Abstract
The slurry polymerization reactors on the industrial scale operate in continuous mode at low monomer conversion per pass to minimize mass and heat transfer limitations. Nevertheless, for the screening of catalytic systems, the laboratory tests are carried out using batch or semi-batch reactors. In this work, ethylene/propylene copolymers were synthesized in a semi-continuous reactor under similar conditions, where the only difference involves the modification of the feed ratio during the reaction. The key point of the control system is a micro-gas chromatograph (MGC), which analyzes the molar ratio ethylene (C 2) to propylene (C 3) in the gas phase during the reaction, and the composition in the liquid phase was calculated using the Soave-Redlich-Kwong equation of state. The effect of the ethylene/propylene copolymer microstructure has been studied using different techniques that allow us to conclude that the method of synthesis influences the comonomer distribution and the final copolymer properties.
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Van Grieken, R., Calleja, G., Suarez, I. et al. Influence of the feeding control on the final properties of ethylene/propylene copolymers obtained in laboratory semi-batch reactor. Macromol. Res. 21, 137–145 (2013). https://doi.org/10.1007/s13233-012-0187-y
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DOI: https://doi.org/10.1007/s13233-012-0187-y