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Influence of alloy composition on nanoporous structure by dealloying Mn-Cu ribbons

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Abstract

Nanoporous copper (NPC) with an average pore size of 5–500 nm was fabricated by dealloying Mn-Cu alloy under the help of hindering force of surfactants as well as promoting force of voltage. The microstructures of NPC were characterized through X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The influence of alloy composition with Cu content from 15% to 45% on nanoporosity was systematically investigated in both chemical and electrochemical dealloying. It is found that alloy composition has a significant effect on the microstructure of NPC with a rapid growth of pore sizes as the Cu composition decrease.

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References

  1. Ding Y., and Kim Y.J., Erlebacher J., Nanoporous gold leaf: “Ancient technology”/advanced material, Adv. Mater., 2004, 16: 1897.

    Article  CAS  Google Scholar 

  2. Chang J.K., Hsu S.H., Sun I.W., and Tsai W.T., Formation of nanoporous nickel by selective anodic etching of the nobler copper component from electrodeposited nickel-copper alloys, J. Phys. Chem. C, 2008, 112: 1371.

    Article  CAS  Google Scholar 

  3. Liu Z.F., Yamazaki T., Shen Y.B., Meng D., Kikuta T., Nakatani N., and Kawabata T., Synthesis of titanate nanorods by high-temperature oxidation, J. Phys. Chem. C., 2008, 112: 1391.

    Article  CAS  Google Scholar 

  4. Ding Y., Mathur A., Chen M.W., and Erlebacher J., Epitaxial casting of nanotubular mesoporous platinum, Angew. Chem, Int. Ed., 2005, 44: 4002.

    Article  CAS  Google Scholar 

  5. Yu J.S., Ding Y., Xu C.X., Inoue A., Sakurai T., and Chen M.W., Nanoporous metals by dealloying multicomponent metallic glasses, Chem. Mater., 2008, 20: 4548.

    Article  CAS  Google Scholar 

  6. Thorp J.C., Sieradzki K., Tang L., Crozier P.A., Misra A., Nastasi M., Mitlin D., and Picraux S.T., Picraux, formation of nanoporous noble metal thin films by electrochemical dealloying of PtxSi(1−x), Appl. Phys. Lett., 2006, 88: 033110.

    Article  Google Scholar 

  7. Smith A.J., Tran T., and Wainwright M.S., Wainwright, Kinetics and mechanism of the preparation of Raney copper, J. Appl. Electrochem., 1999, 29: 1085.

    Article  CAS  Google Scholar 

  8. Hayes J.R., Hodge A.M., Biener J., and Hamza A.V., Monolithic nanoporous copper by dealloying Mn-Cu, Mater. J. Res., 2006, 21: 2611.

    Article  CAS  Google Scholar 

  9. Chen L.Y., Yu J.S., and Chen M.W., Nanoporous copper with tunable nanoporosity for SERS applications, Adv. Funct. Mater., 2009, 19: 1.

    Google Scholar 

  10. Forty A.J., and Durkin P., Micromorphological studies of the corrosion of gold alloys, Philos. Mag., A, 1980, 42: 295.

    Article  CAS  Google Scholar 

  11. Erlebacher J., Aziz M.J., Karma A., Dimitrov N., and Sieradzki K., Evolution of nanoporosity in dealloying, Nature, 2001, 410: 450.

    Article  CAS  Google Scholar 

  12. Lu X., Balk T.J., Spolenak R., and Arzt E., Dealloying of Au-Ag thin films with a composition gradient: Influence on morphology of nanoporous Au, Thin Solid Films, 2007, 515: 7122.

    Article  CAS  Google Scholar 

  13. Li W.C., and Balk T.J., Achieving finer pores and ligaments in nanoporous palladium-nickel thin films, Scripta Materialia, 2010, 62: 167.

    Article  CAS  Google Scholar 

  14. Morimoto H., Tobishima S., and Negishi H., Anode behavior of electroplated rough surface Sn thin films for lithium-ion batteries, J. Power Sources, 2005, 146, 469.

    Article  CAS  Google Scholar 

  15. Smith A.J., Tran T., Wainwright M.S., Wainwright, Kinetics and mechanism of the preparation of Raney copper, J. Appl. Electrochem., 1999, 29: 1085.

    Article  CAS  Google Scholar 

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Correspondence to Shichao Zhang.

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Zheng, J., Zhang, S., Liu, W. et al. Influence of alloy composition on nanoporous structure by dealloying Mn-Cu ribbons. Rare Metals 30 (Suppl 1), 370–374 (2011). https://doi.org/10.1007/s12598-011-0305-6

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  • DOI: https://doi.org/10.1007/s12598-011-0305-6

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