Abstract
Voigt deconvolution method was applied to analyze experimental pure oxygen absorption spectrum at 1270 nm band. This method gives two bands, the first is a weak discrete absorption band at 1268 nm and vanishes under high pressures, whereas the second is a continuous absorption band at 1264 nm and prevails under high pressures. Applicable pressures were varied between 10 and 25 bar, and temperatures at 298, 323, 348, and 373 K. Competition between pressure broadening and Doppler broadening was very sensitive. Gaussian width, Lorentzian width, and Voigt full width at half-maximum height (Voigt FWHM) were calculated for each spectral line.
Similar content being viewed by others
References
P.H. Krupenie, The spectrum of molecular oxygen. J. Phys. Chem. Ref. Data 1, 423 (1972). doi:10.1063/1.3253101
D.L. Grimminck, F.R. Spiering, L.M. Janssen, A. van der Avoird, W.J. van der Zande, G.C. Groenenboom, A theoretical and experimental study of pressure broadening of the oxygen A-band by helium. J. Chem. Phys. 140, 204314 (2014). doi:10.1063/1.4878666
A. Meckler, Electronic energy levels of molecular oxygen. J. Chem. Phys. 21, 1750 (1953). doi:10.1063/1.1698657
H. Margenau, Pressure shift and broadening of spectral lines. Phys. Rev. 40, 387 (1932). doi:10.1103/PhysRev.40.387
G. Peach, Theory of the pressure broadening and shift of spectral lines. Adv. Phys. 30, 367 (1981). doi:10.1080/00018738100101467
R.G. Gordon, Theory of the width and shift of molecular spectral lines in gases. J. Chem. Phys. 44, 3083 (1966). doi:10.1063/1.1727183
M. Smith, D.A. Newnham, Near-infrared absorption spectroscopy of oxygen and nitrogen gas mixtures. Chem. Phys. Lett., 308,1(1999). www.elsevier.nlrlocatercplett
J.C.S. Chagas, D.A. Newnham, K.M. Smith, K.P. Shine, Impact of new measurements of oxygen collision-induced absorption on estimates of short-wave atmospheric absorption. Q. J. R. Meteorol. Soc. 128, 2377 (2002). doi:10.1256/qj.01.159
R.M. Badger, A.C. Wright, R.F. Whitlock, Absolute intensities of the discrete and continuous absorption bands of oxygen gas at 1.26 and 1.065 μ and the radiative lifetime of the 1δ g state of oxygen. J. Chem. Phys. 43, 4345 (1965). doi:10.1063/1.1696694
R.R. Gamache, A.A. Goldman, L.S. Rothmanii, Improved spectral parameters for the three most abundant isotopomers of the oxygen molecule. J. Quant. Spectrosc. Radiat. Transfer 59, 495 (1998). doi:10.1016/S0022-4073(97)00124-6
F.J. Murcray, A. Goldman, J.C. Landry, T.M. Stephen, O2 continuum: a possible explanation for the discrepancies between measured and modeled shortwave surface irradiances. Geophys. Res. Lett. 24, 2315 (1997). doi:10.1029/97GL02220/pdf
B. Mate, C. Lug, G.T. Frase, W.J. Lafferty, Absolute intensities for the O2 1.27 μm continuum absorption. J. Geophys. Res. 104, 30585–30590 (1999). doi:10.1029/1999JD900824
A. Jablonski, General theory of pressure broadening of spectral lines. Phys. Rev. 68, 78 (1945). doi:10.1103/PhysRev.68.78
H. Margenau, The second virial coefficient for gases: a critical comparison between theoretical and experimental results. Phys. Rev. 36, 1782 (1930). doi:10.1103/PhysRev.36.1782
V.M. Devi, D.C. Benner, M.A.H. Smith, C.P. Rinsland, pressure broadening and pressure shift coefficients in the 2ν 20 and Ν1 bands of 16O13C18O. J. Quant. Spectrosc. Radiat. Transf. 60, 771 (1998). doi:10.1016/S0022-4073(98)00081-8
F.W. Byron Jr., H.M. Foley, Theory of collision broadening in the sudden approximation. Phys. Rev. 134, A625–A637 (1964). doi:10.1103/PhysRev.134.A625
A. Bielski, J. Karwowski, J. Wolnikowski, A numerical method for separation of overlapping components of a spectral line. Opt. Commun. 23(3), 362–364 (1977). doi:10.1016/0030-4018(77)90381-9
T. Giesen, R. Schieder, G. Winnewisser, K.M.T. Yamada, Precise measurements of pressure broadening and shift for several H2O lines in the ν2 band by argon, nitrogen, oxygen, and air. J. Mol. Spectrosc. 153, 406 (1992). doi:10.1016/0022-2852(92)90485-7
J. Humlíček, Optimized computation of the Voigt and complex probability functions. J. Quant. Spectrosc. Radiat. Transfer 27, 437 (1982). doi:10.1016/0022-4073(82)90078-4
L. Régalia-Jarlot, X. Thomas, P. Von der Heyden, A. Barbe, Pressure-broadened line widths and pressure-induced line shifts coefficients of the (1-0) and (2-0) bands of 12C16O. J. Quant. Spectrosc. Radiat. Transfer 91, 121 (2005). doi:10.1016/j.jqsrt.2004.05.042
M. A. AL-Jalali, Y. M. Mahzia, Pressure broadening and narrowing in pure oxygen absorption spectrum at 1270 nm band: part I. J. Chem. Bio. Phy. Sci. Sec. C. 7, 92 (2017). http://jcbsc.org/issuephy.php?volume=7&issue=1
M. A. AL-Jalali, Y. M. Mahzia, Pressure broadening and narrowing in pure oxygen absorption spectrum at 1270 nm band: part II. J. Chem. Bio. Phy. Sci. Sec. C. 7, 110 (2017). http://jcbsc.org/issuephy.php?volume=7&issue=1
M.A. AL-Jalali, I.F. Aljghami, Y.M. Mahzia, Voigt deconvolution method and its applications to pure oxygen absorption spectrum at 1270 nm band. Spectrochim. Acta Part A Mol. Spectrosc. 157, 34 (2016). doi:10.1016/j.saa.2015.12.010
M. A. A L-Jalali, I. F. Aljghami, Y. M. Mahzia, Absorption spectrum deconvolution of zero air at 1270 nm band. Int. J. ChemTech Res. 8, 116 (2015). http//: sphinxsai.com/2015/ch_vol8_no7/1/(116-127) V8N7CT
M.A. AL-Jalali, Comparison between simple and advanced data analysis to pure oxygen absorption spectrum at the 1270 nm band. J. Appl. Math. Phys. 3, 1114 (2015). doi:10.4236/jamp.2015.39138
M. A. AL-Jalali, I. F. Aljghami, Y. M. Mahzia, Virial expansion and its application to oxygen spectroscopic measurements at 1270 nm band. J. Chem. Soc. Pak. 37, 1226(2015). http://jcsp.org.pk/ViewByVolume.aspx?v=1206&i=VOLUME%2037,%20NO6,%20DEC-2015
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
AL-Jalali, M.A., Mahzia, Y.M. Competition between Lorentzian Gaussian width in pure oxygen absorption spectrum at 1264 nm band. J Opt 46, 241–246 (2017). https://doi.org/10.1007/s12596-017-0409-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12596-017-0409-y