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Synthesis, characterization, and thermal stability properties of PVTNP-co-PVAA through the azidoacetylation of polyvinyl 2,4,6-trinitrophenylacetal

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Abstract

A new energetic polymer, poly(vinyl 2,4,6-trinitrophenylacetal)-co-poly(vinyl acetate azide) (PVTNP-co-PVAA), was synthesized by a two-step process involving initial chloroacetylation and subsequent azidation of poly(vinyl 2,4,6-trinitrophenylaceta). The synthesized polymers were characterized by elemental analysis, UV-Vis, ATR-FTIR, and 1H NMR techniques. The glass-transition temperature of PVTNP-co-PVAA was evaluated by differential scanning calorimetry (DSC), and the thermal stability of PVTNP-co-PVAA was tested by differential thermal analysis (DTA) and thermogravimetric analysis (TGA). DSC traces showed that PVTNP-co-PVAA had two glass-transition temperatures at −27.53 and 67.05 °C, respectively. DTA and TGA curves showed that the thermo-oxidative degradation of PVTNP-co-PVAA in air was a two-step reaction, and the percentage of degraded PVTNP-co-PVAA reached nearly 100% at 600 °C.

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Authors and Affiliations

  1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang, 621010, P. R. China

    Bo Jin, Juan Shen, Rufang Peng & Shijin Chu

  2. Institute of Chemical Materials, Chinese Academy of Engineering Physics, Sichuan Mianyang, 621900, P. R. China

    Yuanjie Shu & Haishan Dong

Authors
  1. Bo Jin
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  2. Juan Shen
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  3. Rufang Peng
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  4. Yuanjie Shu
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  5. Shijin Chu
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  6. Haishan Dong
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Correspondence to Bo Jin or Rufang Peng.

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The image from this article is used as the cover image of the Volume 22, Issue 2.

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Jin, B., Shen, J., Peng, R. et al. Synthesis, characterization, and thermal stability properties of PVTNP-co-PVAA through the azidoacetylation of polyvinyl 2,4,6-trinitrophenylacetal. Macromol. Res. 22, 117–123 (2014). https://doi.org/10.1007/s13233-014-2028-7

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  • DOI: https://doi.org/10.1007/s13233-014-2028-7

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