Skip to main content
Log in

Gelcasting of titanium hydride to fabricate low-cost titanium

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

In this work, low-cost titanium was fabricated by gelcasting of titanium hydride powder. The effects of morphology and grain composition of powder raw material and solid loading on the rheological behavior of gelcasting slurry were studied. The degreasing, dehydriding and sintering behaviors of gelcasted green body were investigated by differential thermal analysis (DTA) and dilatometer. The results show that the solid loading of titanium hydride slurry reaches 50 vol%. Combination of dehydriding and sintering in one process accelerates the densification, and the relative sintered density of the final part achieves 96.5 %. In order to test the ability of gelcasting process for fabricating structural materials, a resin handle produced by 3D printing technology was used as a model and a titanium handle was successfully fabricated. Higher solid loading and better sinterability of titanium hydride powder promote manufacture of bulk titanium with high relative density, complex shape and well-defined microstructure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Wang Z, Li J, Hua YX, Zhang Z, Zhang Y, Ke PC. Research progress in production technology of titanium. Chin J Rare Met. 2014;38(5):927.

    Google Scholar 

  2. Jabbar H, Monchoux JP, Houdellier F, Dolle M, Schimansky FP, Pyczak F, Thomas M, Couret A. Microstructure and mechanical properties of high niobium containing TiAl alloys elaborated by spark plasma sintering. Intermetallics. 2010;18(12):2312.

    Article  Google Scholar 

  3. Liu XL, Xu YM, Tao CH. Evaluation of vibration stress of TA11 titanium alloy blade by quantitative fractography. Rare Met. 2014;33(3):269.

    Google Scholar 

  4. Liu R, Hui SX, Ye WJ, Li CL, Fu YY, Yu Y, Song XY. Dynamic stress-strain properties of Ti-Al-V titanium alloys with various element contents. Rare Met. 2013;32(6):555.

    Article  Google Scholar 

  5. Ivasishin OM, Demidik AN, Sawakin DG. Use of titanium hydride for the synthesis of titanium aluminides from powder materials. Powder Metall Met Ceram. 1999;38(9–10):482.

    Article  Google Scholar 

  6. Ivasishin OM, Sawakin DG, Froes F, Mokson VC, Bondareva KA. Synthesis of alloy Ti-6Al-4V with low residual porosity by a powder metallurgy method. Powder Metall Met Ceram. 2002;41(7–8):382.

    Article  Google Scholar 

  7. Wang HT, Lefler M, Fang ZZ, Lei T, Fang SM, Zhang JM, Zhao Q. Titanium and titanium alloy via sintering of TiH2. Key Eng Mater. 2010;436:57.

    Article  Google Scholar 

  8. Xie R, Zhou KC, Gan XP, Zhang D. Effects of epoxy resin on gelcasting process and mechanical properties of alumina ceramics. J Am Ceram Soc. 2013;96(4):1107.

    Article  Google Scholar 

  9. Xue JF, Dong MJ, Li J, Zhou GH, Wang SW. Gelcasting of aluminum nitride ceramics. J Am Ceram Soc. 2010;93(4):928.

    Article  Google Scholar 

  10. Young AC, Omatete OO, Janney MA, Menchhofer PA. Gelcasting of alumina. J Am Ceram Soc. 1991;74(3):612.

    Article  Google Scholar 

  11. Janney MA. Gelcasting superalloy powders. In: Proceedings of the International Conference on Powder Metallurgy in Aerospace, Defense and Demanding. Applications, Anaheim; 1995. 139.

  12. Janney MA, Ren WJ, Kirby GH, Nunn SD, Viswanathan S. Gelcast tooling: net shape casting and green machining. Mater Manuf Process. 1998;13(3):389.

    Article  Google Scholar 

  13. Stampfl J, Liu HC, Nam SW, Sakamoto K, Tsuru H, Kang SY, Cooper AG, Nickel A, Prinz FB. Rapid prototyping and manufacturing by gelcasting of metallic and ceramic slurries. Mater Sci Eng A. 2002;334(1–2):187.

    Article  Google Scholar 

  14. Li Y, Guo ZM, Hao JJ, Ren SB. Porosity and mechanical properties of porous titanium fabricated by gelcasting. Rare Met. 2008;27(3):282.

    Article  Google Scholar 

  15. Kendra AE, David CD, Kenneth RS. Titanium with controllable pore fractions by thermoreversible gelcasting of TiH2. Acta Mater. 2008;56(18):5147.

    Article  Google Scholar 

  16. Bhosle V, Baburaj EG, Miranova M, Salama K. Dehydrogenation of TiH2. Mater Sci Eng A. 2003;356(1–2):190.

    Article  Google Scholar 

  17. Liu H, He P, Feng JC, Cao J. Kinetic study on nonisothermal dehydrogenation of TiH2 powders. Int J Hydrogen Energ. 2009;34(7):3018.

    Article  Google Scholar 

Download references

Acknowledgments

This study was financially supported by the National Natural Science Foundation of China (No. 51274039) and the State Key Laboratory of Advanced Metals and Materials (No. 2012-ZD04).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhi-Meng Guo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ye, Q., Guo, ZM., Bai, JL. et al. Gelcasting of titanium hydride to fabricate low-cost titanium. Rare Met. 34, 351–356 (2015). https://doi.org/10.1007/s12598-015-0478-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-015-0478-5

Keywords

Navigation