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Characterization of Ti6Al4V–Ti6Al4V/30Ta Bilayer Components Processed by Powder Metallurgy for Biomedical Applications

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Abstract

The design and fabrication of a bilayer Ti6Al4V–Ti6Al4V/30Ta component were performed by using the powder metallurgy process and solid-state sintering as the consolidation step. Phase change and sintering densification of the component were studied by dilatometry. The addition of 30 vol% of Ta to the Ti6Al4V matrix had a noticeable effect over the microstructural and mechanical properties of the alloy, which showed decrements of up to 12.2 and 21.5% in nano-hardness and elastic modulus, respectively. The decrement of these properties strongly affected the wear and corrosion performance of the component. Special attention was focused on the intermediate zone between layers denoted by a transition zone, which presented better wear response because of the properties and microstructure caused by the gradient diffusion of Ta. Ti6Al4V/30Ta alloy showed an improved corrosion behaviour compared to Ti6Al4V alloy, decreasing 2.4 times their susceptibility to corrosion and about two orders of magnitude their corrosion rate. The bilayer component in this study is proposed as an alternative to decrease the consumption of expensive materials with improved properties.

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References

  1. C. Marker, S.-L. Shang, J.-C. Zhao, Z.-K. Liu, Comput. Mater. Sci. 142, 215–226 (2018)

    CAS  Google Scholar 

  2. H.B. Waterson, M.R. Whitehouse, N.V. Greidanus, D.S. Garbuz, B.A. Masri, C.P. Duncan, Bone Joint J. 100-B, 720–724 (2018)

    CAS  Google Scholar 

  3. J.B. Stambough, J.B. Mason, A.M. Riesgo, T.K. Fehring, Arthroplasty Today 4, 3–9 (2018)

    Google Scholar 

  4. M. Bahraminasab, B. Sahari, K. Edwards, F. Farahmand, M. Arumugam, T.S. Hong, Mater. Des. 42, 459–470 (2012)

    CAS  Google Scholar 

  5. Y. Oshida, Bioscience and Bioengineering of Titanium Materials (Elsevier, Amsterdam, 2010)

    Google Scholar 

  6. S. Datta, M. Das, V.K. Balla, S. Bodhak, V.K. Murugesan, Surf. Coat. Technol. 344, 214–222 (2018)

    CAS  Google Scholar 

  7. J.L. Cabezas-Villa, L. Olmos, D. Bouvard, J. Lemus-Ruiz, O. Jiménez, J. Mater. Res. 33, 650–661 (2018)

    CAS  Google Scholar 

  8. Q. Wang, Y. Qiao, M. Cheng, G. Jiang, G. He, Y. Chen, X. Zhang, X. Liu, Sci. Rep. 6, 26248 (2016)

    CAS  Google Scholar 

  9. J. Ruan, H. Yang, X. Weng, J. Miao, K. Zhou, J. Mater. Sci. Mater. Med. 27, 76 (2016)

    Google Scholar 

  10. A. Santos-Coquillat, R. Gonzalez-Tenorio, M. Mohedano, E. Martinez-Campos, R. Arrabal, E. Matykina, Appl. Surf. Sci. 454, 157–172 (2018)

    CAS  Google Scholar 

  11. A. Gao, R. Hang, L. Bai, B. Tang, P.K. Chu, Electrochim. Acta 271, 699–718 (2018)

    CAS  Google Scholar 

  12. H. Shahali, A. Jaggessar, P.K.D.V. Yarlagadda, Proc. Eng. 174, 1067–1076 (2017)

    CAS  Google Scholar 

  13. K. Ren, W. Yue, H. Zhang, Surf. Coat. Technol. 349, 602–610 (2018)

    CAS  Google Scholar 

  14. L. Shi, L. Shi, L. Wang, Y. Duan, W. Lei, Z. Wang, J. Li, X. Fan, X. Li, S. Li, Z. Guo, PLoS ONE 8, e55015 (2013)

    CAS  Google Scholar 

  15. C. Torres-Sanchez, J. McLaughlin, A. Fotticchia, J. Alloys Compd. 731, 189–199 (2018)

    CAS  Google Scholar 

  16. Y. Torres, S. Lascano, J. Bris, J. Pavón, J.A. Rodriguez, Mater. Sci. Eng., C 37, 148–155 (2014)

    CAS  Google Scholar 

  17. D.R.N. Correa, P.A.B. Kuroda, M.L. Lourenço, C.J.C. Fernandes, M.A.R. Buzalaf, W.F. Zambuzzi, C.R. Grandini, J. Alloys Compd. 749, 163–171 (2018)

    CAS  Google Scholar 

  18. M. Niinomi, M. Nakai, J. Hieda, Acta Biomater. 8, 3888–3903 (2012)

    CAS  Google Scholar 

  19. G. Dercz, I. Matuła, M. Zubko, A. Kazek-Kęsik, J. Maszybrocka, W. Simka, J. Dercz, P. Świec, I. Jendrzejewska, Mater. Charact. 142, 124–136 (2018)

    CAS  Google Scholar 

  20. Y. Liu, K. Li, H. Wu, M. Song, W. Wang, N. Li, H. Tang, J. Mech. Behav. Biomed. Mater. 51, 302–312 (2015)

    CAS  Google Scholar 

  21. B. Rahmati, A.A.D. Sarhan, W.J. Basirun, W.A.B.W. Abas, J. Alloys Compd. 676, 369–376 (2016)

    CAS  Google Scholar 

  22. G. Xu, X. Shen, Y. Hu, P. Ma, K. Cai, Surf. Coat. Technol. 272, 58–65 (2015)

    CAS  Google Scholar 

  23. G. Li, X. Sui, C. Jiang, Y. Gao, K. Wang, Q. Wang, D. Liu, Mater. Des. 110, 105–111 (2016)

    Google Scholar 

  24. C.Y. Wu, Y.H. Xin, X.F. Wang, J.G. Lin, Solid State Sci. 12, 2120–2124 (2010)

    CAS  Google Scholar 

  25. V.K. Balla, S. Banerjee, S. Bose, A. Bandyopadhyay, Acta Biomater. 6, 2329–2334 (2010)

    CAS  Google Scholar 

  26. P. Gill, N. Munroe, C. Pulletikurthi, S. Pandya, W. Haider, J. Mater. Eng. Perform. 20, 819–823 (2011)

    CAS  Google Scholar 

  27. Y. Yamabe, J. Umeda, H. Imai, K. Kondoh, Mater. Trans. 59, 61–65 (2018)

    CAS  Google Scholar 

  28. H. Attar, S. Ehtemam-Haghighi, D. Kent, M.S. Dargusch, Int. J. Mach. Tools Manuf 133, 85–102 (2018)

    Google Scholar 

  29. R. Karre, B.K. Kodli, A. Rajendran, J. Nivedhitha, D.K. Pattanayak, K. Ameyama, S.R. Dey, Mater. Sci. Eng. C 94, 619–627 (2019)

    CAS  Google Scholar 

  30. D. Mereib, U.C.C. Seu, M. Zakhour, M. Nakhl, N. Tessier-Doyen, J.-L. Bobet, J.-F. Silvain, J. Mater. Sci. 53, 7857–7868 (2018)

    CAS  Google Scholar 

  31. J. Chávez, L. Olmos, O. Jiménez, D. Bouvard, E. Rodríguez, M. Flores, Powder Metall. 60, 257–266 (2017)

    Google Scholar 

  32. S.J.L. Kang, Sintering: Densification, Grain Growth and Microstructure (Elsevier, Amsterdam, 2004)

    Google Scholar 

  33. R.M. German, Sintering Theory and Practice (Wiley, New York, 1996)

    Google Scholar 

  34. S. Xu, Y. Liu, C. Yang, H. Zhao, B. Liu, J. Li, M. Song, Mater. Sci. Eng., A 712, 386–393 (2018)

    CAS  Google Scholar 

  35. Y.-L. Zhou, M. Niinomi, Mater. Sci. Eng., C 29, 1061–1065 (2009)

    CAS  Google Scholar 

  36. J.L. Cabezas-Villa, L. Olmos, J. Lemus-Ruiz, D. Bouvard, J. Chavez, O. Jimenez, V. Manuel Solorio, EPJ Web Conf. 140, 13007 (2017)

    Google Scholar 

  37. D. Džunić, S. Mitrović, M. Babić, I. Bobić, M. Pantić, D. Adamović, B. Nedeljković, Tribol. Ind. 37, 413 (2015)

    Google Scholar 

  38. M.E. Maja, O.E. Falodun, B.A. Obadele, S.R. Oke, P.A. Olubambi, Ceram. Int. 44, 4419–4425 (2018)

    CAS  Google Scholar 

  39. W.C. Oliver, G.M. Pharr, J. Mater. Res. 7, 1564–1583 (1992)

    CAS  Google Scholar 

  40. T. Kokubo, H. Takadama, Biomaterials 27, 2907–2915 (2006)

    CAS  Google Scholar 

  41. A. Greco, A. Strafella, C.L. Tegola, A. Maffezzoli, Polym. Compos. 32, 657–664 (2011)

    CAS  Google Scholar 

  42. K. Youngmoo, S. Young-Beom, L. Sung Ho, J. Korean Powder Metall. Inst. 25, 109–119 (2018)

    Google Scholar 

  43. X. Xu, P. Nash, D. Mangabhai, J. Miner. Metals Mater. Soc. 69, 770–775 (2017)

    CAS  Google Scholar 

  44. A. Gupta, R.K. Khatirkar, A. Kumar, M.S. Parihar, J. Mater. Res. 33, 946–957 (2018)

    CAS  Google Scholar 

  45. X. Xu, P. Nash, Mater. Sci. Eng., A 607, 409–416 (2014)

    CAS  Google Scholar 

  46. K. Das, S. Das, J. Phase Equilib. Diffus. 26, 322–329 (2005)

    CAS  Google Scholar 

  47. H. Baker, A.S.M. Handbook, Alloy Phase Diagrams (ASM International, Novelty, 1992)

    Google Scholar 

  48. Y.-L. Zhou, M. Niinomi, J. Alloys Compd. 466, 535–542 (2008)

    CAS  Google Scholar 

  49. F. Zhang, S. Liu, P. Zhao, T. Liu, J. Sun, Mater. Des. 131, 144–155 (2017)

    CAS  Google Scholar 

  50. H.Y. Kim, S. Miyazaki, Mater. Trans. 56, 625–634 (2015)

    CAS  Google Scholar 

  51. Z. Feng, Y. Yang, Z. Xu, Q. Shi, Mater. Res. 21, 1–8 (2018)

    Google Scholar 

  52. J. Xu, W. Zeng, Y. Zhao, X. Sun, Z. Du, J. Alloys Compd. 688, 301–309 (2016)

    CAS  Google Scholar 

  53. N. Kherrouba, M. Bouabdallah, R. Badji, D. Carron, M. Amir, Mater. Chem. Phys. 181, 462–469 (2016)

    CAS  Google Scholar 

  54. F. Sun, J. Li, H. Kou, B. Tang, Y. Chen, H. Chang, J. Cai, J. Alloys Compd. 576, 108–113 (2013)

    CAS  Google Scholar 

  55. W.B. Pearson, A Handbook of Lattice Spacings and Structures of Metals and Alloys: International Series of Monographs on Metal Physics and Physical Metallurgy (Elsevier, Amsterdam, 2013)

    Google Scholar 

  56. Z.Z. Fang, J.D. Paramore, P. Sun, K.S.R. Chandran, Y. Zhang, Y. Xia, F. Cao, M. Koopman, M. Free, Int. Mater. Rev. 63, 407–459 (2017)

    Google Scholar 

  57. G. Lütjering, J.C. Williams, Titanium (Springer, Berlin, 2013)

    Google Scholar 

  58. V.A. Joshi, Titanium Alloys: An Atlas of Structures and Fracture Features (CRC Press, Boca Raton, 2006)

    Google Scholar 

  59. A.O. Adegbenjo, E. Nsiah-Baafi, M.B. Shongwe, M. Ramakokovhu, P.A. Olubambi, Int. J. Chem. Mol. Nucl. Mater. Metall. Eng. 10, 541–547 (2016)

    Google Scholar 

  60. Q. Zhou, Y. Ren, Y. Du, W. Han, D. Hua, H. Zhai, P. Huang, F. Wang, H. Wang, J. Alloys Compd. 780, 671–679 (2019)

    CAS  Google Scholar 

  61. T.L.M. Morgado, H. Navas, R. Brites, Proc. Struct. Integr. 2, 1266–1276 (2016)

    Google Scholar 

  62. L.P. Luzhnikov, V.M. Novikova, A.P. Mareev, Metal Sci. Heat Treat. 5, 78–81 (1963)

    Google Scholar 

  63. B.A. Obadele, O.E. Falodun, S.R. Oke, P.A. Olubambi, Part. Sci. Technol. (2018). https://doi.org/10.1080/02726351.2018.1515798

    Article  Google Scholar 

  64. D. Mareci, R. Chelariu, G. Ciurescu, D. Sutiman, T. Gloriant, Mater. Corros. 61, 768–774 (2010)

    CAS  Google Scholar 

  65. J. Kesteven, M.B. Kannan, R. Walter, H. Khakbaz, H.C. Choe, Mater. Sci. Eng. C Mater. Biol. Appl. 46, 226–231 (2015)

    CAS  Google Scholar 

  66. B. Becker, J. Bolton, J. Mater. Sci. Mater. Med. 8, 793–797 (1997)

    CAS  Google Scholar 

  67. K.H.W. Seah, R. Thampuran, X. Chen, S.H. Teoh, Corros. Sci. 37, 1333–1340 (1995)

    CAS  Google Scholar 

  68. D. Blackwood, A. Chua, K. Seah, R. Thampuran, S. Teoh, Corros. Sci. 42, 481–503 (2000)

    CAS  Google Scholar 

  69. K.H.W. Seah, R. Thampuran, S.H. Teoh, Corros. Sci. 40, 547–556 (1998)

    CAS  Google Scholar 

  70. J. Fojt, L. Joska, J. Málek, Corros. Sci. 71, 78–83 (2013)

    CAS  Google Scholar 

  71. B. Burnat, M. Walkowiak-Przybyło, T. Błaszczyk, L. Klimek, Acta Bioeng. Biomech. 15, 87–95 (2013)

    Google Scholar 

  72. K. Cai, X. Sui, Y. Hu, L. Zhao, M. Lai, Z. Luo, P. Liu, W. Yang, Mater. Sci. Eng., C 31, 1800–1808 (2011)

    CAS  Google Scholar 

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Acknowledgements

The authors thank the Mexican Council of Science and Technology (CONACyT) for the support given to Dr. Chávez (postdoctoral fellow, 000614) and at the CIC of the University Michoacana de San Nicolas de Hidalgo for the financial and technical support during the development of this research.

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Chávez, J., Jiménez Alemán, O., Flores Martínez, M. et al. Characterization of Ti6Al4V–Ti6Al4V/30Ta Bilayer Components Processed by Powder Metallurgy for Biomedical Applications. Met. Mater. Int. 26, 205–220 (2020). https://doi.org/10.1007/s12540-019-00326-y

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