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Thermally reduced sugarcane bagasse carbon quantum dots and in-plane flax fiber unsaturated polyester composites: surface conductivity and mechanical properties

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Abstract

This study looked at the mechanical, electrical, and thermal surface conductivity of a polyester composite reinforced with flax fiber and thermally reduced carbon quantum dots. The primary objective of this work was to ascertain how incorporating carbon dots from thermally reduced biomass sugarcane bagasse enhanced the qualities of the polyester composite and resulted in its development as a sustainable material for cutting-edge applications. By pyrolyzing sugarcane bagasse, carbon dots were produced, and then hand layup was used to create the composites. After that, the effects of the addition of carbon dots were evaluated by testing the composite material in accordance with the American Society for Testing of Materials (ASTM) criteria. The findings demonstrated that increasing the amount of carbon dots in a polyester composite by up to 5 vol.% increased its tensile, flexural, and impact strength. However, the properties changed when the carbon dots content was raised to 7 vol.%. The highest hardness of the 7 vol.% carbon dots distributed composite, in contrast, was 82 shore-D, and its specific wear rate was reduced at 0.005 mm3/Nm. The dielectric constant and dielectric loss are both at their maximum values in the 7 vol.% carbon dots dispersed composite, at 4.1 and 0.15, respectively. This polyester composite also exhibits excellent thermal conductivity (0.394 W/mK), demonstrating effective heat transfer bridge development. Thus, these polyester composites with better surface conductivity (electrical, thermal, and hydrophobicity) and mechanical properties could be employed as a functional material for electrical and thermal applications.

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References

  1. Karthick et al (2022) Int J Chem Eng 2022

  2. Natrayan L et al (2021) Processing and characterization of carbon nanofibre composites for automotive applications. J Nanomater 2021:1–7

  3. Ramaswamy R, Gurupranes SV, Kaliappan S, Natrayan L, Patil PP (2022) Characterization of prickly pear short fiber and red onion peel biocarbon nanosheets toughened epoxy composites. Polym Compos 43(8):4899–4908

  4. Crosky A et al (2013) Thermoset matrix natural fibre-reinforced composites. Woodhead Publishing Limited

    Google Scholar 

  5. Karthi N, Kumaresan K, Sathish S, Prabhu L, Gokulkumar S, Balaji D, Vigneshkumar N, Rohinth S, Rafiq S, Muniyaraj S, Pavithran S (2021) Effect of weight fraction on the mechanical properties of flax and jute fibers reinforced epoxy hybrid composites. Mater Today Proc 45:8006–8010

  6. Aynalem GF, Sirahbizu B (2021) Effect of Al2O3 on the tensile and impact strength of flax/unsaturated polyester composite with emphasis on automobile body applications. AdvMater Sci Eng 2021:1–9

  7. Lu MM, Fuentes CA, Van Vuure AW (2022) Moisture sorption and swelling of flax fibre and flax fibre composites. Compos Part B Eng 231:109538

  8. Jia Y, Fiedler B (2020) Tensile creep behaviour of unidirectional flax fibre reinforced bio-based epoxy composites. Compos Commun 18:5–12

  9. Malik K, Ahmad F, Yunus NA, Gunister E, Nakato T, Mouri E, Ali S (2022) A Review of flax fiber reinforced thermoset polymer composites: Thermal-physical properties, improvements and application. J Nat Fibers 19(15):10412–10430

  10. Qian H, Greenhalgh ES, Shaffer MSP, Bismarck A (2010) Carbon nanotube-based hierarchical composites: a review. J Mater Chem 20(23):4751

  11. Wang B, Zhou G, Wang L, Gao Y (2016) Preparation and properties of hierarchical composites based on carbon nanotubes‐coated glass babric preform. Polym Compos 37(4):979–986

  12. Madhi A, Shirkavand Hadavand B (2022) UV protective bio-based epoxy/carbon quantum dots nanocomposite coatings: Synthesis and investigation of properties. J Compos Mater 56(14):2201–2210

  13. Jayaraman R, Girimurugan R, Suresh V, Shilaja C, Mayakannan S (2022) Improvement on tensile properties of epoxy resin matrix sugarcane fiber and tamarind seed powder reinforced hybrid bio-composites. ECS Trans 107(1):7265

  14. Wang X, Feng Y, Dong P, Huang J (2019) A mini review on carbon quantum dots: preparation, properties, and electrocatalytic application. Front Chem 7:671

  15. Singh H, Chatterjee A (2020) Potential of alkali treated cornhusk film as reinforcement for epoxy laminate composites. Cellulose 27(5):2555–2567

  16. Arun Prakash VR, Viswanathan R (2019) Fabrication and characterization of silanized echinoidea fillers and kenaf fibre-reinforced Azadirachta-indica blended epoxy multi-hybrid biocomposite. Int J Plast Technol 23:207–217

  17. Jayabalakrishnan D, Saravanan K, Ravi S, Prabhu P, Maridurai T, Arun Prakash VR (2021) Fabrication and characterization of acrylonitrile butadiene rubber and stitched E-glass fibre tailored Nano-silica epoxy resin composite. Silicon 13(8):2509–2517

  18. Alshahrani H, Arun Prakash VR (2022) Mechanical, fatigue and DMA behaviour of high content cellulosic corn husk fibre and orange peel biochar epoxy biocomposite: a greener material for cleaner production. J Clean Prod 374:133931

  19. Alshahrani H, Arun Prakash VR (2022) Thermal, mechanical and barrier properties of rice husk ash biosilica toughened epoxy biocomposite coating for structural application. Prog Org Coat 172:107080

  20. Alshahrani H, Pathinettampadian G, Gujba AK, Arun Prakash VR (2022) Effect of palmyra sprout fiber and biosilica on mechanical, wear, thermal and hydrophobic behavior of epoxy resin composite. J Ind Text 52:15280837221137382

  21. Arun Prakash VR, Rajadurai A (2016) Mechanical, thermal and dielectric characterization of iron oxide particles dispersed glass fiber epoxy resin hybrid composite. Dig J Nanomater Biostructures 11(2)

  22. Huang X, Cui B, Ma Y, Yan X, Xia L, Zhou N, Wang M, He L, Zhang Z (2019) Three-dimensional nitrogen-doped mesoporous carbon nanomaterials derived from plant biomass: Costeffective construction of label-free electrochemical aptasensor for sensitively detecting alpha-fetoprotein. Anal Chim Acta 1078:125–134

  23. Arun Prakash VR, Jaisingh SJ (2018) Mechanical strength behaviour of silane treated E-glass fibre/Al 6061 & SS-304 wire mesh reinforced epoxy resin hybrid composite. Silicon 10(5):2279–2286

  24. Hamidon MH, Sultan MTH, Ariffin AH, Shah AUM (2019) Effects of fibre treatment on mechanical properties of kenaf fibre reinforced composites: a review. J Mater Res Technol 8(3):3327–3337

  25. Ramesh M, Rajeshkumar L, Deepa C, Tamil Selvan M, Kushvaha V, Asrofi M (2022) Impact of silane treatment on characterization of ipomoea staphylina plant fiber reinforced epoxy composites. J Nat Fibers 19(13):5888–5899

  26. Bourchak M, Ajaj R, Khalid M, Juhany KA, Arun Prakash VR, Alshahrani H (2023) Development of light weight sustainable pineapple/kevlar hybridized fiber and peanut husk cellulose toughened vinyl ester biocomposite for unmanned aerial vehicle applications. J Vinyl Addit Technol. https://doi.org/10.1002/vnl.21990

  27. Zhou D, Qiu F, Wang H, Jiang Q (2014) Manufacture of nano-sized particle-reinforced metal matrix composites: a review. Acta Metall Sin (English Letters) 27:798–805

  28. Alshahrani H, Vr AP (2022) Biomass Convers. Biorefinery 1:1–12

  29. Sailesh A, Palanikumar K (2021) Mechanical properties of flax-cotton fiber reinforced polymer composites. Green Compos: 393–411

  30. Giri P, Charan K, Muniappan A (2018) Investigation of mechanical properties of natural fiber composite with & without fiber surface treatments. Int J Mech Prod Eng Res Dev 8(4):785–790

  31. Prabhu P, Jayabalakrishnan D, Balaji V, Bhaskar K, Maridurai T, Arun Prakash VR (2022) Mechanical, tribology, dielectric, thermal conductivity, and water absorption behaviour of Caryota urens woven fibre-reinforced coconut husk biochar toughened wood-plastic composite. Biomass Convers. Biorefinery 2022:1–8

  32. Karthigairajan M, Nagarajan PK, Raviraja Malarvannan R, Ramesh Bapu BR, Jayabalakrishnan D, Maridurai T, Shanmuganathan VK (2021) Effect of silane-treated rice husk derived biosilica on visco-elastic, thermal conductivity and hydrophobicity behavior of epoxy biocomposite coating for air-duct application. Silicon 13:4421–4430

  33. Eyssa HM, Afifi M, Moustafa H (2023) Improvement of the acoustic and mechanical properties of sponge ethylene propylene diene rubber/carbon nanotube composites crosslinked by subsequent sulfur and electron beam irradiation. Polymer International 72(1):87–98

  34. Jayabalakrishnan D, Prabhu P, Iqbal MS, Mugendiran V, Ravi S, Arun Prakash VR (2022) Mechanical, dielectric, and hydrophobicity behavior of coconut shell biochar toughened Caryota urens natural fiber reinforced epoxy composite. Polym Compos 43(1):493–502

  35. Arun Prakash VR, Rajadurai A (2016) Mechanical, thermal and dielectric characterization of iron oxide particles dispersed glass fiber epoxy resin hybrid composite. Dig J Nanomater Biostruct 11(2):373–380

  36. Arun Prakash VR, Rajadurai A (2016) Thermo-mechanical characterization of siliconized E-glass fiber/hematite particles reinforced epoxy resin hybrid composite. Appl Surf Sci 384:99–106

  37. Thiyagu TT, Sai Prasanna Kumar JV, Sathiyamoorthy V,  Arun Prakash VR (2021) Effect of cashew shell biomass synthesized cardanol oil green compatibilizer on flexibility, barrier, thermal, and wettability of PLA/PBAT biocomposite films. Biomass Conv Bioref 2021: 1–11. https://doi.org/10.1007/s13399-021-01941-9

  38. Alshahrani H, Arun Prakash VR (2022) Mechanical, thermal, viscoelastic and hydrophobicity behavior of complex grape stalk lignin and bamboo fiber reinforced polyester composite. Int J Biol Macromol 223:851–859

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K. Saravanan, D. Jayabalakrishnan: research, drafting, and proofing.

K. Bhaskar, S. Madhu: conceptualization.

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Correspondence to K. Saravanan.

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Saravanan, K., Jayabalakrishnan, D., Bhaskar, K. et al. Thermally reduced sugarcane bagasse carbon quantum dots and in-plane flax fiber unsaturated polyester composites: surface conductivity and mechanical properties. Biomass Conv. Bioref. (2023). https://doi.org/10.1007/s13399-023-04158-0

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