Skip to main content
Log in

Preparation of titanium oxycarbide from various titanium raw materials: Part I. Carbothermal reduction

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

Carbothermal reduction was performed at temperatures up to 1600°C for vanadium-bearing titanomagnetite, ilmenite concentrate, and high titania slag. The possibility of selective carbothermal reduction was discussed in detail from the viewpoint of thermodynamics, and also tested. The products were analyzed by X-ray diffraction, scanning electron microscopy, and chemical analysis. The results show that it is possible to reduce all iron oxide to metallic iron, and titania to oxycarbide (TiC x O y ), without the reduction of other oxides like silica and magnesia.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kroll W. J., The production of ductile titanium, Trans. Am. Electrochem. Soc., 1940, 78: 35.

    Google Scholar 

  2. Tomonari T., Titanium Industry—Its Growing Steps and Future Possibility, The Japan Titanium Society, Tokyo, 2000.

    Google Scholar 

  3. Chen G. Z., Fray D. J., and Farthing T. W., Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride, Nature, 2000, 407: 361.

    Article  CAS  ADS  PubMed  Google Scholar 

  4. Ono K. and Suzuki R.O., A new concept for producing Ti sponge: calciothermic reduction, JOM, 2002, 54(2): 59.

    Article  CAS  Google Scholar 

  5. Okabe T.H., Oda T., and Mitsuda Y., Titanium powder by preform reduction process (PRP), J. Alloys Compd., 2004, 364: 156.

    Article  CAS  Google Scholar 

  6. Jiao S.Q. and Zhu H.M., Electrolysis of Ti2CO solid solution prepared by TiC and TiO2, J. Alloys Compd., 2007, 438: 243.

    Article  CAS  Google Scholar 

  7. Jiao S.Q. and Zhu H.M., New metallurgical process for titanium production, J. Mater. Res., 2006, 21: 2172.

    Article  CAS  ADS  Google Scholar 

  8. Becher R.G., Canning R.G., Goodherat B.A, and Uusna S., A new process for upgrading ilmenite minerals sands, Proc. Australas. Inst. Min. Metall., 1965, 214: 21.

    Google Scholar 

  9. Welham N.J. and Williams J.S., Carbothermal reduction of ilmenite (FeTiO3) and rutile (TiO2), Metall. Mater. Trans. B, 1999, 30: 1075.

    Article  Google Scholar 

  10. Welham N.J. and Willis P.E., Formation of TiN/TiC-Fe composites from ilmenite (FeTiO3) concentrate, Metall. Mater. Trans. B, 1998, 29: 1077.

    Article  Google Scholar 

  11. Wang H.Z. The Analysis of the Slag, Science Press, Beijing, 2006

    Google Scholar 

  12. Berger L.M., Gruner W., Landgholf E., and Stolle S., On the mechanism of carbothermal reduction processes of TiO2 and ZrO2, Int. J. Refract. Met. Hard Mater., 1999, 17: 235.

    Article  CAS  Google Scholar 

  13. Afir A., Achour M., and Saoula N., X-ray diffraction study of Ti-O-C system at high temperature and in a continuous vacuum, J. Alloys Compd., 1999, 288: 124.

    Article  CAS  Google Scholar 

  14. Hideo N. and Himuea K., The study on Ti-C-O system equilibrium phase diagram, Trans. Jpn. Met. 1956, 20: 589.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hongmin Zhu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gao, C., Jiang, B., Cao, Z. et al. Preparation of titanium oxycarbide from various titanium raw materials: Part I. Carbothermal reduction. Rare Metals 29, 547–551 (2010). https://doi.org/10.1007/s12598-010-0166-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-010-0166-4

Keywords

Navigation