Graphical abstract
摘要
探究材料维度与超导电性之间的物理关联已经引起了大量的研究兴趣。在本工作中,我们报告了利用维度实现对层状材料GeP5的超导电性的有效调制。随着GeP5的厚度从块体减薄到~96 nm时,其超导相变温度提高了~10%,表现出超导相变温度与厚度之间奇特的负相关特性。这种奇特的负相关特性被认为源于GeP5中各种量子序之间复杂的关联耦合作用,包括较薄的GeP5材料中被抑制的电荷密度波以及增强的电子-声子耦合作用等。我们研究成果为利用维度限域作用调制材料的超导电性提供了一个新的材料与物理基础。
References
Shi XB, He P, Zhao WW. Dual topology in van der Waals-type superconductor Nb2S2C. Tungsten. 2023;5(3):357. https://doi.org/10.1007/s42864-022-00135-8.
Guan DD, Wang DL, Ma YW. Progress of research on properties and applications of MgB2 fabricated by internal Mg diffusion method. Chin J Rare Met. 2022;46(4):497. https://doi.org/10.13373/j.cnki.cjrm.XY20040031.
Shao DF, Lu WJ, Lv HY, Sun YP. Electron-doped phosphorene: a potential monolayer superconductor. EPL. 2014;108(6):67004. https://doi.org/10.1209/0295-5075/108/67004.
Ge JF, Liu ZL, Liu CH, Gao CL, Qian D, Xue QK, Liu Y, Jia JF. Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3. Nat Mater. 2015;14(3):285. https://doi.org/10.1038/nmat4153.
Wang N, Huang CY, Zhang Y, Zhu HM. Preparation of Nb3Al powder by chemical reaction in molten salts. Rare Met. 2022;41:1671. https://doi.org/10.1007/s12598-015-0523-4.
Sipos B, Kusmartseva AF, Akrap A, Berger H, Forró L, Tutiš E. From Mott state to superconductivity in 1T-TaS2. Nat Mater. 2008;7(12):960. https://doi.org/10.1038/nmat2318.
Wilson JA, Di Salvo FJ, Mahajan S. Charge-density waves and superlattices in the metallic layered transition metal dichalcogenides. Adv Phys. 1975;24(2):117. https://doi.org/10.1080/00018737500101391.
Zheng FP, Feng J. Electron-phonon coupling and the coexistence of superconductivity and charge-density wave in monolayer NbSe2. Phys Rev B. 2019;99(16): 161119. https://doi.org/10.1103/PhysRevB.99.161119.
Lian CS, Heil C, Liu XY, Si C, Giustino F, Duan WH. Coexistence of superconductivity with enhanced charge density wave order in the two-dimensional limit of TaSe2. J Phys Chem Lett. 2019;10(14):4076. https://doi.org/10.1021/acs.jpclett.9b01480.
Nakata Y, Sugawara K, Shimizu R, Okada Y, Han P, Hitosugi T, Ueno K, Sato T, Takahashi T. Monolayer 1T-NbSe2 as a Mott insulator. NPG Asia Mater. 2016;8(11): e321. https://doi.org/10.1038/am.2016.157.
Qin SY, Kim J, Niu Q, Shih CK. Superconductivity at the two-dimensional limit. Science. 2009;324(5932):1314. https://doi.org/10.1126/science.1170775.
Zhu MC, Chen D, Zhu AK, Wu YL, Han ML, Han YY, Zheng GL, Gao WS, Tian ML. Thickness dependence of quantum transport in the topological superconductor candidate SnTaS2. Appl Phys Lett. 2022;120(5): 053102. https://doi.org/10.1063/5.0080851.
Li HJ, Wang HH, Gao WS, Chen Z, Han YY, Zhu XD, Tian ML. Thickness dependence of superconductivity in layered topological superconductor β-PdBi2. Nanomaterials. 2021;11(11):2826. https://doi.org/10.3390/nano11112826.
Bodepudi SC, Wang X, Singh AP, Pramanik S. Thickness dependent interlayer magnetoresistance in multilayer graphene stacks. J Nanomater. 2016;2016:1. https://doi.org/10.1155/2016/8163742.
Bekaert J, Khestanova E, Hopkinson DG, Birkbeck J, Clark N, Zhu MJ, Bandurin DA, Gorbachev R, Fairclough S, Zou YC, Hamer M, Terry DJ, Peters JJP, Sanchez AM, Partoens B, Haigh SJ, Milošević MV, Grigorieva IV. Enhanced superconductivity in few-layer TaS2 due to healing by oxygenation. Nano Lett. 2020;20(5):3808. https://doi.org/10.1021/acs.nanolett.0c00871.
Liu HL, Huangfu SX, Zhang XF, Lin H, Schilling A. Superconductivity and charge density wave formation in lithium-intercalated 2H-TaS2. Phys Rev B. 2021;104(6): 064511. https://doi.org/10.1103/PhysRevB.104.064511.
Wei ZY, Hu KM, Sa BS, Wu B. Pressure-induced structure, electronic, thermodynamic and mechanical properties of Ti2AlNb orthorhombic phase by first-principles calculations. Rare Met. 2021;40(10):2964. https://doi.org/10.1007/s12598-017-0915-8.
Chen KY, Wang NN, Yin QW, Gu YH, Jiang K, Tu ZJ, Gong GS, Uwatoko Y, Sun JP, Lei HC, Hu JP, Cheng JG. Double superconducting dome and triple enhancement of Tc in the Kagome superconductor CsV3Sb5 under high pressure. Phys Rev Lett. 2021;126(24): 247001. https://doi.org/10.1103/PhysRevLett.126.247001.
Shi LF, Liu ZY, Li J, Zhang XX, Wang NN, Cui Q, Chen KY, Liu QY, Yang PT, Sun JP, Wang BS, Uwatoko Y, Sui Y, Yang HX, Cheng JG. Pressure-driven superconducting dome in the vicinity of CDW in the pyrite-type superconductor CuS2. Phys Rev Mater. 2022;6(1): 014802. https://doi.org/10.1103/PhysRevMaterials.6.014802.
Mogera U, Kulkarni GU. A new twist in graphene research: twisted graphene. Carbon. 2020;156:470. https://doi.org/10.1016/j.carbon.2019.09.053.
Hamer MJ, Giampietri A, Kandyba V, Genuzio F, Menteş TO, Locatelli A, Gorbachev RV, Barinov A, Mucha-Kruczyński M. Moiré superlattice effects and band structure evolution in near-30-degree twisted bilayer graphene. ACS Nano. 2022;16(2):1954. https://doi.org/10.1021/acsnano.1c06439.
Cao Y, Fatemi V, Fang S, Watanabe K, Taniguchi T, Kaxiras E, Jarillo-Herrero P. Unconventional superconductivity in magic-angle graphene superlattices. Nature. 2018;556(7769):43. https://doi.org/10.1038/nature26160.
Navarro-Moratalla E, Island JO, Mañas-Valero S, Pinilla-Cienfuegos E, Castellanos-Gomez A, Quereda J, Rubio-Bollinger G, Chirolli L, Silva-Guillén JA, Agraït N, Steele GA, Guinea F, Zant HSJVD, Coronado E. Enhanced superconductivity in atomically thin TaS2. Nat Commun. 2016;7(1):11043. https://doi.org/10.1038/ncomms11043.
Xi XX, Zhao L, Wang ZF, Berger H, Forró L, Shan J, Mak KF. Strongly enhanced charge-density-wave order in monolayer NbSe2. Nat Nanotechnol. 2015;10(9):765. https://doi.org/10.1038/nnano.2015.143.
Xi XX, Wang ZF, Zhao WW, Park JH, Law KT, Berger H, Forró L, Shan J, Mak KF. Ising pairing in superconducting NbSe2 atomic layers. Nat Phys. 2016;12(2):139. https://doi.org/10.1038/NPHYS3538.
Li WW, Li HQ, Lu ZJ, Gan L, Ke LB, Zhai TY, Zhou HS. Layered phosphorus-like GeP5: a promising anode candidate with high initial coulombic efficiency and large capacity for lithium ion batteries. Energy Environ Sci. 2015;8(12):3629. https://doi.org/10.1039/C5EE02524A.
Donohue PC, Young HS. Synthesis, structure, and superconductivity of new high pressure phases in the systems Ge-P and Ge-As. J Solid State Chem. 1970;1:143. https://doi.org/10.1016/0022-4596(70)90005-8.
Yang BC, Nie AM, Chang YK, Cheng Y, Wen FS, Xiang JY, Li L, Liu ZY, Tian YJ. Metallic layered germanium phosphide GeP5 for high rate flexible all-solid-state supercapacitors. J Mater Chem A. 2018;6(40):19409. https://doi.org/10.1039/C8TA06568C.
Dai YJ, Zhao SX, Han H, Yan YF, Liu WH, Zhu H, Li L, Tang X, Li Y, Li H, Zhang CJ. Controlled growth of indium selenides by high-pressure and high-temperature method. Front Mater. 2022;8: 816821. https://doi.org/10.3389/fmats.2021.816821.
Chang YK, Mu CP, Yang BC, Nie AM, Wang BC, Xiang JY, Yang Y, Wen FS, Liu ZY. Microwave absorbing properties of two dimensional materials GeP5 enhanced after annealing treatment. Appl Phys Lett. 2019;114(1): 013103. https://doi.org/10.1063/1.5066337.
Zhou XR, Feng ZX, Qin PX, Yan H, Wang XN, Nie P, Wu HJ, Zhang X, Chen HY, Meng ZA, Zhu ZW, Liu ZQ. Negligible oxygen vacancies, low critical current density, electric-field modulation, in-plane anisotropic and high-field transport of a superconducting Nd0.8Sr0.2NiO2/SrTiO3 heterostructure. Rare Met. 2021;40:2847. https://doi.org/10.1007/s12598-021-01768-3.
Peng J, Yu Z, Wu JJ, Zhou Y, Guo YQ, Li ZJ, Zhao JY, Wu CZ, Xie Y. Disorder enhanced superconductivity toward TaS2 monolayer. ACS Nano. 2018;12:9461. https://doi.org/10.1021/acsnano.8b04718.
Yu X-L, Wu J. Superconducting dome driven by intervalley phonon scattering in monolayer MoS2. New J Phys. 2020;22(1): 013015. https://doi.org/10.1088/1367-2630/ab5cce.
Kang L, Jin BB, Liu XY, Jia XQ, Chen J, Ji ZM, Xu WW, Wu PH, Mi SB, Pimenov A, Wu YJ, Wang BG. Suppression of superconductivity in epitaxial NbN ultrathin films. J Appl Phys. 2011;109(3): 033908. https://doi.org/10.1063/1.3518037.
Du Q, Gunzburger MD, Peterson JS. Analysis and approximation of the ginzburg-landau model of superconductivity. SIAM Rev Soc Ind Appl Math. 1992;34(1):54.
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (Nos. 11904001 and 11904004), the Joint Funds of the National Natural Science Foundation of China and the Chinese Academy of Sciences Large-Scale Scientific Facility (No. U1932156) and Anhui Innovation Project (No. 2021LCX007).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interests
The authors declare that they have no conflict of interest.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Wu, L., Yang, KM., Gan, W. et al. Thickness dependence of superconductivity in layered GeP5. Rare Met. 43, 1323–1328 (2024). https://doi.org/10.1007/s12598-023-02526-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-023-02526-3