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Effect of Silicon Separation on the Preparation of High-Purity Aluminum

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Abstract

To evaluate the effect of the distribution coefficient (kSi) on silicon (Si) separation during aluminum (Al) refining by zone melting, kSi is measured under different experimental conditions, and the obtained samples are examined. The experimental results show that Si content in the sample located in the middle region is less than 2.33 ppm (Its location number is No. 3) when the zone melting speed is less than 1 mm/min. As the times of purification increasing, kSi gradually approaches k0, and the migration effect of Si is significantly improved. The influence of the times of purification on the distribution coefficient is obviously greater than that of the zone melting speed. When the zone melting speed is 1 mm/min, and there are 10 and 15 times, the highest removal rate of Si occurs in the middle of the sample. The Si removal rates in the samples at No. 3 are 74% and 74.6%, respectively.

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References

  1. Matsubara H, Izawa N, Nakanishi M (1998) Macroscpic segregation in Al-11mass% Si alloy containing 2 mass% Fe solidified under centrifugal force. J Jpn Inst Light Met 48(2):93–97

    Article  CAS  Google Scholar 

  2. Zhang LF, Lv XW, Torgerson AT, Long MJ (2011) Removal of impurity elements from molten aluminum: a review. Miner Process Extr Metall Rev 32:150–228

    Article  CAS  Google Scholar 

  3. Jeffvey BP, Nicholas JG, Zhou JH (1998) Microstructure and properties of 7150 aluminum alloy containing iron and silicon. Shanghai steel research co. LTD 5, pp 35

  4. Ohira T, Kishi T (1986) Effect of Iron content on fracture toughness and cracking processes in high strength Al-Zn-mg-cu alloy. Mater Sci Eng 78:9–10

    Article  CAS  Google Scholar 

  5. Wang PC, Ai LQ, Li YG, Sang XM, Bu JL (2011) Research advance in harmful effects and removal of impurity Fe from Al and Al Alloys. Adv Mater 295–297:751–759

    Google Scholar 

  6. Kondo M, Maeda H, Mizuguchi M (1990) The production of high-purity aluminum in Japan. JOM 42:36–37

    Article  CAS  Google Scholar 

  7. Hashimoto E, Ueda Y, Kino T (1995) Purification of ultra-high purity aluminum. J Phys IV 5:153–157

    Google Scholar 

  8. Ding Z, Li H, Shaw L (2020) New insights into the solid-state hydrogen storage of nanostructured LiBH4-MgH2 System. Chem Eng J 385:123856

    Article  CAS  Google Scholar 

  9. Zhu GL, Shu D, Wang J (2008) B.D Sun. research advance in removal on impurity Si from molten Al and Al alloys. Material Rev 22:61–64

    Google Scholar 

  10. Dong AP, Shu D, Wang J, Cai XC, Sun BD (2007) Separation of Zinc dross from hot dip galvanizing melt by using alternating magnetic field. J Shanghai Jiaotong Univ 41:1614

    Google Scholar 

  11. Ding Z, Wu PK, Shaw L (2019) Solid-state hydrogen desorption of 2 MgH2 + LiBH4 nano -mixture: a kinetics mechanism study. J Alloy Compd 806:350–360

    Article  CAS  Google Scholar 

  12. Ding Z, Shaw L (2019) Enhancement of hydrogen desorption from nano-composite prepared by ball-milling MgH2 with in-situ Aerosol-Spraying LiBH4. ACS Sustain Chem Eng 7:15064–15072

    Article  CAS  Google Scholar 

  13. Ding Z, Lu Y, Li L, Shaw L (2019) High reversible capacity hydrogen storage through Nano- LiBH4+ Nano-MgH2 system. Energy Storage Mater 20:24–35

    Article  Google Scholar 

  14. Yang YS, Zhang QS, He YL, Hu Z (2001) The segregation of copper and silicon in Al-Si-cu alloy during eletromagnetic centrifugal solidification. Sci Technol Adv Mater 2:271

    Article  CAS  Google Scholar 

  15. Nagao M, Oosumi K, Nakamura T (1996) Removal of impurity silicon from molten aluminum alloy with compound method. J Jpn Inst Light Metals 11:588

    Article  Google Scholar 

  16. Wu YY, Liu XF, Bian XF (2007) Effect of boron on the microstructure of near-eutectic Al-Si alloys. Mater Charact 58:205

    Article  CAS  Google Scholar 

  17. Han YF, Shu D, Wang J, Sun BD (2006) Microstructure and grain refining performance of Al-5Ti-1B master alloy prepared under high-intensity ultransound. Mater Sci Eng A 430:326

    Article  Google Scholar 

  18. Grobner J, Mirkovic D, Schmid-Fetzer R (2005) Thermodynarmic aspects of grain refinement of Al-Si alloys using Ti and B. Mater Sci Eng A 395:10

    Article  Google Scholar 

  19. Spim JA, Bernadou MJ, Garcia A (2000) Numerical modeling and optimization of zone refining. J Alloys Compd 298:299–305

    Article  CAS  Google Scholar 

  20. Cheung N, Bertazzoli R, Garcia A (2007) Numberial and experimental analysis of an approach based on variable solute distribution coefficients during purification by zone refining. Sep Purif Technol 52:504–511

    Article  CAS  Google Scholar 

  21. Chi DH, Ho MY, Tzuoo LY (1999) The optimal variation of zone lengths in multipass zone refining process. Sep Purif Technol 15:69–78

    Article  Google Scholar 

  22. Ghosh K, Mani VN, Dhar S (2009) Numerical study and experimental investigation of zone refining in ultra-high purification of gallium and its use in the growth of GaAs epitaxial layers. J Cryst Growth 311:1521–1528

    Article  CAS  Google Scholar 

  23. Su CH, Sha YG (1998) Segregation coefficients of impurities in selenium by zone refining. J Cryst Growth 87:569–572

    Article  Google Scholar 

  24. Chen NK, Liu MZ (1957) Some experiments on purification of aluminium and tin by zone smelting. Acta Metall Sin 2:163–170

    CAS  Google Scholar 

  25. Ali ST, Reddy RC, Munirathnam NR, Sudheer C, Anil G, Prakash TL (2006) A novel in-situtechnique of ultra-purification of cadmium for electronic applications. Sep Purif Technol 52:288–294

    Article  CAS  Google Scholar 

  26. Zaiour A, Zahraman K, Roumie M, Charara J, Fawaz A, Lmai F, Hage-Ali M (2006) Purification of tellurium to nearly 7N purity. Mater Sci Eng B 131:54–61

    Article  CAS  Google Scholar 

  27. Nakamura M, Watanabe M, Tanaka K (2014) Zone refining of aluminum and its simulation. Mater Trans 55:664–670

    Article  CAS  Google Scholar 

  28. Cheung N, Bertazzoli R, Garcia A (2008) Experimental impurity segregation and numerical analysis based on variable solute distribution coefficients during multi-pass zone refining of aluminum. J Cryst Growth 310:1274–1280

    Article  CAS  Google Scholar 

  29. Gao SL, Zeng P, Cui J, Liu G, Shang GY, Liu J, Zhai XS, He XG, Song YP China nonferrous metal industry standards: YS/T 275-2008

  30. Pfann WG (1952) Principles of zone melting. TMS 4:747–753

    CAS  Google Scholar 

  31. Mondolford LF (1976) Aluminum alloy: structure and properties. Butterworths, London

    Google Scholar 

  32. Kim P, Mihara Y, Ozawa E, Ozawa Y, Hayashi C (2000) High purity metal production using dry refing process. Mater Trans JIM 41:37–43

    Article  CAS  Google Scholar 

  33. Pfann WG (1966) Zone Melting2nd edn. Wiley, New York

    Google Scholar 

  34. Zhang XX, Friedrich S, Friedrich B (2018) Production of high purity metals: a review on zone refining process. J Cryst Process Technol 8:33–55

    Article  Google Scholar 

  35. Schober HR (2016) Heterogeneous diffusion, viscosity, and the stokes-Einstein relation in binary liquids. Phys Rev E 93:1–12

    Article  Google Scholar 

  36. Charbonneau B, Charbonneau P, Szamel G (2018) A microscopic model of the stokes-Einstein relation in arbitrary dimension. J Chem Phys 148:1–15

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by National Science Foundation of China (No. 51734006), Science and Technological Talent Cultivation Plan of Yunnan Province, China (No.2017HB009), Supported by Program for Innovative Research Team in University of Yunnan Province (No.201808), the Program for the academician free exploration fund of Yunnan Province (No. 2017HA006), the Science and Technology Planning Project of Yunnan Province (No. 2019FD037).

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Correspondence to Yifu Li.

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Wan, H., Xu, B., Yang, B. et al. Effect of Silicon Separation on the Preparation of High-Purity Aluminum. Silicon 13, 399–407 (2021). https://doi.org/10.1007/s12633-020-00443-z

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