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Fabrication of corrosion inhibiting microcapsules functional coating and their high-efficiency corrosion resistance

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本文采用自组装法将苯并三氮唑(benzotriazole, BTA)负载入碳酸钙微球壳内, 制备了一种新型高效缓蚀微胶囊, 将其添加并分散至环氧树脂涂料中, 获得了一种新型耐蚀性功能涂层。采用极化曲线测试验证BTA对铝合金基体的缓蚀作用, 利用扫描电镜、激光共聚焦拉曼光谱、热重分析等验证缓蚀微胶囊的有效性及对缓蚀剂负载能力, 最后通过交流阻抗测试验证缓蚀微胶囊对功能涂层耐蚀性的影响。结果表明: 该缓蚀微胶囊对BTA负载量可达到36.57 wt%, 将其添加到涂层中经过3.5 wt% NaCl溶液浸泡腐蚀后, BTA可以得到有效释放, 浸泡5天后, 涂层仍具有较高的阻抗值, 相较于空白对照涂层样品显示出良好的耐腐蚀能力。

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Acknowledgements

This work was financially supported by the National New Material Production and Application Demonstration Platform Construction Project (No. TC190H3ZV-2).

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  1. Hao-Ran Yun and Lu Lu have contributed equally to this work.

Authors and Affiliations

  1. School of Material Science and Engineering, Tiangong University, Tianjin, 300387, China

    Hao-Ran Yun & Xing-Xiang Zhang

  2. National Center of Analysis and Testing for Nonferrous Metals and Electronic Materials, General Research Institute for Nonferrous Metals, Beijing, 100088, China

    Lu Lu & Xue-Long Hao

  3. Guobiao (Beijing) Testing & Certification Co., Ltd., Beijing, 101407, China

    Lu Lu & Xue-Long Hao

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Correspondence to Xue-Long Hao or Xing-Xiang Zhang.

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Yun, HR., Lu, L., Hao, XL. et al. Fabrication of corrosion inhibiting microcapsules functional coating and their high-efficiency corrosion resistance. Rare Met. 43, 842–848 (2024). https://doi.org/10.1007/s12598-023-02436-4

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