Abstract
We synthesized mesoporous SiO2 nanomatrix using rice husks as a precursor through a facile thermal combustion process. XRD, FTIR, EDX, and TEM analyses were used to validate the produced mesoporous SiO2 nanomatrix. Electrochemical measurements were used to determine the specific capacitance of mesoporous SiO2 nanomatrix, and the results showed that the specific capacitances are 216, 204, 182, 163, 152, 142, 135, 133, 124.4, 124 F/g at current densities of 0.5, 1, 2, 4, 6, 8, 10, 12, 14, and 16 A/g. The benefit of impurities, as well as the large surface area and mesoporous structure of rice husk derived SiO2 nanostructures, allow Faradaic redox reactions at the electrode surface and the resulting supercapacitive behavior. This research might lead to a low-cost technique of producing supercapacitor electrodes using rice husk-derived SiO2 as a precursor.
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References
Khan I, Saeed K, Khan I (2019) Nanoparticles: properties, applications and toxicities. Arab J Chem 12:908–931
Baig N, Kammakakam I, Falath W (2021) Nanomaterials: a review of synthesis methods, properties, recent progress, and challenges. Mater Adv 2:1821–1187
Abid N, Khan AM, Shujait S, Chaudhary K, Ikram M, Imran M, Haider J, Khan M, Khan Q, Maqbool M (2022) Synthesis of nanomaterials using various top-down and bottom-up approaches, influencing factors, advantages, and disadvantages: a review. Adv Colloid Inter Sci 300:102597
Bayda S, Adeel M, Tuccinardi T, Cordani M, Rizzolio F (2019) The history of nanoscience and nanotechnology: from chemical–physical applications to nanomedicine. Molecules. 25:112
Meier J, Schiotz J, Liu P, Norskov JK, Stimming U (2004) Nano-scale effects in electrochemistry. Chem Phys Lett 390:440–444
Eftekhari A (2008) Nanostructured materials in electrochemistry. Wiley-VCH GmbH, Weinheim
Erdemir F, Güler O, Çanakçı A (2021) Electroless nickel-phosphorus coated expanded graphite paper: binder-free, ultra-thin, and low-cost electrodes for high-performance supercapacitors. J Energy Storage 44:103364
Rashidi S, Karimi N, Sunden B, Kim KC, Olabi AG, Mahian O (2022) Progress and challenges on the thermal management of electrochemical energy conversion and storage technologies: fuel cells, electrolysers, and supercapacitors. Prog Energy Combust Sci 88:100966
Luo X, Morrin A, Killard A, Smyth M (2006) Application of nanoparticles in electrochemical sensors and biosensors. Electroanalysis 18:319–326
Lu H, He B, Gao B (2021) Emerging electrochemical sensors for life healthcare. Eng Regen 2:175–181
Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Kluwer-Plenum, New York
Raza W, Ali F, Raza N, Luo Y, Kim K, Yang J, Kumar S, Mehmood A, Kwon EE (2018) Recent advancements in supercapacitor technology. Nano Energy 52:441–473
Aricò AS, Bruce P, Scrosati B, Tarascon JM, Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nature Mater 4:366–377
Erdemir F, Tuzcu E, Bilgin S, Alver Ü, Çanakçı A (2021) Influence of fluorine doping of zinc oxide on its electrochemical performance in supercapacitors. Mater Chem Phy 259:124033
Sajjad M (2021) Recent advances in SiO2 based composite electrodes for supercapacitor applications. J Inorg Organomet Polym 31:3221–3239 ISSN 0254-0584
Prabha S, Durgalakshmi D, Rajendran S, Lichtfouse E (2021) Plant-derived silica nanoparticles and composites for biosensors, bioimaging, drug delivery and supercapacitors: a review. Environ Chem Lett 19:1667–1691
Laskowski Ł, Laskowska M, Vila N, Schabikowski M, Walcarius A (2019) Mesoporous silica-based materials for electronics-oriented applications. Molecules 24:2395
Vijayan R, Kumar GS, Karunakaran G, Surumbarkuzhali N, Prabhu S, Ramesh R (2020) Microwave combustion synthesis of tin oxide-decorated silica nanostructure using rice husk template for supercapacitor applications. J Mater Sci Mater Electron 31:5738–5745
Ali GAM, Fouad OA, Makhlouf SA, Yusoff MM, Chong KF (2014) Co3O4/SiO2 nanocomposites for supercapacitor application. J Solid State Electrochem 18:2505–2512
Huang HS, Chang KH, Suzuki N, Yamauchi Y, Hu CC, Wu KCW (2013) Evaporation-induced coating of hydrous ruthenium oxide on mesoporous silica nanoparticles to develop high-performance supercapacitors. Small 9:2520–2526
Joshi A, Lalwani S, Singh G, Sharma RK (2019) Highly oxygen deficient, bimodal mesoporous silica based supercapacitor with enhanced charge storage characteristics. Electrochim Acta 297:705–714
Vijayan R, Srinivasan R, Kumar GS, Surumbarkuzhali N, Prabhu S, Ramesh R, Karunakaran G, Kolesnikov E, Kim M (2021) Synthesis of silver-integrated silica nanostructures using rice hulls and their electrochemical performance for supercapacitor application. J Mater Sci Mater Electron 32:17534–17544
Pal A, Das T, Ghosh S, Nandi M (2020) Supercapacitor behaviour of manganese dioxide decorated mesoporous silica synthesized by rapid sol-gel inverse micelle method. Dalton Trans 49:12716–12730
Zhang Y, Zhao Y, Cao S, Yin Z, Cheng L, Wu L (2017) Design and synthesis of hierarchical SiO2@C/TiO2 hollow spheres for high-performance supercapacitors. ACS Appl Mater Interfaces 9:29982–29991
Javed M, Abbas SM, Siddiq M, Han D, Niu L (2018) Mesoporous silica wrapped with graphene oxide-conducting PANI nanowires as a novel hybrid electrode for supercapacitor. J Phys Chem Solids 113:220–228
Cevik E, Gunday ST, Akhtar S, Yamani ZH, Bozkurt A (2019) Sulfonated hollow silica spheres as electrolyte store/release agents: high-performance supercapacitor applications. Energy Technol 7:1900511
Bodie AR, Micciche AC, Atungulu GG, Rothrock MJ, Ricke SC (2019) Current trends of rice milling byproducts for agricultural applications and alternative food production systems. Front Sustain Food Syst 3:47
Elkodous A et al (2021) Recent advances in waste-recycled nanomaterials for biomedical applications: waste-to-wealth. Nanotechnol Rev 10:1662–1739
Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319
Barrett EP, Joyner LG, Halenda PA (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380
Erdemir F (2017) Study on particle size and X-ray peak area ratios in high energy ball milling and optimization of the milling parameters using response surface method. Measurement 112:53–60
Ibrahim DM, El-Hemaly SA, Abdel-Kerim FM (1980) Study of rice-husk ash silica by infrared spectroscopy. Thermochim Acta 37:307–314
Soltani N, Bahrami A, Pech-Canul MI, González LA (2015) Review on the physicochemical treatments of rice husk for production of advanced materials. Chem Eng J 264:899–935
Yalcin N, Sevinc V (2001) Studies on silica obtained from rice husk. Ceram Int 27:219–224
Araichimani P, Kumar GS, Prabu KM, Karunakaran G, Minh NV, Kolesnikov E, Gorshenkov MV (2021) Amorphous silica nanoparticles derived from biowaste via microwave combustion for drug delivery. Int J Appl Ceram Technol 18:583-589
Acknowledgements
G. Suresh Kumar would like to express his heartfelt gratitude to the management of K.S. Rangasamy College of Arts and Science (Autonomous), Tiruchengode for their continuous support. P. Araichimani and K.M. Prabu are grateful for the continuous support and encouragement from the management of Sri Vidya Mandir Arts and Science College, Uthangarai, for performing this research.
Funding
The authors from King Khalid University would like to express their gratitude to the Deanship of Scientific Research at King Khalid University, Abha, Saudi Arabia for funding this work through the Research Groups Program under Grant No. R.G.P.1/397/42.
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P. Araichimani: Conceptualization, Investigation, Methodology, Writing - Original Draft. K.M. Prabu: Supervision. G. Suresh Kumar: Validation, Writing-Review & Editing. Gopalu Karunakaran: Visualization, Formal analysis. S. Surendhiran: Characterization of materials. Mohd. Shkir: Characterization of materials, Review & Editing, S. AlFaify: Characterization of material.
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Araichimani, P., Prabu, K.M., Kumar, G.S. et al. Rice Husk-Derived Mesoporous Silica Nanostructure for Supercapacitors Application: a Possible Approach for Recycling Bio-Waste into a Value-Added Product. Silicon 14, 10129–10135 (2022). https://doi.org/10.1007/s12633-022-01699-3
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DOI: https://doi.org/10.1007/s12633-022-01699-3