Skip to main content

Advertisement

Log in

Assessment and geospatial distribution mapping of fluoride concentrations in the groundwater of Al-Howban Basin, Taiz-Yemen

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

Groundwater is one of the most important natural resources of drinking water on the earth planet. In rural areas of Yemen, groundwater is the main resource for drinking as well as for domestic purposes. According to the World Health Organization, one of the most important elements that has to be found in drinking water is fluorine (fluoride) but within the range of concentration of 0.5 up to 1.5 mg/l. Otherwise, any concentration of fluoride out of that range may cause serious diseases in human’s body such as fluorosis, kidney chronic disease, and/or nephrotoxicity. Taiz City, the third important and largest city in Yemen, has been suffering from dental fluorosis for a few decades. The main resource for drinking water in this city and adjacent areas is Al-Howban Basin (the study area) from where 33 groundwater samples were collected from 33 stations. These samples were preserved and then chemically analyzed according to the American Public Health Association Standards. The results reflected high levels of fluoride concentrations up to 3.6 mg/l in groundwater of many stations. GIS mapping was used to produce a geospatial distribution map of fluoride concentrations using ArcGIS-inverse distance weighted (IDW) tool. As a result, three zones of risks were identified in the study area: mild risk zone which covers the major part of the study area, moderate risk zone, and zone of no risk (optimum level zone). The last two zones occupy small portions of the study area. Consequently, dental and skeletal fluorosis, kidney, and/or nephrotoxic diseases are highly expected to be detected in the study area. Groundwater treatment measurements and health precautions are strongly recommended to be taken by local authorities in the near future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Abdulaziz A (2005) Geophysical and hydrogeological investigations and groundwater quality evaluation and protection from Upper Wadi Rasyan, Taiz, Yemen. Dissertation, University of Cairo

  • Al-Amry AS (2009) Hydro-geochemistry and origin of fluoride in groundwater of Hidhran and Alburayhi Basin, northwest Taiz City, Yemen. Delta Journal of Sciences, University of Tanta-Egypt 33(1):10–20

    Google Scholar 

  • Al-Amry AS (2011) Geochemical process controlling the elevated fluoride concentrations in groundwater of Al-Azareq Basin, Al-Dhala, Yemen. University of Aden, J Nat Appl Sci 15(1):111–120

    Google Scholar 

  • Anazawa K (2006) Fluorine and coexisting volatiles in the geosphere: the role in Japanese volcanic rocks. In: Tressaud A (ed) Fluorine and the environment: atmospheric chemistry, emissions, and lithosphere. Elsevier, Amsterdam, pp 30–184

    Google Scholar 

  • APHA (American Public Health Association) (1998) Standard methods for the examination of water and wastewater. American Public Health Association, Washington DC

    Google Scholar 

  • Ayoob S, Gupta AK (2006) Fluoride in drinking water: a review on the status and stress effects. Crit Rev Env Sci Tec 36:433–487

    Article  Google Scholar 

  • Balakrishnan P, Saleem A, Mallikarjun ND (2011) Groundwater quality mapping using geographic information system (GIS): a case study of Gulbarga City, Karnataka, India. Afr J Environ Sci Technol 5(12):1069–1084

    Article  Google Scholar 

  • Balakrishnan S, Kumar S, Elango KP (2015) Spatial analysis of groundwater quality using geographic information system: a case study. International Organization of Scientific Research-Journal of Environmental Science Toxicology and Food Technology (IOSR-JESTFT) 9(2):01–06

    Google Scholar 

  • Bell MC, Ludwig TG (1970) The supply of fluoride to man: ingestion from water. Fluoride and human health World Health Organization monograph series. WHO, Geneva

    Google Scholar 

  • Brunt R, Vasak L, Griffioen J (2004) Fluoride in groundwater: Probability of occurrence of excessive concentration on global scale. International Groundwater Resources Assessment Centre (IGRAC), Report NO. SP 2004-2, Utrecht, Netherlands

  • Chandrajith R, Dissanayake CB, Ariyarathna T, Herath HM, Padmasiri JP (2011) Dose-dependent Na and Ca in fluoride-rich drinking water-another major cause of chronic renal failure in tropical arid regions. Sci Total Environ 409(4):671–675

    Article  Google Scholar 

  • Deutsch WJ (1997) Groundwater geochemistry: fundamentals and applications to contamination. CRC, Boca Raton

    Google Scholar 

  • Dissanayake CB (1991) The fluoride problem in the groundwater of Sri Lanka—environmental management and health. Intl J Environ Stud 19:195–203

    Article  Google Scholar 

  • Domenico PA, Schwartz W (1998) Physical and chemical hydrogeology, 2nd edn. Wiley, New York

    Google Scholar 

  • Edmunds WM, Smedley PL (2005) Fluoride in natural waters. In: Selinus O (ed) Essentials of medical geology. Elsevier Academic Press, London, pp 301–329

    Google Scholar 

  • El-Hames AS, Al-Ahmadi M, Al-Amri N (2011) A GIS approach for the assessment of groundwater quality in Wadi Rabigh aquifer. Saudi Arabia Environ Earth Sci 63:1319–1331

    Article  Google Scholar 

  • Gaciri SJ, Davies TC (1993) The occurrence and geochemistry of fluoride in some natural waters of Kenya. J Hydrol 143:395–412

    Article  Google Scholar 

  • Gizaw B (1996) The origin of high bicarbonate and fluoride concentrations in waters of the main Ethiopian Rift Valley. J Afr Earth Sci 22:391–402

    Article  Google Scholar 

  • Guo Q, Wang Y, Ma T, Ma R (2006) Geochemical processes controlling the elevated fluoride concentrations in groundwater of the Taiyuan Basin, Northern China. J Geochem Explor 93(1):1–12

    Article  Google Scholar 

  • Gupta SK, Deshpande RD, Agarwal M, Raval BR (2005) Origin of high fluoride in groundwater in the North Gujarat-Cambay region, India. Hydrogeol J 13:596–605

    Article  Google Scholar 

  • Ibrahim HA, Al Gabery AS, Abdulqader AA (2011) Use of vertical electrical sounding for delineating groundwater contamination in the uplands wadi Rasyan, Taiz, Yemen. JAKU Earth Sci 22(2):131–154

    Article  Google Scholar 

  • Igboekwe MU, Akankpo AO (2011) Application of geographic information system (GIS) in mapping groundwater quality in Uyo, Nigeria. Intel J Geosci 2:394–397

    Article  Google Scholar 

  • Ileperuma OA, Dharmagunawardhane HA, Herath KPRP (2009) Dissolution of aluminum from sub-standard utensils under high fluoride stress: a possible risk factor for chronic renal failure in the North-Central Province. J Natl Sci Found Sri 37(3):219–222

    Google Scholar 

  • Inkielewicz I, Krechniak J (2003) Fluoride content in soft tissues and urine of rats exposed to sodium fluoride in drinking water. Fluoride 36:263–266

    Google Scholar 

  • Jacks G, Bhattacharya P, Chaudhary V, Singh KP (2005) Controls on the genesis of high-fluoride groundwater in India. Appl Geochem 20:221–228

    Article  Google Scholar 

  • Kadri RA, Al-Maqtari RA (2010) Endemic fluorosis among 14-year-old Yemeni adolescents: an exploratory survey. Int Dent J 60(6):407–410

    Google Scholar 

  • Ketata-Rokbani M, Gueddari M, Bouhlila R (2011) Use of geographical information system and water quality index to assess groundwater quality in El Khairat deep aquifer (Enfidha, Tunisian Sahel). Iranica Journal of Energy & Environment 2(2):133–144

    Google Scholar 

  • Kim K, Jeong YG (2005) Factors influencing natural occurrence of fluoride-rich ground waters: a case study in the southeastern part of the Korean peninsula. Chemosphere 58:1399–1408

    Article  Google Scholar 

  • Krishnaraj S, Kumar S, Elango KP (2015) Spatial analysis of groundwater quality using geographic information system—a case study. IOSR Journal of Environmental Science, Toxicology and Food Technology (IOSR-JESTFT) 9(2):1–6

    Google Scholar 

  • Kruck W, Thiele J, Schaffer A (1996) Explanatory notes on the geological map of Republic of Yemen (former Yemen Arab Republic) with 33 figures and 8 maps. Geologisches Jahrbuch, Reihe B Regional geologie Ausland, Heft 87:3–104

    Google Scholar 

  • Kumar SPJ, Jegathambal P, Nair S, James EJ (2015) Temperature and pH dependent geochemical modeling of fluoride mobilization in the groundwater of a crystalline aquifer in southern India. J Geochel Explor 156:1–9

    Article  Google Scholar 

  • Kundu N, Panigrahi MK, Tripathy S, Munshi S, Powell MA, Hart BR (2001) Geochemical appraisal of fluoride contamination of groundwater in the Nayagarh district of Orrissa India. Environ Geol 41:451–460

    Article  Google Scholar 

  • Lloyd JW, Heathcote JA (1985) Natural inorganic hydrochemistry in relation to groundwater. Oxford University Press, New York

    Google Scholar 

  • Mahramanlioglu M, Kizilcikli I, Bicer IO (2002) Adsorption of fluoride from aqueous solution by acid treated spent bleaching earth. J Fluor Chem 115:41–47

    Article  Google Scholar 

  • Nanyaro JT, Aswathanarayana U, Mungere JS, Lahermo P (1984) A geochemical model for the abnormal fluoride concentrations in water in parts of northern Tanzania. J Arf Earth Sci 2:129–140

    Google Scholar 

  • NWRA (2006) Quality of groundwater in Al- Howban catchment area. Unpublished report, Natural Water Resources Authority (NWRA), Taiz, Yemen, p 32

  • NWRA (2008) Technical notice on quality of groundwater in Al- Howban catchment area. Unpublished report, Natural Water Resources Authority (NWRA), Taiz, Yemen, p 47

  • Oruc N (2008) Occurrence and problems of high fluoride waters in Turkey: and overview. Environ Geochem Health 30(4):315-323

  • Rao SN, Devadas DJ (2003) Fluoride incidence in groundwater in an area of peninsular India. Environ Geol 45(2):243–251

    Article  Google Scholar 

  • Reddy AG, Reddy DV, Kumar M, Naik PK (2016) Evaluation of fluoride enrichment processes in groundwater of Chimakurthy granitic pluton complex in Prakasam District India. Afr J Environ Sci Technol 10:350–379

    Google Scholar 

  • Robertson Group (1990) Yemen natural resources satellite mapping program. Technical report. Ministry of Oil and Mineral Resources, Yemen, p 316

    Google Scholar 

  • Salman FD (2007) Prevalence of dental fluorosis among primary school children in Thamar–Yemen. Al– Rafidain Dent J 7(1):14–19

    Google Scholar 

  • Singh CK, Shashtri S, Mukherjee S (2011a) Integrating multivariate statistical analysis with GIS for geochemical assessment of groundwater quality in Shiwaliks of Punjab, India. Environmental Earth Sciences 62(7):1387–1405

    Article  Google Scholar 

  • Singh CK, Rina K, Singh RP, Shashtri S, Kamal V, Mukherjee S (2011b) Geochemical modeling of high fluoride concentration in groundwater of Pokhran area of Rajasthan, India. Bull Environ Contam Toxicol 86(2):152–158

    Article  Google Scholar 

  • Singh CK, Kumari R, Singh N, Mallik J, Mukherjee S (2013) Fluoride enrichment in aquifers of the Thar desert: controlling factors and its geochemical modeling. Hydrol Process 27:2462–2474

    Article  Google Scholar 

  • Sorg TJ (1978) Treatment technology to meet the interim primary drinking water regulations for inorganics. Journal (American Water Works Association) 70(2):105–111

    Google Scholar 

  • Swarna LP, Nageswara RK (2010) Assessment and spatial distribution of quality of groundwater in zone II and III, greater Visakhapatnam, India using water quality index and GIS. Int J Environ Sci 1(2):198–212

    Google Scholar 

  • Tavener SJ, Clark JH (2006) Fluorine: friend or foe? A green chemist’s perspective. In: Tressaud A (ed) Fluorine and the environment: agrochemicals, archaeology, green chemistry and water. Elsevier, Amsterdam Ch.5

    Google Scholar 

  • Totsche KU, Wilcke W, Korbus M, Kobaza J, Zech W (2000) Evaluation of fluoride-induced metal mobilization in soil columns. J Environ Qual 29:454–459

    Article  Google Scholar 

  • UNICEF (2008) Survey report about the effect of fluoridation among schoolchildren in the district of Sanhan, Sana’a, Yemen. Unpublished report, UNICEF Office at Sana’a, Yemen, p 123

  • USGS (2003) PHREEQC I-A Graphical User Interface to the Geochemical Model PHREEQC. USGS Fact Sheet FS-031-02, USGS science for a changing world. https://wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc/fs/FactSheetFS-031-02.html. Accessed 26 Sep 2016

  • Van der WJ (1997) Hydrochemistry and pollution studies in the upper wadi Rasyan catchment. Unpublished report, Natural Water Resources Authority (NWRA), Sana’a, Yemen, p 134

  • Viswanatham KS (2008) Fluorosis in Yemen prevention control status and strategies for mitigation. NWRA/Sana'a, Yemen

    Google Scholar 

  • Wang Y, Reardon EJ (2001) Activation and regeneration of a soil sorbent for defluoridation of drinking water. Appl Geochem 16:531–539

    Article  Google Scholar 

  • Wasana HMS, Aluthpatabendi D, Kularatne WMTD, Wijekoon P, Weerasooriya R, Bandara J (2016) Drinking water quality and chronic kidney disease of unknown etiology (CKDu): synergic effects of fluoride, cadmium and hardness of water. Environ Geochem Hlth 38:157–168

    Article  Google Scholar 

  • WHO (1984) Fluorine and fluoride environmental health criteria. World Health Organization, Geneva

    Google Scholar 

  • WHO (2011) Guidelines for drinking water quality, 4th edn. World Health Organization, Geneva (Electronic Resource)

    Google Scholar 

  • Xiong X, Liu J, He W, Xia T, He P, Chen X (2007) Dose-effect relationship between drinking water fluoride levels and damage to liver and kidney functions in children. Environ Res 3(1):112–116

    Article  Google Scholar 

  • Zhang B, Hong M, Zhao YS, Lin XY, Zhang XL, Dong J (2003) Distribution and risk assessment of fluoride in drinking water in the west plain region of Jilin province, China. Environ Geochem Hlth 25:421–431

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to deeply thank the Natural Water Resources Authority of Taiz Governorate (NWRA-Taiz) for their kind support and providing invaluable data during conducting this research. In addition, the authors would love to thank Prof. Magdy El-Maghraby, a Professor at Taibah University, for his great help during reviewing this manuscript. Finally, the authors would also like to thank those unknown reviewers for their valuable remarks.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Adnan Aqeel.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aqeel, A., Al-Amry, A. & Alharbi, O. Assessment and geospatial distribution mapping of fluoride concentrations in the groundwater of Al-Howban Basin, Taiz-Yemen. Arab J Geosci 10, 312 (2017). https://doi.org/10.1007/s12517-017-3069-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12517-017-3069-y

Keywords

Navigation