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Development of UiO-66-NH2 and RuO2 composite-modified carbon fiber for highly sensitive sensing of ferulic acid

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摘要

通过脉冲激光沉积法和电泳沉积法在碳纤维布上制备得到UiO-66-NH2 & RuO2 复合物，并将此类复合物应用于阿魏酸电化学传感器中。探究了UiO-66-NH2 & RuO2 复合物的表面形貌、化学组成及成键情况，分析了阿魏酸在UiO-66-NH2 & RuO2 复合物电极上的电化学反应过程。结果显示，在UiO-66-NH2体系中引入RuO2可以有效提高UiO-66-NH2的导电能力，复合物整体表现出良好的电催化活性。基于UiO-66-NH2 & RuO2 复合物的电化学传感器可以对阿魏酸进行有效检测，并且灵敏度、选择性和稳定性优异。差分脉冲伏安法显示了两个线性阿魏酸浓度区间：0.08-2.00 和2-15 mol·L−1，阿魏酸的最低检测限为 0.021 mol·L−1。此阿魏酸电化学传感器也可以对实际中药材中的阿魏酸进行检测。

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Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (No. 2022YFE0119300), Beijing Natural Science Foundation (No. 7202136) and CAMS Innovation Fund for Medical Sciences (CIFMS) (No. 2021-I2M-1-029).

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Authors and Affiliations

  1. Key Laboratory of Chinese Medicine Resources Conservation, State Administration of Traditional Chinese Medicine of the Peoples Republic of China, Engineering Research Center of Chinese Medicine Resource of Ministry of Education, Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing, 100193, China

    Jing Wang, Qing-Bin Xu, Jin-Xin Liu & Lin-Chun Shi

  2. School of Traditional Chinese Medicine, Capital Medical University, Beijing, 100069, China

    Wei-Jun Kong

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  1. Jing Wang
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  2. Qing-Bin Xu
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  3. Jin-Xin Liu
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Correspondence to Jin-Xin Liu, Wei-Jun Kong or Lin-Chun Shi.

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Wang, J., Xu, QB., Liu, JX. et al. Development of UiO-66-NH2 and RuO2 composite-modified carbon fiber for highly sensitive sensing of ferulic acid. Rare Met. 42, 3630–3637 (2023). https://doi.org/10.1007/s12598-023-02376-z

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