Abstract
In this study, we present the fabrication route of quasicrystal surface relief grating (SRG) of azopolymer. Based on photo-reconfigurable azobenzene property, various morphologies of grating patterns were inscribed on azopolymer thin-films by two-beam coupling light interference lithography (LIL) process. Multiplexing the LIL with different rotation sequence on azopolymers resulted in unusual surface structures including quasicrystal-like SRGs with Fibonacci sequences in rotational LIL. We investigated the effect of rotation sequence on the grating patterns by atomic force microscope, revealing that rotation sequence is a critical parameter determining surface structures of azopolymer films.
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A. Priimagi and A. Shevchenko, J. Polym. Sci., Part B: Polym. Phys., 52, 163 (2014).
A. Sobolewska, J. Zawada, and S. Bartkiewicz, Langmuir, 30, 17 (2014).
F. Pirani, A. Angelini, S. Ricciardi, F. Frascella, and E. Descrovi, Appl. Phys. Lett., 110, 101603 (2017).
F. Pirani, A. Angelini, F. Frascella, R. Rizzo, S. Ricciardi, and E. Descrovi, Sci. Rep., 6, 31702 (2016).
C. Zong, Y. Zhao, H. Ji, X. Han, J. Xie, J. Wang, Y. Cao, S. Jiang, and C. Lu, Angew. Chem. Int. Ed. Engl., 55, 3931 (2016).
S. Lee, H. S. Kang, A. Ambrosio, J. K. Park, and L. Marrucci, ACS Appl. Mater. Interfaces, 7, 8209 (2015).
Z. Sekkat and S. Kawata, Laser Photonics Rev., 8, 1 (2014).
A. Sobolewska and S. Bartkiewicz, J. Mater. Chem. C Mater. Opt. Electron. Devices, 3, 5616 (2015).
A. Ambrosio, S. Girardo, A. Camposeo, D. Pisignano, and P. Maddalena, Appl. Phys. Lett., 102, 093102 (2013).
C. Hubert, C. Fiorini-Debuisschert, I. Maurin, J. M. Nunzi, and P. Raimond, Adv. Mater., 14, 729 (2002).
R. Barille, J. M. Nunzi, S. Ahmadi-Kandjani, E. Ortyl, and S. Kucharski, Opt. Commun., 280, 217 (2007).
L. Mazaheri, O. Lebel, and J. M. Nunzi, Opt. Lett., 42, 4845 (2017).
B. Stiller, T. Geue, K. Morawetz, and M. Saphiannikova, J. Micosc., 219, 109 (2005).
Z. Sekkat, Appl. Opt., 55, 259 (2016).
K. H. Kim and Y. C. Jeong, Opt. Express, 26, 5711 (2018)
S. Kawata and Y. Kawata, Chem. Rev., 100, 1777 (2000).
D. Gindre, A. Boeglin, A. Fort, L. Mager, and K. D. Dorkenoo, Opt. Express, 14, 9896 (2006).
J. W. Kang, M. J. Kim, J. P. Kim, S. J. Yoo, J. S. Lee, D. Y. Kim, and J. J. Kim, Appl. Phys. Lett., 82, 3823 (2003).
R. J. Stockermans and P. L. Rochon, Appl. Opt., 38, 3714 (1999).
O. M. Tanchak and C. J. Barrett, Macromolecules, 38, 10566 (2005).
M. Döbbelin, A. Ciesielski, S. Haar, S. Osella, M. Bruna, A. Minoia, L. Grisanti, T. Mosciatti, F. Richard, E. A. Prasetyanto, L. De Cola, V. Palermo, R. Mazzaro, V. Morandi, R. Lazzaroni, A. C. Ferrari, D. Beljonne, and P. Samorì, Nat. Commun., 7, 11090 (2016).
D. Liu, C. W. Bastiaansen, J. M. den Toonder, and D. J. Broer, Angew. Chem. Int. Ed. Engl., 51, 892 (2012).
J. M. Harrison, D. Goldbaum, T. C. Corkery, C. J. Barrett, and R. R. Chromik, J. Mater. Chem. C Mater. Opt. Electron. Devices, 3, 995 (2015).
V. Teboul, R. Barillé, P. Tajalli, S. Ahmadi-Kandjani, H. Tajalli, S. Zielinska, and E. Ortyl, Soft Matter, 11, 6444 (2015).
P. Karageorgiev, D. Neher, B. Schulz, B. Stiller, U. Pietsch, M. Giersig, and L. Brehmer, Nat. Mater., 4, 699 (2005).
K. H. Kim and Y. C. Jeong, Opt. Express, 24, 25242 (2016).
L. Sorelli, F. Fabbri, J. Frech-Baronet, A. D. Vu, M. Fafard, T. Gacoin, K. Lahlil, L. Martinelli, Y. Lassailly, and J. Peretti, J. Mater. Chem. C Mater. Opt. Electron. Devices, 3, 11055 (2015).
T. B. Lim, K. H. Cho, Y. H. Kim, and Y. C. Jeong, Opt. Express, 24, 17950 (2016).
M. Guo, Z. Xu, and X. Wang, Langmuir, 24, 2740 (2008).
R. Wei, Z. Xu, and X. Wang, Opt. Mater. Express, 5, 1348 (2015).
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Acknowledgments: This work was supported by MOTIE (Ministry of Trade, Industry & Energy (project number 10051918, 10077471)) and KDRC (Korea Display Research Consortium) support program for the development of future devices technology for display industry.
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Kim, KH., Cho, K.Y. & Jeong, YC. Nature-Inspired Quasicrystal SRG Using Fibonacci Sequences in Photo-Reconfiguration on Azo Polymer Films. Macromol. Res. 26, 1042–1047 (2018). https://doi.org/10.1007/s13233-018-6146-5
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DOI: https://doi.org/10.1007/s13233-018-6146-5