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Understanding sedimentary depositional environments through geochemical signatures of a Tropical (Vaghotan) estuary, West Coast of India

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Abstract

Two sediment cores collected from intertidal mudflats of the main estuarine channel and adjoining sub-channel from Vaghotan Estuary, West Coast of India, were studied to understand the depositional environment, sources and enrichment of metals and their toxicity. Sediment components and metal associations suggest that main channel and sub-channel sediment properties varied owing to differential sediment supply and processes. The sub-channel sediments tend to accumulate higher metal concentrations facilitated by sheltered and calm sedimentary environment. Main channel sediments, however, are subjected to relatively higher energy conditions due to tidal flushing which caused re-suspension and transfer of finer sediments to places of less energy environments retaining higher coarser sediments. Results also showed that the metals in lower sections of the two cores were mainly from a lithogenic source whereas the upper sections indicated an anthropogenic influence in recent times. Pollution indices indicated contamination of sediments by metal in recent times due to enhanced human induced activities in the catchment area and concentration of Co in the mudflat sediments pose a higher risk to biota in sub-channel mudflats than the main channel.

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References

  • Achyuthan H, Richardmohan D (2002) Trace metals concentrations in the sediment cores of estuary and tidal zones between Chennai and Pondicherry, along the east coast of India. Indian J Mar Sci 31:141–149

    Google Scholar 

  • Algeo TJ, Maynard JB (2004) Trace-element behavior and redox facies in core shales of Upper Pennsylvanian Kansas-type cyclothems. Chem Geol 206:289–318

    Article  Google Scholar 

  • Amos CL (1995) Siliciclastic tidal flats. In: Perillo GM (ed.), Geomorphology and sedimentology of estuaries. Developments in sedimentology. Elsevier, New York, pp 273–306

  • Bentivegna C, Alfano J, Bugel S, Czechowicz K (2004) Influence of sediment characteristics of heavy metals to toxicity in an urban marsh. Urban Habitat Electron J Biol Urban Areas Around World 2:22–24

    Google Scholar 

  • Borole DV, Sarin MM, Somayajulu BL (1982) Composition of Narmada and Tapti estuarine particulates and adjacent Arabian Sea sediments. Indian J Mar Sci 11:57–62

    Google Scholar 

  • Breit GN, Wanty RB (1991) Vanadium accumulation in carbonaceous rocks: a review of geochemical controls during deposition and diagenesis. Chem Geol 91:83–97

    Article  Google Scholar 

  • Breslin V, Sanudo-Wilhelmy S (1999) High spatial resolution sampling of metals in sediment and water column in Port Jefferson Harbour, New York. Estuaries 22:669–680

    Article  Google Scholar 

  • Buchman MF (1999) NOAA screening quick reference tables. NOAA HAZMAT report 99–111, Coastal Protection and Restoration Division, National Oceanic and Atmospheric administration, Seattle, WA, p 12

  • Burba P, Rocha J, Klockow D (1994) Labile complexes of trace metals in aquatic humic substances: investigations by means of ion exchange-based flow procedure. Fresen J Anal Chem 349:800–807

    Article  Google Scholar 

  • Carpenter R, Peterson ML, Bennet JT, Somayajulu BL (1984) Mixing and cycling of uranium, thorium and 210Pb in Puget Sound sediments. Geochim Cosmochim Acta 48:1949–1963

    Article  Google Scholar 

  • Cronan DS (1980) Underwater minerals, (Academic Press London,) p 362

  • Cynthia L, Fianko JR, Akiti TT, Osei J, Brimah AK, Osae S, Bam EK (2011) Determination of Trace Elements in the Sakumo Wetland Sediments. Res J Environ Earth Sci 3:417–421

    Google Scholar 

  • Dalai TK, Rengarajan R, Patel PP (2004) Sediment geochemistry of the Yamuna River System in the Himalaya: implications to weathering and transport. Geochem J 38:441–453

    Article  Google Scholar 

  • Fernandes L, Nayak GN (2009) Distribution of sediment parameters and depositional environment of Mudflats of Mandovi Estuary, Goa, India. J Coastl Res 25:273–284

    Article  Google Scholar 

  • Fernandes L, Nayak GN (2012) Heavy metals contamination in mudflat and mangrove sediments (Mumbai, India). Chem Ecol 28:435–455

    Article  Google Scholar 

  • Fernandes MC, Nayak GN, Pande A, Volvoikar SP, Dessai DRG (2014) Depositional environment of mudflats and mangroves and bioavailability of selected metals within mudflats in a tropical estuary. Environ Earth Sci. doi:10.1007/s12665-014-3095-y

    Google Scholar 

  • Flegal AR, Schaule BK, Patterson CC (1984) Stable isotopic ratios of lead in surface waters of the central Pacific. Mar Chem 14:281–287

    Article  Google Scholar 

  • Folk RL (1974) In petrology of sedimentary rocks. Hemphill, Austin, p 182

    Google Scholar 

  • Francois R (1988) A study on the regulation of the concentrations of some trace metals (Rb, Sr, Zn, Pb, Cu, V, Cr, Ni, Mn and Mo) in Saanich Inlet sediments, British Columbia, Canada. Mar Geol 83:285–308

    Article  Google Scholar 

  • Gohil R, Parmar D, Pandya J (2009) Heavy metal availability in relation to soil characteristics in some mud flat of Salicornia growing at coast of Gujarat. Agric Sci Dig 29:48–50

    Google Scholar 

  • Grecco LE, Marcos AO, Gómez EA, Botté S, Marcovecchio J (2004) Natural and anthropogenic input of heavy metals in sediments from Bahía Blanca estuary (Argentina). J Coastal Res 39:1021–1025

    Google Scholar 

  • Gujar AR (1996) Heavy mineral placers in the nearhore areas of South Konkan Maharashtra; their nature of distribution, origin and economic evaluation. Thanjavur India: Ph.D. Thesis, Tamil University

  • Gujar AR, Rajamanickam GV, Wagle B (2000) Shoreline configuration control on the concentration of near shore heavy minerals: a case study from Konkan Maharashtra, Central west coast of India. Proc Int Quat. Seminar on INQUA shoreline, Indian Ocean Sub Commission, pp 140–147

  • Gujar AR, Borole D, Parthiban G, Rajamanickam GV (2005) Pb210 Geochronology in changing coastal environment: a case study of Vijaydurg, central west coast of India. 7th Marine Archeology Seminar at NIO, 17

  • Gujar AR, Angusamy N, Rajamanickam GV (2008) Wave refraction patterns and their role in sediment redistribution along South Konkan, Maharashtra. India. GeoActa 7:69–79

    Google Scholar 

  • Ho HH, Swennen R, Damme AV (2010) Distribution and contamination status of heavy metals in estuarine sediments near Cua Ong Harbor, Ha Long Bay, Vietnam. Geol Belgica 13:37–47

    Google Scholar 

  • Hornberger MI, Luoma SN, Van Geen A, Fuller C, Anima R (1999) Historical trends of metals in the sediments of San Franciso Bay, California. Mar Chem 64:39–55

    Article  Google Scholar 

  • Idris AM, Eltayeb MAH, Potgieter-Vermaak SS, Van Grieken R, Potgieter JH (2007) Assessment of heavy metals pollution in Sudanese harbours along the Red Sea Coast. Microchem J 87:104–112

    Article  Google Scholar 

  • Jarvis IJ, Jarvis K (1985) Rare earth element geochemistry of standard sediments: a study using inductively coupled plasma spectrometry. Chem Geol 53:335–344

    Article  Google Scholar 

  • Liaghati T, Preda M, Cox M (2003) Heavy metal distribution and controlling factors within coastal plain sediments, Bells creek Catchment, Southeast Queensland, Australia. Environ Int 29:935–948

    Article  Google Scholar 

  • Liu YF, Han MK, Wu L, Mimura N (1998) Recent evolution of outlets in Zhujiang River delta and the prospect for land reclamation. Acta Geogr Sin 53:492–500

    Google Scholar 

  • Liu B, Hu K, Jiang Z, Yang J, Luo X, Liu A (2011) Distribution and enrichment of heavy metals in a sediment core from the Pearl River Estuary. Environ Earth Sci 62:265–275

    Article  Google Scholar 

  • Majeed HN, Pawar RS, Panaskar DB (2012) Assessment of heavy metals in sediments from coastal Al-Hodiedah Governorate, Yemen. Univ J Environ Res Technol 2:168–173

    Google Scholar 

  • Mohan PM (2000) Sediment transport mechanism in the Vellar estuary, east coast of India. Indian J Mar Sci 29:27–31

    Google Scholar 

  • Muller G (1979) Schwermetalle in den Sedimentation des Rheins–Ver-anderungen seit 1971. Umschau 79:778–783

    Google Scholar 

  • Mwamba MJ, Torres R (2002) Rainfall effects on marsh sedi-ment redistribution, North Inlet, South Carolina, USA. Mar Geol 189:267–287

    Article  Google Scholar 

  • Nyangababo JT, Henry I, Omutunge E (2005) Heavy metal contamination in plants, sediments and air precipitation of Katonga, Simiyu and Nyando wetlands of Lake Victoria Basin, East Africa. Bull Environ Contam Toxicol 75:189–196

    Article  Google Scholar 

  • Pande A, Nayak GN (2013) Understanding distribution and abundance of metals with space and time in estuarine mudflat sedimentary environment. Environ Earth Sci. doi:10.007/s12665-013-2298-y

    Google Scholar 

  • Patterson CC, Settle DM (1987) Review of data on eolian fluxes of industrial and natural lead to the lands and seas in remote regions on a global scale. Mar Chem 22:137–162

    Article  Google Scholar 

  • Paul SK (2001) Geochemistry of bottom sediments from a river-estuary-shelf mixing zone on the tropical southwest coast of India. Bull Geol Surv Jpn 52:371–382

    Article  Google Scholar 

  • Pejrup M (1988) The triangular diagram used for classification of estuarine sediments: a new approach. In: deBoer PL, van Gelder A, Nio SD (Eds.), Tide-influenced Sedimentary Environments and Facies. Dordrecht: D. Reidel Publishing Company. pp 289–300

  • Perin G, Craboledda L, Lucchese M, Cirillo R, Dotta L, Zanetta ML et al. (1985). Heavy metal speciation in the sediments of Northern Adriatic Sea. A new approach for environmental toxicity determination. In: Heavy Metals in the Environment (Lakkas T D, ed). CEP Consultants Edinburg

  • Peterson ML, Carpenter R (1986) Arsenic distributions in porewaters and sediments of Puget Sound, Lake Washington, the Washington coast and Saanich Inlet, B.C. Geochim Cosmochim Acta 50:353–369

    Article  Google Scholar 

  • Pilditch CA, Widdows J, Kuhn NJ, Pope ND, Brins-ley MD (2008) Effects of low tide rainfall on the erodibility of inter-tidal cohesive sediment. Cont Shelf Res 28:1854–1865

    Article  Google Scholar 

  • Qi S, Leipe T, Rueckert P, Di Z, Harff J (2010) Geochemical sources, deposition and enrichment of heavy metals in short sediment cores from the Pearl River Estuary, Southern China. J Mar Syst 82:S28–S42

    Article  Google Scholar 

  • Rubio B, Nombela MA, Vilas F (2000) Geochemistry of major and trace elements in Sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution. Mar Pollut Bull 40:968–980

    Article  Google Scholar 

  • Schaule BK, Patterson CC (1981) Lead concentrations in the northeast Pacific: evidence for global anthropogenic perturbations. Earth Planet Sci Lett 54:97–116

    Article  Google Scholar 

  • Settle DM, Patterson CC (1982) Magnitudes and sources of precipitation and dry deposition fluxes of industrial and natural leads to the North Pacific at Enewetak. J Geophys Res 87:8857–8869

    Article  Google Scholar 

  • Shi Z (1992) Application of the ‘Pejrup Approach’ for the Classification of the Sediments in the Microtidal Dyfi Estuary, West Wales, UK. J Coast Res 8:482–491

    Google Scholar 

  • Sholkovitz ER (1976) Flocculation of dissolved organic and inorganic matter during the mixing of river water and sea water. Geochim Cosmochim Acta 40:831–845

    Article  Google Scholar 

  • Shrader EL Jr, Rule JH, Furbish WJ (1977) Trace metal geochemistry of a fluvial system in eastern Tennessee affected by coal mining. South east Geol 18:157–172

    Google Scholar 

  • Singh KT, Nayak GN (2009) Sedimentary and geochemical signatures of depositional environment of sediments in mudflats from a microtidal Kalinadi Estuary, central west coast of India. J Coast Res 25:641–650

    Article  Google Scholar 

  • Singh M, Muller G, Singh I (2002) Heavy metals in freshly deposited stream sediments of rivers associated with urbanization of the Ganga plain, India. Water Air Soil Pollut 141:35–54

    Article  Google Scholar 

  • Siraswar R, Nayak GN (2011) Mudflats in the lower middle estuary as a favourable location for concentartion of metals, West coast of India. Indian J Mar Sci 40:372–385

    Google Scholar 

  • Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51(7):844–851

    Article  Google Scholar 

  • Tolhurst TJ, Defew EC, de Brouwer JFC, Wolfstein K, Stal LJ, Paterson DM (2006) Small-scale temporal and spatial variability in the erosion threshold and properties of cohesive intertidal sediments. Cont Shelf Res 26:351–362

    Article  Google Scholar 

  • Tomlinson DL, Wilson JG, Harris CR, Jeffney DW (1980) Problems in the assessment of heavy metal levels in estuaries and the formation of a pollution index, Helgol. Wiss. Meeresunters 33:566–572

    Article  Google Scholar 

  • Torres R, Goni MA, Voulgaris G, Lovell CR, Morris JT (2004) Effects of low tide rainfall on intertidal zone material cycling. In: Fagherazzi S, Marani M, Blum KL (Eds.) The ecogeomorphology of tidal marshes, coastal and estuarine studies. American Geophysical Union, pp 93–114

  • Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. The geological society of america. 175–191

  • Volvoikar SP, Nayak GN (2013) Depositional environment and geochemical response of mangrove sediments from creeks of northern Maharashtra coast, India. Mar Pollut Bull 69:223–227

    Article  Google Scholar 

  • Volvoikar SP, Nayak GN (2014) Factors controlling the distribution of Metals in Intertidal mudlat sedimetns of Vaitarna estuary North Maharashtra coast India. Arab J Geosci. doi:10.1007/s12517-013-1162-4

    Google Scholar 

  • Walkey A, Black IA (1934) An examination of the degtjareff method for the determining organic matter and a proposed modification of the chromic acid titration method. Soil Sci 37:29–38

    Article  Google Scholar 

  • Wood AKH, Ahmad Z, Shazili NAM, Yaakob R, Carpenter R (2004) Metal diagenesis and transport in coastal sediments around Penang island. Malays J Nucl Rel Technol 1:1–22

    Google Scholar 

Download references

Acknowledgments

This investigation was carried out as a part of research project entitled “Reading pollution history, Paleoclimate and sea level changes from the study of mudflats, Central West Coast of India” funded by Ministry of Earth Sciences, Government of India, New Delhi, to the first author (P. I.). The authors acknowledge the support of the ministry. The authors are also grateful to the India Meteorological Department for supplying the annual rainfall data.

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Correspondence to Cheryl A. Noronha-D’Mello.

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Nayak, G.N., Noronha-D’Mello, C.A., Pande, A. et al. Understanding sedimentary depositional environments through geochemical signatures of a Tropical (Vaghotan) estuary, West Coast of India. Environ Earth Sci 75, 111 (2016). https://doi.org/10.1007/s12665-015-4842-4

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