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Weatherability and heat resistance enhanced by interaction between AG25 and Mg/Al-LDH

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Abstract

Although inorganic pigments in common spectral tuning materials show good weatherability and heat resistance, the limited color choices, weak coloring power, poor dispersibility, and a possibility of toxicity limit their development. On the basis of organic pigments which possess a wide range of colors, high coloring power, good transparency, and high safety, herein, the modified pigment and biomimetic coating with improved weatherability, especially ultraviolet (UV) resistance (from 2 to 6 days), was achieved by intercalating acid green 25 (AG25) pigment into Mg/Al-layered double hydroxides (Mg/Al-LDH). Furthermore, the heat resistance of AG25 was also significantly increased. Moreover, the spectral stability of pigments after heat treatment is superior with almost unchanged spectral profile and green reflection peak. The formation of strong N–H bonds and the S–M (Mg, Al) bonds between Mg/Al-LDH laminates and AG25 molecules contributes to the improvement. This work shows potential for biomimetic leaf materials in respect of reflective spectra stability.

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摘要

尽管一般的光谱调控材料中的无机颜料表现出良好的耐候性和耐热性，但其颜色选择有限、着色能力弱、分散性差以及可能存在毒性等性质限制了其发展。在有机颜料具有广泛的颜色选择范围、高着色能力、好的透明度和高安全性的基础上，通过将酸性绿25（AG25）颜料插层进入Mg/Al水滑石（Mg/Al-LDH）中，获得了具有改善的耐候性，特别是抗紫外老化能力（从2天到6天）的改性颜料和仿生涂层。此外，AG25的耐热性也显著提高。另外，热处理后的颜料的光谱稳定性优异，光谱轮廓和绿色反射峰几乎不变。Mg/Al-LDH层板和AG25分子之间形成强的N-H键和S-M（Mg，Al）键有助于提高性能。这项工作对仿生叶片材料在提高反射光谱稳定性方面展现出广阔的应用前景。

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Acknowledgements

This study was financially supported by the External Collaboration Fund (No. XM2022FH5079).

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Author notes

  1. Pei-Yao Yang and Xiang-Cui Liu have contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory of Powder Metallurgy, Powder Metallurgy Research Institute, Central South University, Changsha, 410083, China

    Pei-Yao Yang, Yu-Chao Wang, Huan-Ran Zheng, Jin-Xian Wang, Meng-Jie Liu, Dan-Ni Deng, Yu Bai, Ying-Bi Chen & Yong-Peng Lei

  2. Research Institute of Chemical Defense, Beijing, 102205, China

    Xiang-Cui Liu, Jia-Yi Zheng, Tong Zhang & Zhi-Ming Liu

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  1. Pei-Yao Yang
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Yang, PY., Liu, XC., Wang, YC. et al. Weatherability and heat resistance enhanced by interaction between AG25 and Mg/Al-LDH. Rare Met. 43, 2758–2768 (2024). https://doi.org/10.1007/s12598-023-02605-5

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