. Lee, RSC Adv. 7, 48083–48094 (2017)

    CAS  Google Scholar 

  10. B. O’Regan, M. Grätzel, Nature 353, 737 (1991)

    Google Scholar 

  11. K. Murugan, D. Dinesh, K. Kavithaa, M. Paulpandi, T. Ponraj, M.S. Alsalhi, S.J. Devanesan, R. Subramaniam, H. Rajaganesh, S. Wei, M. Kumar, G. Nicoletti, P. Benelli, Parasitol. Res. 115, 1085–1096 (2016)

    PubMed  Google Scholar 

  12. K. Kądzioła, I. Piwoński, A. Kisielewska, D. Szczukocki, B. Krawczyk, J. Sielski, Appl. Surf. Sci. 288, 503–512 (2014)

    Google Scholar 

  13. R. Khan, M.H. Fulekar, J. Colloid Interface Sci. 475, 184–191 (2016)

    CAS  PubMed  Google Scholar 

  14. O.V. Kharissova, H.V.R. Dias, B.I. Kharisov, B.O. Pérez, V.M.J. Pérez, Trends Biotechnol. 31, 240–248 (2013)

    CAS  PubMed  Google Scholar 

  15. G. Nabi, N.R. Qurat-ul-Aain, M.Bilal Khalid, M. Tahir, M. Rafique, S. Rizwan, T. Hussain, A.Majid Iqbal, J. Inorg. Organomet. Polym Mater. 28, 1552–1564 (2018)

    CAS  Google Scholar 

  16. N.I. Hulkoti, T.C. Taranath, Colloids Surf. B 121, 474–483 (2014)

    CAS  Google Scholar 

  17. S.P. Goutam, G. Saxena, V. Singh, A.K. Yadav, R.N. Bharagava, K.B. Thapa, Chem. Eng. J. 336, 386–396 (2018)

    CAS  Google Scholar 

  18. WHO, Guidelines for Drinking Water Quality (World Health Organization, Geneva, 2006)

    Google Scholar 

  19. G. Donmez, Z. Aksu, Process Biochem. 38, 751–762 (2002)

    CAS  Google Scholar 

  20. Y.C. Zhang, M. Yang, G. Zhang, D.D. Dionysiou, Appl. Catal. B Environ. 142–143, 249–258 (2013)

    Google Scholar 

  21. D. Chen, A.K. Ray, Chem. Eng. Sci. 56, 1561–1570 (2001)

    CAS  Google Scholar 

  22. M. Shirzad Siboni, M.T. Samadi, J.K. Yang, S.M. Lee, Desalin Water Treat. 40, 77–83 (2012)

    CAS  Google Scholar 

  23. K. Ramachandran, K. Kashyapa, R. Chand, The Useful Plants of India (Council of Scientific and Industrial Research, New Delhi, 1986)

    Google Scholar 

  24. A. Chevallier, Encyclopedia of Herbal Medicine (Dorling Kindersley Publishing Inc, New York, 2000)

    Google Scholar 

  25. T. Warashina, T. Miyase, A. Veno, Phytochemistry 31, 961–965 (1992)

    CAS  PubMed  Google Scholar 

  26. H. Hussain, S. Aziz, G.A. Miana, V.U. Ahmad, S. Anwar, I. Ahmed, Biochem. Syst. Ecol. 37, 124–126 (2009)

    CAS  Google Scholar 

  27. L.A. Shaver, S.H. Leung, A. Puderbaugh, S.A. Angel, J. Chem. Educ. 88, 492–495 (2011)

    CAS  Google Scholar 

  28. V.L. Singleton, R. Orthofer, R.M. Lamuela-Raventós, Methods Enzymol. 299, 152–178 (1999)

    CAS  Google Scholar 

  29. K. Velayutham, A.A. Rahuman, G. Rajakumar, T. Santhoshkumar, S. Marimuthu, C. Jayaseelan, A. Bagavan, A.V. Kirthi, C. Kamaraj, A.A. Zahir, G. Elango, Parasitol. Res. 111, 2329–2337 (2012)

    PubMed  Google Scholar 

  30. R. Dobrucka, Iran. J. Pharm. Res. 16, 756–762 (2017)

    PubMed  PubMed Central  Google Scholar 

  31. T. Mahmood, M.T. Saddique, A. Naeem, P. Westerhoff, S. Mustafa, A. Alum, Ind. Eng. Chem. Res. 50, 10017–10023 (2011)

    CAS  Google Scholar 

  32. W.F. Tan, S.J. Lu, F. Liu, X.H. Feng, J.Z. He, L.K. Koopal, Soil Sci. 173, 277–286 (2008)

    CAS  Google Scholar 

  33. L.S. Clesceri, A.E. Greenberg, A.D. Eaton, Standard Methods for the Examination of Water and Wastewater (American Public Health Association, Washington, 1998)

    Google Scholar 

  34. E.E. Elemike, D.C. Onwudiwe, Z. Mkhize, Mater. Lett. 185, 452–455 (2016)

    CAS  Google Scholar 

  35. J.C. Tauc, The Optical Properties of Solids (North Holland, Amsterdam, 1972)

    Google Scholar 

  36. C. Dette, M.A. Pérez-Osorio, C.S. Kley, P. Punke, C.E. Patrick, P. Jacobson, F. Giustino, S.J. Jung, K. Kern, Nano Lett. 14, 6533–6538 (2014)

    CAS  PubMed  Google Scholar 

  37. N. Wang, L. Zhu, K. Deng, Y. She, Y. Yu, H. Tang, Appl. Catal. B Environ. 95, 400–407 (2010)

    CAS  Google Scholar 

  38. M. Hudlikar, S. Joglekar, M. Dhaygude, K. Kodam, Mater. Lett. 75, 196–199 (2012)

    CAS  Google Scholar 

  39. J.S.J. Hargreaves, Catal. Struct. React. 2, 33–37 (2016)

    CAS  Google Scholar 

  40. R.K.B. Bharti, S. Kumar, H.N. Lee, Sci. Rep. 6, 1–12 (2016)

    CAS  Google Scholar 

  41. D. Hariharan, A.J. Christy, J. Mayandi, L.C. Nehru, Mater. Lett. 222, 45–49 (2018)

    CAS  Google Scholar 

  42. N. Serpone, J. Photochem. Photobiol. 104, 1–12 (1997)

    CAS  Google Scholar 

  43. K. Kabra, R. Chaudhary, R.L. Sawhney, Environ. Prog. 24, 487–495 (2008)

    Google Scholar 

  44. J. Saien, A.R. Soleymani, J. Iran. Chem. Soc. 6, 602–611 (2009)

    CAS  Google Scholar 

  45. L.B. Khalil, W.E. Mourad, M.W. Rophael, Appl. Catal. B Environ. 17, 267–273 (1998)

    CAS  Google Scholar 

  46. T. Papadam, N.P. Xekoukoulotakis, I. Poulios, D. Mantzavinos, J. Photochem. Photobiol. 186, 308–315 (2007)

    CAS  Google Scholar 

  47. J. Saien, A. Azizi, A.R. Soleymani, J. Iran. Chem. Soc. 11, 1439–1448 (2014)

    CAS  Google Scholar 

  48. P. Sane, S. Chaudhari, P. Nemade, S. Sontakke, J. Environ. Chem. Eng. 6, 68–73 (2018)

    CAS  Google Scholar 

Download references

Acknowledgement

The authors wish to acknowledge the university authorities for providing the financial support to carry out this work.

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Authors and Affiliations

  1. Department of Ornamental Plants, Faculty of Agriculture, Arak Branch, Islamic Azad University, Arāk, Iran

    R. Norouzi Esfahani

  2. Department of Agronomy and Plant Breeding, Arak Branch, Islamic Azad University, Arāk, Iran

    Sh. Khaghani & M. Gomarian

  3. Department of Chemistry, Faculty of Science, Arak University, Arāk, 3815688138, Iran

    A. Azizi

  4. Department of Horticulture, Khorasgan (Isfahan) Branch, Islamic Azad University, Esfahān, Iran

    F. Mortazaeinezhad

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  1. R. Norouzi Esfahani
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  2. Sh. Khaghani
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Correspondence to Sh. Khaghani.

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Esfahani, R.N., Khaghani, S., Azizi, A. et al. Facile and eco-friendly synthesis of TiO2 NPs using extracts of Verbascum thapsus plant: an efficient photocatalyst for reduction of Cr(VI) ions in the aqueous solution. J IRAN CHEM SOC 17, 205–213 (2020). https://doi.org/10.1007/s13738-019-01755-7

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