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Non-destructive spectroscopic investigation of artefacts from middle Hallstatt period—case study of a stone bead from Tărtăria I hoard, Romania

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Abstract

A stone bead, part of a necklace found in a middle Hallstatt period—type of settlement—the Tărtăria site in Alba County, Romania, was investigated following a non-destructive approach, by means of energy-dispersive X-ray fluorescence spectrometry and Fourier transform infrared spectroscopy. The highly heterogenous object, found together with numerous bronze and iron objects, appeared to be a variety of chalcedony rich in iron and copper impurities, still preserving clay minerals from the sedimentary matrix in some of the areas. Organic molecules found at the surface of the stone artefact may indicate the presence of a wax or resin residue, possible evidence of early craft specialization. The non-destructive protocol applied allowed an in-depth characterization of the artefact, providing important information not only on the crystal structure but also on the diagnostic impurities present within this peculiar stone bead.

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References

  • Bagdzevičienė J, Niaura C, Garškaitė E, Senvaitienė J, Lukšėnienė J, Tautkus S (2011) Spectroscopic analysis of lead tin yellow pigment in medieval necklace beads from Kernavė-Kriveikiškės cemetery in Lithuania. CHEMIJA 22:2016–2222

    Google Scholar 

  • Bar-Yosef Mayer DE (2016) Stone beads. In: Selin H (ed) Encyclopaedia of the history of science, technology, and medicine in non-western cultures. Springer, Netherlands, pp 4023–4026

    Google Scholar 

  • Bar-Yosef Mayer DE, Porat N (2008) Green stone beads at the dawn of agriculture. Proc Natl Acad Sci (PNAS) 105:8548–8551

    Article  Google Scholar 

  • Baron J, Miazga B, Ntfalos T, Puziewicz J, Szumny A (2016) Beeswax remnants, phase and major element chemical composition of the bronze age mould from Gaj Oławski (SW Poland). Archaeol Anthropol Sci 8:187–196

    Article  Google Scholar 

  • Borș C, Irimuș L, Rumega V, Dobrotă S, Rișcuța C (2014) Un nou sit de tip Basarabi. Raport arheologic preliminar asupra cercetărilor arheologice preventive de la Tărtăria – Podu Tărtăriei vest (campania 2012). Cercetări Arheologice 20:9–102 (in Romanian)

    Google Scholar 

  • Cantisani E, Cavalieri M, Lofrumento C, Pecchioni E, Ricci M (2012) Ceramic findings from the archaeological site at Aiano-Torraccia di Chiusi (Siena, Italy): a multi-analytical approach. Archaeol Anthropol Sci 4:29–46

    Article  Google Scholar 

  • Cârciumaru M, Ion RM, Niţu EC, Ştefănescu R (2012) New evidence of adhesive as hafting material on Middle and Upper Palaeolithic artefacts from Gura Cheii-Râşnov Cave (Romania). J Archaeol Sci 39:1942–1950

    Article  Google Scholar 

  • Centeno SA, Williams VI, Little NC, Speakman RJ (2012) Characterization of surface decorations in Prehispanic archaeological ceramics by Raman spectroscopy, FTIR, XED and XRF. Vib Spectrosc 58:119–124

    Article  Google Scholar 

  • Craig N, Speakman RJ, Popelka-Filcoff RS, Glascock MD, Robertson JD, Shackley MS, Aldenderfer MS (2007) Comparison of XRF and PXRF for analysis of archaeological obsidian from southern Perú. J Archaeol Sci 34:2012–2014

    Article  Google Scholar 

  • Delgado Robles AA, Ruvalcaba Sil JL, Claes P, Manrique Ortega MD, González EC, Maynez Rojas MA, Cuevas García M, García Castillo S (2015) Non-destructive in situ spectroscopic analysis of greenstone objects from royal burial offerings of the Mayan site of Palenque, Mexico. Herit Sci 3. doi: 10.1186/s40494-015-0048-z

  • Ekgasit S, Padermshoke A (2001) Optical contact in ATR/FTIR spectroscopy. Appl Spectrosc 55:1352–1359

    Article  Google Scholar 

  • Fernandes R, van Os BJH, Huisman HDJ (2013) The use of hand-held XRF for investigating the composition and corrosion of Roman copper-alloyed artefacts. Herit Sci 1:30. doi:10.1186/2050-7445-1-30

    Article  Google Scholar 

  • Forouzan F, Glover JB, Williams F, Deocampo D (2012) Portable XRF analysis of zoomorphic figurines, “tokens”, and sling bullets from Chogha Gavaneh, Iran. J Archaeol Sci 39:3534–3541

    Article  Google Scholar 

  • Galli A, Bonizzoni L, Sibilia E, Martini M (2011) EDXRF analysis of metal artefacts from the grave goods of the Royal Tomb 14 of Sipán, Peru. X-Ray Spectrom 40:74–78

    Article  Google Scholar 

  • Gasanova S, Pagès-Camagna S, Andrioti M, Hermon S (2016) Non-destructive in situ analysis of polychromy on ancient Cypriot sculptures. Archaeol Anthropol Sci. doi:10.1007/s12520-016-0340-1

    Article  Google Scholar 

  • Gauss RK, Bátora J, Nowaczinski E, Rassman K, Schukraft G (2013) The Early Bronze Age settlement of Fidvár, Vráble (Slovakia): reconstructing prehistoric settlement patterns using portable XRF. J Archaeol Sci 40:2942–2960

    Article  Google Scholar 

  • Glascock MD, Neff H (2003) Neutron activation analysis and provenance research in archaeology. Meas Sci Technol 14:1516–1526

    Article  Google Scholar 

  • Helwig K (1998) The characterization of iron earth pigments using infrared spectroscopy. IRUG2 at V&A Postprints. 83–92

  • Homsher RS, Tepper Y, Drake BL, Adams MJ, David J (2016) From the Bronze Age to the “Lead Age”: observations on sediment analyses at two archaeological sites in the Jezreel Valley, Israel. Mediterr Archaeol Ar 16:203–220

    Google Scholar 

  • Levent P, Īsrafil Ş, Jiri T, Jiri P, Petr N, Jakub N (2015) Dielectric behaviors at microwave frequencies and Mössbauer effects of chalcedony, agate, and zultanite. Chinese Phys B 24:059101

    Article  Google Scholar 

  • Liu S, Li QH, Gan F, Zhang P, Lankton JW (2012) Silk Road glass in Xianjiang, China: chemical compositional analysis and interpretation using a high-resolution portable XRF spectrometer. J Archaeol Sci 39:2128–2142

    Article  Google Scholar 

  • Metzner-Nebelsick C (2005) Despre importanța cronologică și cultural-istorică a depozitelor din România în epoca târzie a bronzului și în epoca timpurie a fierului. In: Soroceanu T (ed.), Bronzefunde aus Rumänien II. / Descoperiri de bronzuri din România II, Bistrița/Cluj-Napoca, 317–342. (in Romanian).

  • Mezzi A, Angelini E, Riccucci C, Grassini S, De Caro T, Faraldi F, Bernardini P (2012) Micro-structural and micro-chemical composition of bronze artefacts from Tharros (Western Sardinia, Italy). Surf Interface Anal 44:958–962

    Article  Google Scholar 

  • Middleton A, la Niece S, Ambers J, Hook D, Hoobs R, Seddon G (2007) An elusive stone: the use of variscite as a semi-precious stone. Br Mus Tech Res Bull 1:29–34

    Google Scholar 

  • Müskens S, Braekmans D, Versluys MJ, Degryse P (2017) Egyptian sculptures from Imperial Rome. Non-destructive characterization of granitoid statues through macroscopic methodologies and in situ XRF analysis. Archaeol Anthropol Sci doi:10.1007/s12520-016-0456-3

    Article  Google Scholar 

  • Papachristodoulou C, Oikonomou A, Ioannides K, Gravani K (2006) A study of ancient pottery by means of X-ray fluorescence spectroscopy, multivariate statistics and mineralogical analysis. Anal Chim Acta 573-574:347–353

    Article  Google Scholar 

  • Paterakis AB (2003) The influence of conservation treatments and environmental storage factors on corrosion of copper alloys in the ancient Athenian Agora. J Am Inst Conserv 42:313–339

    Article  Google Scholar 

  • Petrescu-Dîmbovița M (1977) Depozitele de bronzuri din România. București (in Romanian)

  • Phillips SC, Speakman RJ (2009) Initial source evaluation of archaeological obsidian from the Kuril Islands of the Russian Far East using portable XRF. J Archaeol Sci 36:1256–1263

    Article  Google Scholar 

  • Pillay AE, Punyadeera C, Jacobson L, Eriksen J (2000) Analysis of ancient pottery and ceramic objects using X-ray fluorescence spectrometry. X-Ray Spectrom 29:53–62

    Article  Google Scholar 

  • Rădvan R, Borş C, Ghervase L (2016) Portable X-ray fluorescence investigation of certain bronze beads of Hoard Tărtăria I and their specific corrosion. Rom J Phys 61:1530–1538

    Google Scholar 

  • Regert M, Colinart S, Degrand L, Decavallas O (2001) Chemical alteration and use of beeswax through time: accelerated ageing tests and analysis of archaeological samples from various environmental contexts. Archaeometry 43:549–569

    Article  Google Scholar 

  • Robertshaw P (2014) Chemical analysis, chronology, and context of a European glass bead assemblage from Garumele, Niger. J Archaeol Sci 41:591–604

    Article  Google Scholar 

  • Schmidt P, Frohlich F (2011) Temperature dependent crystallographic transformations in chalcedony, SiO2, assessed in mid infrared spectroscopy. Spectrochim Acta A 78:1476–1481

    Article  Google Scholar 

  • Simileanu M, Rădvan R (2011) Remote method and set-up for the characterization of the submerged archaeological remmants. J Optoelectron Adv M 13:528–531

    Google Scholar 

  • Smith BC (1998) Infrared spectral interpretation: a systematic approach. CRC Press

  • Sokaras D, Karydas AG, Oikonomou A, Zacharias N, Beltsios K, Kantarelou V (2009) Combined elemental analysis of ancient glass beads by means of ion beam, portable XRF, and EPMA techniques. Anal Bioanal Chem 395:2199–2209

    Article  Google Scholar 

  • Soroceanu T (1995) Die Fundumstände bronzezeitlicher Deponierung – Ein Beitrag zur Hortdeutung beiderseits der Karpaten. In: Soroceanu T (ed) Bronzefunde aus Rumänien, Prähistorische Archäologie in Südosteuropa, vol 10, pp 15–80

    Google Scholar 

  • Speakman RJ, Little NC, Creel D, Miller MR, Iñañez JG (2011) Sourcing ceramics with portable XRF spectrometers? A comparison with INAA using Mimbres pottery from the American Southwest. J Archaeol Sci 38:3483–3496

    Article  Google Scholar 

  • Tripati S, Mudholkar A, Vora KH, Ramalingeswara Rao B, Sundaresh ASG (2010) Geochemical and mineralogical analysis of stone anchors from west coast on India: provenance study using thin sections, XRF and SEM-EDS. J Archaeol Sci 37:1999–2009

    Article  Google Scholar 

  • Vasilache V, Aparaschivei D, Sandu I (2011) A scientific investigation of the ancient jewels found in the Ibida site, Romania. Int J Conserv Sci 2:117–126

    Google Scholar 

  • Vahur S, Kriiska A, Leito I (2011) Investigation of the adhesive residue on the flint insert and the adhesive lump found from the Pulli Early Mesolithic settlement site (Estonia) by micro-ATR-FT-IR spectroscopy. Est J Archaeol 15:3–17

    Article  Google Scholar 

  • Wright KI, Critchley P, Garrard A, Baird D, Bains R, Groom S (2008) Stone bead technologies and early craft specialization: insights from two Neolithic sites in eastern Jordan. Levant 40:131–165

    Article  Google Scholar 

  • Zhu J, Yang Y, Xu W, Chen D, Dong J, Wang L, Glascock MD (2012) Study of an archaeological opaque red glass bead from China by XRD, XRF, and XANES. X-Ray Spectrom 41:363–366

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by a grant of the Romanian National Authority for Scientific Research, CNDI-UEFISCDI, PN II-PT-PCCA-2013-4-1022.

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Authors and Affiliations

  1. National Institute of Research and Development for Optoelectronics INOE 2000, 409 Atomiștilor St, Măgurele, Ilfov County, Romania

    Luminița Ghervase, Ioana Maria Cortea & Roxana Rădvan

  2. National Museum of Romanian History, 12 Calea Victoriei St, Bucharest, Romania

    Corina Borș

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  1. Luminița Ghervase
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  2. Ioana Maria Cortea
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  3. Roxana Rădvan
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  4. Corina Borș
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Correspondence to Ioana Maria Cortea.

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Ghervase, L., Cortea, I.M., Rădvan, R. et al. Non-destructive spectroscopic investigation of artefacts from middle Hallstatt period—case study of a stone bead from Tărtăria I hoard, Romania. Archaeol Anthropol Sci 10, 1841–1849 (2018). https://doi.org/10.1007/s12520-017-0502-9

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