Abstract
Land disposal of organic waste materials may alter the heavy metal status of the soil by affecting metal solubility or dissociation kinetics. The aim of this investigation was to study the influences of two organic matters (poultry manure and pistachio compost) on copper desorption of two calcareous soils of Iran and determine the best models for description of the kinetics of Cu release in this soils. Organic matters were added to soils at the rate of 300 g kg−1, and samples were incubated at 24–25°C and near field capacity for 90 days. For Cu desorption studies, samples were extracted with 0.01 M EDTA at pH 7.0 with shaker for periods of 5 to 2,880 min. Results showed that during the reaction periods from 5 to 2,800 min, desorption of Cu from two soils increased with time. In the all of samples, copper release was rapid at first and then became slower until equilibrium was approached. In the two soils, desorption of Cu, which increased in poultry manure and decreased in pistachio compost treatments than the control soil, and two-constant rate and simple Elovich were the best equations for description of Cu desorption from soils.
الخلاصة : قد الأراضي المتخلص من مواد النفايات العضوية امکن تغيير وضع المعادن الثقيلة في التربة التي تؤثر على ذوبان المعدن أو حركية التفكك. وكان الهدف من هذا التحقيق دراسة التأثيرات لاثنين من المواد العضوية (روث الدواجن وسماد الفستق) على امتزاز النحاس اثنين من التربة الجيرية من إيران وتحديد أفضل نماذج لوصف حركية الافراج عن النحاس في هذه التربة. تم إضافة المواد العضوية للتربة بمعدل 300 كجم ز - 1 وكانت حضنت العينات في 24–25°C وبالقرب من القذرات الميدانية لمدة 90 يوما. لدراسات امتزاز النحاس ، تم استخراج عينات مع يدتا 0،01 متر في الرقم الهيدروجيني 7،0 مع شاكر لفترات تتراوح بين 5 حتي 2880 دقيقة. وأظهرت النتائج أنه خلال فترات رد الفعل 5 حتي 2800 دقيقة ، الامتزاز من النحاس اثنين من التربة ازداد مع مرور الوقت. في جميع العينات ، والإفراج عن النحاس كان سريعا في البداية ثم أصبحت أبطأ حتى اقترب التوازن. في التربة اثناين ، الامتزاز من النحاس ، وزيادة في سماد الدواجن وانخفاض في العلاجات سماد الفستق من السيطرة على الاراضي ، واثناين من المعدلات ثابتة ، و ایلوویج بسيطة كانت أفضل المعادلات لوصف الامتزاز من النحاس ، التربة.الكلمات الرئيسية : التربة الجيرية ، الافراج عن النحاس ، سماد الدواجن ، سماد الفستق
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The authors wish to thank the Mahan international center of science high technology and environmental sciences for Excellences for financial and technical supports of this project.
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Sadegh, L., Fekri, M. & Gorgin, N. Effects of poultry manure and pistachio compost on the kinetics of copper desorption from two calcareous soils. Arab J Geosci 5, 571–578 (2012). https://doi.org/10.1007/s12517-010-0211-5
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DOI: https://doi.org/10.1007/s12517-010-0211-5