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Interfacial engineering of the layered oxide cathode materials for sodium-ion battery

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Abstract

The layered metal oxides are reviewed as the hopeful cathode materials for high-performance sodium-ion batteries (SIBs) due to their large theoretical capacity, favorable two-dimensional (2D) ion diffusion channel, and simple manipuility. However, their cycling stability, rate capability, and thermal stability are still significantly concerned and highlighted before further practical application. The chemical, mechanical and electrochemical stability of the cathode–electrolyte interfaces upon cycling is of great significance. Herein, the unique structural and electrochemical properties of the layered oxide cathode materials for SIB are reviewed. The mechanism of bulk/surface degradation induced by oxygen evolution, phase transition, microcrack, and electrolyte decomposition is thoroughly understood. Furthermore, the interfacial engineering to construct stable interface through various effective methods is fully discussed. The future outlook and challenges for interfacial engineering in this filed are also summarized. This review should shed light on the rational design and construct of robust interface for applications of superior layered oxide cathodes in SIB and may suggest future research directions.

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References

  1. Usiskin, R.; Lu, Y. X.; Popovic, J.; Law, M.; Balaya, P.; Hu, Y. S.; Maier, J. Fundamentals, status and promise of sodium-based batteries. Nat. Rev. Mater. 2021, 6, 1020–1035.

    Article  CAS  ADS  Google Scholar 

  2. Dunn, B.; Kamath, H.; Tarascon, J. M. Electrical energy storage for the grid: A battery of choices. Science 2011, 334, 928–935.

    Article  CAS  PubMed  ADS  Google Scholar 

  3. Liu, H.; Zhang, X.; He, S. M.; He, D.; Shang, Y.; Yu, H. J. Molten salts for rechargeable batteries. Mater. Today 2022, 60, 128–157.

    Article  CAS  Google Scholar 

  4. Han, M. H.; Gonzalo, E.; Singh, G.; Rojo, T. A comprehensive review of sodium layered oxides: Powerful cathodes for Na-ion batteries. Energy Environ. Sci. 2015, 8, 81–102.

    Article  Google Scholar 

  5. Fang, Y. J.; Xiao, L. F.; Chen, Z. X.; Ai, X. P.; Cao, Y. L.; Yang, H. X. Recent advances in sodium-ion battery materials. Electrochem. Energy Rev. 2018, 1, 294–323.

    Article  CAS  Google Scholar 

  6. Zhou, Q.; Li, Y. Q.; Tang, F.; Li, K. X.; Rong, X. H.; Lu, Y. X.; Chen, L. Q.; Hu, Y. S. Thermal stability of high power 26650-type cylindrical Na-ion batteries. Chin. Phys. Lett. 2021, 38, 076501.

    Article  CAS  ADS  Google Scholar 

  7. Deng, J. Q.; Luo, W. B.; Chou, S. L.; Liu, H. K.; Dou, S. X. Sodium-ion batteries: From academic research to practical commercialization. Adv. Energy Mater. 2018, 8, 1701428.

    Article  Google Scholar 

  8. Yu, F.; Tang, W.; Wang, S. C.; Guo, M. C.; Deng, W. W.; Hu, J. H.; Jia, S.; Fan, C. Organic-carbon core–shell structure promotes cathode performance for Na-ion batteries. Adv. Funct. Mater. 2023, 33, 2300740.

    Article  CAS  Google Scholar 

  9. Huang, Y.; Zhang, X.; Ji, L.; Wang, L.; Xu, B. B.; Shahzad, M. W.; Tang, Y. X.; Zhu, Y. F.; Yan, M.; Sun, G. X. et al. Boosting the sodium storage performance of Prussian blue analogs by single-crystal and high-entropy approach. Energy Storage Mater. 2023, 58, 1–8.

    Article  Google Scholar 

  10. Jia, Y. H.; Wu, Y.; Li, L. S.; Song, L. M.; Gao, J. H. Monoclinic Na2VOP2O7: A 4 V-class cost-effective cathode for sodium-ion batteries. Mater. Today Phys. 2023, 33, 101038.

    Article  CAS  Google Scholar 

  11. Sun, S. Q.; Liu, S. B.; Chen, Y. J.; Li, L.; Bai, Q.; Tian, Z.; Huang, Q.; Wang, Y. Z.; Wang, X. M.; Guo, L. Quantum physics and deep learning to reveal multiple dimensional modified regulation by ternary substitution of iron, manganese, and cobalt on Na3V2(PO4)3 for superior sodium storage. Adv. Funct. Mater. 2023, 33, 2213711.

    Article  CAS  Google Scholar 

  12. Yan, S. X.; Luo, S. H.; Yang, L.; Feng, J.; Li, P. W.; Wang, Q.; Zhang, Y. H.; Liu, X. Novel P2-type layered medium-entropy ceramics oxide as cathode material for sodium-ion batteries. J. Adv. Ceram. 2021, 11, 158–171.

    Article  Google Scholar 

  13. Liu, N. B.; Zhao, X. Y.; Qin, B.; Zhao, D. D.; Dong, H. H.; Qiu, M. D.; Wang, L. B. A high-performance Na-storage cathode enabled by layered P2-type KxMnO2 with enlarged interlayer spacing and fast diffusion channels for sodium-ion batteries. J. Mater. Chem. A 2022, 10, 25168–25177.

    Article  CAS  Google Scholar 

  14. Wang, X.; Li, H. X.; Zhang, W.; Ge, X. C.; He, L.; Zhang, L. Y.; Li, S. H.; Wen, N. F.; Guo, J. L.; Lai, Y. Q. et al. Unlocking fast and highly reversible sodium storage in Fe-based mixed polyanion cathodes for low-cost and high-performance sodium-ion batteries. J. Mater. Chem. A 2023, 11, 6978–6985.

    Article  CAS  Google Scholar 

  15. Zhao, A. L.; Ji, F. J.; Liu, C. Y.; Zhang, S. H.; Chen, K. A.; Chen, W. H.; Feng, X. M.; Zhong, F. P.; Ai, X. P.; Yang, H. X. et al. Revealing the structural chemistry in Na6−2xFex(SO4)3 (1.5 ≤ x ≥ 2.0) for low-cost and high-performance sodium-ion batteries. Sci. Bull. 2023, 68, 1894–1903.

    Article  CAS  Google Scholar 

  16. Gu, Z. Y.; Heng, Y. L.; Guo, J. Z.; Cao, J. M.; Wang, X. T.; Zhao, X. X.; Sun, Z. H.; Zheng, S. H.; Liang, H. J.; Li, B. et al. Nano self-assembly of fluorophosphate cathode induced by surface energy evolution towards high-rate and stable sodium-ion batteries. Nano Res. 2023, 16, 439–448.

    Article  CAS  ADS  Google Scholar 

  17. Zhao, C. L.; Wang, Q. D.; Yao, Z. P.; Wang, J. L.; Sánchez-Lengeling, B.; Ding, F. X.; Qi, X. G.; Lu, Y. X.; Bai, X. D.; Li, B. H. et al. Rational design of layered oxide materials for sodium-ion batteries. Science 2020, 370, 708–711.

    Article  CAS  PubMed  ADS  Google Scholar 

  18. Delmas, C.; Fouassier, C.; Hagenmuller, P. Structural classification and properties of the layered oxides. Phys. B+C 2007, 99, 81–85.

    Article  ADS  Google Scholar 

  19. Chen, C.; Huang, W. Y.; Li, Y. W.; Zhang, M. J.; Nie, K. Q.; Wang, J. O.; Zhao, W. G.; Qi, R.; Zuo, C. J.; Li, Z. B. et al. P2/O3 biphasic Fe/Mn-based layered oxide cathode with ultrahigh capacity and great cyclability for sodium ion batteries. Nano Energy 2021, 90, 106504.

    Article  CAS  Google Scholar 

  20. Cheng, Z. W.; Fan, X. Y.; Yu, L. Z.; Hua, W. B.; Guo, Y. J.; Feng, Y. H.; Ji, F. D.; Liu, M. T.; Yin, Y. X.; Han, X. G. et al. A rational biphasic tailoring strategy enabling high-performance layered cathodes for sodium-ion batteries. Angew. Chem., Int. Ed. 2022, 61, e202117728.

    Article  CAS  ADS  Google Scholar 

  21. Yuan, T.; Li, S. Q.; Sun, Y. Y.; Wang, J. H.; Chen, A. J.; Zheng, Q. F.; Zhang, Y. X.; Chen, L. W.; Nam, G.; Che, H. Y. et al. A high-rate, durable cathode for sodium-ion batteries: Sb-doped O3-type Ni/Mn-based layered oxides. ACS Nano 2022, 16, 18058–18070.

    Article  CAS  PubMed  Google Scholar 

  22. Zhao, Q. Q.; Butt, F. K.; Yang, M.; Guo, Z. F.; Yao, X. Y.; Zapata, M. J. M.; Zhu, Y. Q.; Ma, X. L.; Cao, C. B. Tuning oxygen redox chemistry of P2-type manganese-based oxide cathode via dual Cu and Co substitution for sodium-ion batteries. Energy Storage Mater. 2021, 41, 581–587.

    Article  Google Scholar 

  23. Mao, Q. J.; Gao, R.; Li, Q. Y.; Ning, D.; Zhou, D.; Schuck, G.; Schumacher, G.; Hao, Y. M.; Liu, X. F. O3-type NaNi0.5Mn0.5O2 hollow microbars with exposed {010} facets as high performance cathode materials for sodium-ion batteries. Chem. Eng. J. 2020, 382, 122978.

    Article  CAS  Google Scholar 

  24. Yu, L. Z.; Dong, H. J.; Chang, Y. X.; Cheng, Z. W.; Xu, K.; Feng, Y. H.; Si, D.; Zhu, X.; Liu, M. T.; Xiao, B. et al. Elucidation of the sodium kinetics in layered P-type oxide cathodes. Sci. China Chem. 2022, 65, 2005–2014.

    Article  CAS  Google Scholar 

  25. Kulka, A.; Marino, C.; Walczak, K.; Borca, C.; Bolli, C.; Novák, P.; Villevieille, C. Influence of Na/Mn arrangements and P2/P’2 phase ratio on the electrochemical performance of NaxMnO2 cathodes for sodium-ion batteries. J. Mater. Chem. A 2020, 8, 6022–6033.

    Article  CAS  Google Scholar 

  26. Lei, Y. C.; Li, X.; Liu, L.; Ceder, G. Synthesis and stoichiometry of different layered sodium cobalt oxides. Chem. Mater. 2014, 26, 5288–5296.

    Article  CAS  Google Scholar 

  27. Sathiya, M.; Jacquet, Q.; Doublet, M. L.; Karakulina, O. M.; Hadermann, J.; Tarascon, J. M. A chemical approach to raise cell voltage and suppress phase transition in O3 sodium layered oxide electrodes. Adv. Energy Mater. 2018, 8, 1702599.

    Article  Google Scholar 

  28. Ling, Y. X.; Zhou, J.; Guo, S.; Fu, H. W.; Zhou, Y. F.; Fang, G. Z.; Wang, L. B.; Lu, B. A.; Cao, X. X.; Liang, S. Q. Copper-stabilized P’2-type layered manganese oxide cathodes for high-performance sodium-ion batteries. ACS Appl. Mater. Interfaces 2021, 13, 58665–58673.

    Article  CAS  PubMed  Google Scholar 

  29. Kim, E. J.; Ma, L. A.; Duda, L. C.; Pickup, D. M.; Chadwick, A. V.; Younesi, R.; Irvine, J. T. S.; Armstrong, A. R. Oxygen redox activity through a reductive coupling mechanism in the P3-type nickel-doped sodium manganese oxide. ACS Appl. Energy Mater. 2020, 3, 184–191.

    Article  CAS  Google Scholar 

  30. Nguyen, N. A.; Kim, K.; Choi, K. H.; Jeon, H.; Lee, K.; Ryou, M. H.; Lee, Y. M. Effect of calcination temperature on a P-type Na0.6Mn0.65Ni0.25Co0.10O2 cathode material for sodium-ion batteries. J. Electrochem. Soc. 2017, 164, A6308–A6314.

    Article  CAS  Google Scholar 

  31. Deng, C. J.; Gabriel, E.; Skinner, P.; Lee, S.; Barnes, P.; Ma, C. R.; Gim, J.; Lau, M. L.; Lee, E.; Xiong, H. Origins of irreversibility in layered NaNixFeyMnzO2 cathode materials for sodium ion batteries. ACS Appl. Mater. Interfaces 2020, 12, 51397–51408.

    Article  CAS  PubMed  Google Scholar 

  32. Hwang, J. Y.; Myung, S. T.; Yoon, C. S.; Kim, S. S.; Aurbach, D.; Sun, Y. K. Novel cathode materials for Na-ion batteries composed of spoke-like nanorods of Na[Ni0.61Co0.12Mn0.27]O2 assembled in spherical secondary particles. Adv. Funct. Mater. 2016, 26, 8083–8093.

    Article  CAS  Google Scholar 

  33. Peng, B.; Chen, Y. X.; Zhao, L. P.; Zeng, S. Y.; Wan, G. L.; Wang, F.; Zhang, X. L.; Wang, W. T.; Zhang, G. Q. Regulating the local chemical environment in layered O3-NaNi0.5Mn0.5O2 achieves practicable cathode for sodium-ion batteries. Energy Storage Mater. 2023, 56, 631–641.

    Article  Google Scholar 

  34. Zhou, P. F.; Che, Z. N.; Liu, J.; Zhou, J. K.; Wu, X. Z.; Weng, J. Y.; Zhao, J. P.; Cao, H.; Zhou, J.; Cheng, F. Y. High-entropy P2/O3 biphasic cathode materials for wide-temperature rechargeable sodium-ion batteries. Energy Storage Mater. 2023, 57, 618–627.

    Article  Google Scholar 

  35. Yabuuchi, N.; Kajiyama, M.; Iwatate, J.; Nishikawa, H.; Hitomi, S.; Okuyama, R.; Usui, R.; Yamada, Y.; Komaba, S. P2-type NaxFe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries. Nat. Mater. 2012, 11, 512–517.

    Article  CAS  PubMed  ADS  Google Scholar 

  36. Huang, Y. Y.; Yan, Z. C.; Luo, W.; Hu, Z. W.; Liu, G. X.; Zhang, L. L.; Yang, X. L.; Ou, M. Y.; Liu, W. J.; Huang, L. Q. et al. Vitalization of P2-Na2/3Ni1/3Mn2/3O2 at high-voltage cyclability via combined structural modulation for sodium-ion batteries. Energy Storage Mater. 2020, 29, 182–189.

    Article  Google Scholar 

  37. Xu, S. Y.; Wu, X. Y.; Li, Y. M.; Hu, Y. S.; Chen, L. Q. Novel copper redox-based cathode materials for room-temperature sodium-ion batteries. Chin. Phys. B 2014, 23, 118202.

    Article  ADS  Google Scholar 

  38. Mu, L. Q.; Xu, S. Y.; Li, Y. M.; Hu, Y. S.; Li, H.; Chen, L. Q.; Huang, X. J. Prototype sodium-ion batteries using an air-stable and Co/Ni-free O3-layered metal oxide cathode. Adv. Mater. 2015, 27, 6928–6933.

    Article  CAS  PubMed  Google Scholar 

  39. Li, Y. M.; Yang, Z. Z.; Xu, S. Y.; Mu, L. Q.; Gu, L.; Hu, Y. S.; Li, H.; Chen, L. Q. Air-stable copper-based P2-Na7/9Cu2/9Fe1/9Mn2/3O2 as a new positive electrode material for sodium-ion batteries. Adv. Sci. 2015, 2, 1500031.

    Article  Google Scholar 

  40. Xu, G. L.; Liu, X.; Zhou, X. W.; Zhao, C.; Hwang, I.; Daali, A.; Yang, Z. Z.; Ren, Y.; Sun, C. J.; Chen, Z. H. et al. Native lattice strain induced structural earthquake in sodium layered oxide cathodes. Nat. Commun. 2022, 13, 436.

    Article  PubMed  PubMed Central  ADS  Google Scholar 

  41. Goodenough, J. B.; Kim, Y. Challenges for rechargeable Li batteries. Chem. Mater. 2010, 22, 587–603.

    Article  CAS  Google Scholar 

  42. Whittingham, M. S. Electrical energy storage and intercalation chemistry. Science 1976, 192, 1126–1127.

    Article  CAS  PubMed  ADS  Google Scholar 

  43. Rouxel, J. Anion-cation redox competition and the formation of new compounds in highly covalent systems. Chem.—Eur. J. 1996, 2, 1053–1059.

    Article  CAS  Google Scholar 

  44. Robertson, A. D.; Bruce, P. G. Mechanism of electrochemical activity in Li2MnO3. Chem. Mater. 2003, 15, 1984–1992.

    Article  CAS  Google Scholar 

  45. Yu, D. Y. W.; Yanagida, K.; Kato, Y.; Nakamura, H. Electrochemical activities in Li2MnO3. J. Electrochem. Soc. 2009, 156, A417–A424.

    Article  CAS  Google Scholar 

  46. Kalyani, P.; Chitra, S.; Mohan, T.; Gopukumar, S. Lithium metal rechargeable cells using Li2MnO3 as the positive electrode. J. Power Sources 1999, 80, 103–106.

    Article  CAS  ADS  Google Scholar 

  47. Assat, G.; Tarascon, J. M. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries. Nat. Energy 2018, 3, 373–386.

    Article  CAS  ADS  Google Scholar 

  48. Kitchaev, D. A.; Vinckeviciute, J.; Van der Ven, A. Delocalized metal-oxygen π-redox is the origin of anomalous nonhysteretic capacity in Li-ion and Na-ion cathode materials. J. Am. Chem. Soc. 2021, 143, 1908–1916.

    Article  CAS  PubMed  Google Scholar 

  49. Kang, S.; Choi, D.; Lee, H.; Choi, B.; Kang, Y. M. A mechanistic insight into the oxygen redox of Li-rich layered cathodes and their related electronic/atomic behaviors upon cycling. Adv. Mater. 2023, 2211965.

  50. Xie, Y.; Saubanère, M.; Doublet, M. L. Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries. Energy Environ. Sci. 2017, 10, 266–274.

    Article  CAS  Google Scholar 

  51. Ren, H. X.; Li, Y.; Ni, Q.; Bai, Y.; Zhao, H. C.; Wu, C. Unraveling anionic redox for sodium layered oxide cathodes: Breakthroughs and perspectives. Adv. Mater. 2022, 34, 2106171.

    Article  CAS  Google Scholar 

  52. Ma, C. Z.; Alvarado, J.; Xu, J.; Clément, R. J.; Kodur, M.; Tong, W.; Grey, C. P.; Meng, Y. S. Exploring oxygen activity in the high energy P2-type Na0.78Ni0.23Mn0.69O2 cathode material for Na-ion batteries. J. Am. Chem. Soc. 2017, 139, 4835–4845.

    Article  CAS  PubMed  Google Scholar 

  53. Yabuuchi, N.; Hara, R.; Kubota, K.; Paulsen, J.; Kumakura, S.; Komaba, S. A new electrode material for rechargeable sodium batteries: P2-type Na2/3[Mg0.28Mn0.72]O2 with anomalously high reversible capacity. J. Mater. Chem. A 2014, 2, 16851–16855.

    Article  CAS  Google Scholar 

  54. de Boisse, B. M.; Nishimura, S. I.; Watanabe, E.; Lander, L.; Tsuchimoto, A.; Kikkawa, J.; Kobayashi, E.; Asakura, D.; Okubo, M.; Yamada, A. Highly reversible oxygen-redox chemistry at 4.1 V in Na4/7−x[□1/7Mn6/7O2 (□: Mn vacancy). Adv. Energy Mater. 2018, 8, 1800409.

    Article  Google Scholar 

  55. Jia, M.; Li, H. F.; Qiao, Y.; Wang, L. L.; Cao, X.; Cabana, J.; Zhou, H. S. Elucidating anionic redox chemistry in P3 layered cathode for Na-ion batteries. ACS Appl. Mater. Interfaces 2020, 12, 38249–38255.

    Article  CAS  PubMed  Google Scholar 

  56. Lai, Y. Y.; Xie, H. X.; Li, P.; Li, B.; Zhao, A. L.; Luo, L. B.; Jiang, Z. W.; Fang, Y. J.; Chen, S. L.; Ai, X. P. et al. Ion-migration mechanism: An overall understanding of anionic redox activity in metal oxide cathodes of Li/Na-ion batteries. Adv. Mater. 2022, 34, 2206039.

    Article  CAS  Google Scholar 

  57. Li, X. L.; Bao, J.; Shadike, Z.; Wang, Q. C.; Yang, X. Q.; Zhou, Y. N.; Sun, D. L.; Fang, F. Stabilizing transition metal vacancy induced oxygen redox by Co2+/Co3+ redox and sodium-site doping for layered cathode materials. Angew. Chem., Int. Ed. 2021, 60, 22026–22034.

    Article  CAS  Google Scholar 

  58. Dai, K. H.; Wu, J. P.; Zhuo, Z. Q.; Li, Q. H.; Sallis, S.; Mao, J.; Ai, G.; Sun, C. H.; Li, Z. Y.; Gent, W. E. et al. High reversibility of lattice oxygen redox quantified by direct bulk probes of both anionic and cationic redox reactions. Joule 2019, 3, 518–541.

    Article  CAS  Google Scholar 

  59. Kim, E. J.; Maughan, P. A.; Bassey, E. N.; Clément, R. J.; Ma, L. A.; Duda, L. C.; Sehrawat, D.; Younesi, R.; Sharma, N.; Grey, C. P. et al. Importance of superstructure in stabilizing oxygen redox in P3-Na0.67Li0.2Mn0.8O2. Adv. Energy Mater. 2022, 12, 2102325.

    Article  CAS  Google Scholar 

  60. Zhao, C.; Chen, C.; Hu, B.; Tong, W.; Liu, H.; Hu, B. W.; Li, C. Correlating Mg displacement with topologically regulated lattice oxygen redox in Na-ion layered oxide cathodes. Chem. Mater. 2022, 34, 9240–9250.

    Article  CAS  Google Scholar 

  61. House, R. A.; Maitra, U.; Pérez-Osorio, M. A.; Lozano, J. G.; Jin, L. Y.; Somerville, J. W.; Duda, L. C.; Nag, A.; Walters, A.; Zhou, K. J. et al. Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes. Nature 2020, 577, 502–508.

    Article  CAS  PubMed  ADS  Google Scholar 

  62. Zheng, W.; Liu, Q.; Wang, Z. Y.; Wu, Z. L.; Gu, S.; Cao, L. J.; Zhang, K. L.; Fransaer, J.; Lu, Z. G. Oxygen redox activity with small voltage hysteresis in Na0.67Cu0.28Mn0.72O2 for sodium-ion batteries. Energy Storage Mater. 2020, 28, 300–306.

    Article  Google Scholar 

  63. Risthaus, T.; Zhou, D.; Cao, X.; He, X.; Qiu, B.; Wang, J.; Zhang, L.; Liu, Z. P.; Paillard, E.; Schumacher, G. et al. A high-capacity P2 Na2/3Ni1/3Mn2/3O2 cathode material for sodium ion batteries with oxygen activity. J. Power Sources 2018, 395, 16–24.

    Article  CAS  ADS  Google Scholar 

  64. Cao, M. H.; Li, R. Y.; Lin, S. Y.; Zheng, S. D.; Ma, L.; Tan, S.; Hu, E. Y.; Shadike, Z.; Yang, X. Q.; Fu, Z. W. Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries. J. Mater. Chem. A 2021, 9, 27651–27659.

    Article  CAS  Google Scholar 

  65. Zuo, W. H.; Ren, F. C.; Li, Q. H.; Wu, X. H.; Fang, F.; Yu, X. Q.; Li, H.; Yang, Y. Insights of the anionic redox in P2-Na0.67Ni0.33Mn0.67O2. Nano Energy 2020, 78, 105285.

    Article  CAS  Google Scholar 

  66. Huang, Y. Y.; Zhu, Y. C.; Nie, A. M.; Fu, H. Y.; Hu, Z. W.; Sun, X. P.; Haw, S. C.; Chen, J. M.; Chan, T. S.; Yu, S. J. et al. Enabling anionic redox stability of P2-Na5/6Li1/4Mn3/4O2 by Mg substitution. Adv. Mater. 2022, 34, 2105404.

    Article  CAS  Google Scholar 

  67. Cheng, C.; Chen, C.; Chu, S. Y.; Hu, H. L.; Yan, T. R.; Xia, X.; Feng, X. F.; Guo, J. H.; Sun, D.; Wu, J. P. et al. Enhancing the reversibility of lattice oxygen redox through modulated transition metal-oxygen covalency for layered battery electrodes. Adv. Mater. 2022, 34, 2201152.

    Article  CAS  Google Scholar 

  68. Rong, X. H.; Liu, J.; Hu, E. Y.; Liu, Y. J.; Wang, Y.; Wu, J. P.; Yu, X. Q.; Page, K.; Hu, Y. S.; Yang, W. L. et al. Structure-induced reversible anionic redox activity in Na layered oxide cathode. Joule 2018, 2, 125–140.

    Article  CAS  Google Scholar 

  69. Xue, Z. C.; Huang, J. N.; Guo, X. Y.; Guo, H.; Zhu, Y.; Hu, G. R.; Peng, Z. D.; Cao, Y. B.; Du, K. Capturing surface interlayer cation migration in Na0.6[Li0.2Mn0.8]O2 layered cathode materials for sodium battery. Ceram. Int. 2022, 48, 25642–25646.

    Article  CAS  Google Scholar 

  70. Liu, Y. H.; Fang, X.; Zhang, A. Y.; Shen, C. F.; Liu, Q. Z.; Enaya, H. A.; Zhou, C. W. Layered P2-Na2/3[Ni1/3Mn2/3]O2 as high-voltage cathode for sodium-ion batteries: The capacity decay mechanism and Al2O3 surface modification. Nano Energy 2016, 27, 27–34.

    Article  CAS  ADS  Google Scholar 

  71. Xia, J. Y.; Wu, W. W.; Fang, K. X.; Wu, X. H. Enhancing the interfacial stability of P2-type cathodes by polydopamine-derived carbon coating for achieving performance improvement. Carbon 2020, 157, 693–702.

    Article  CAS  Google Scholar 

  72. Sathiya, M.; Thomas, J.; Batuk, D.; Pimenta, V.; Gopalan, R.; Tarascon, J. M. Dual stabilization and sacrificial effect of Na2CO3 for increasing capacities of Na-ion cells based on P2-NaxMO2 electrodes. Chem. Mater. 2017, 29, 5948–5956.

    Article  CAS  Google Scholar 

  73. Liu, J.; Didier, C.; Sale, M.; Sharma, N.; Guo, Z. P.; Peterson, V. K.; Ling, C. D. Elucidation of the high-voltage phase in the layered sodium ion battery cathode material P3-Na0.5Ni0.25Mn0.75O2. J. Mater. Chem. A 2020, 8, 21151–21162.

    Article  CAS  Google Scholar 

  74. Liu, Z. B.; Liu, J. Structural evolution in P2-type layered oxide cathode materials for sodium-ion batteries. ChemNanoMat 2022, 8, e202100385.

    Article  CAS  Google Scholar 

  75. Wang, C. C.; Liu, L. J.; Zhao, S.; Liu, Y. C.; Yang, Y. B.; Yu, H. J.; Lee, S.; Lee, G. H.; Kang, Y. M.; Liu, R. et al. Tuning local chemistry of P2 layered-oxide cathode for high energy and long cycles of sodium-ion battery. Nat. Commun. 2021, 12, 2256.

    Article  CAS  PubMed  PubMed Central  ADS  Google Scholar 

  76. Liu, H. Q.; Chen, H. Y.; Deng, W. T.; Zhang, S.; Mei, Y.; Huang, J. N.; Hu, X. Y.; Wang, K.; Jian, W. S.; Zou, G. Q. et al. Orthorhombic Na2/3Cu0.1Mn0.9O2 cathode: Enhanced Na storage performances with the suppressed Mn-O bond anisotropy. Chem. Eng. J. 2023, 460, 141744.

    Article  CAS  Google Scholar 

  77. Voronina, N.; Yu, J. H.; Kim, H. J.; Yaqoob, N.; Guillon, O.; Kim, H.; Jung, M. G.; Jung, H. G.; Yazawa, K.; Yashiro, H. et al. Engineering transition metal layers for long lasting anionic redox in layered sodium manganese oxide. Adv. Funct. Mater. 2023, 33, 2210423.

    Article  CAS  Google Scholar 

  78. Yoon, G. H.; Koo, S.; Park, S. J.; Lee, J.; Koo, C.; Song, S. H.; Jeon, T. Y.; Kim, H.; Bae, J. S.; Moon, W. J. et al. Enabling stable and nonhysteretic oxygen redox capacity in Li-excess Na layered oxides. Adv. Energy Mater. 2022, 12, 2103384.

    Article  CAS  Google Scholar 

  79. Liu, Q. N.; Hu, Z.; Chen, M. Z.; Zou, C.; Jin, H. L.; Wang, S.; Gu, Q. F.; Chou, S. L. P2-type Na2/3Ni1/3Mn2/3O2 as a cathode material with high-rate and long-life for sodium ion storage. J. Mater. Chem. A 2019, 7, 9215–9221.

    Article  CAS  Google Scholar 

  80. Liu, H. Q.; Gao, X.; Chen, J.; Gao, J. Q.; Yin, S. Y.; Zhang, S.; Yang, L.; Fang, S. S.; Mei, Y.; Xiao, X. H. et al. Reversible OP4 phase in P2-Na2/3Ni1/3Mn2/3O2 sodium ion cathode. J. Power Sources 2021, 508, 230324.

    Article  CAS  Google Scholar 

  81. Liu, Z. B.; Shen, J. D.; Feng, S. H.; Huang, Y. L.; Wu, D. J.; Li, F. K.; Zhu, Y. M.; Gu, M.; Liu, Q.; Liu, J. et al. Ultralow volume change of P2-type layered oxide cathode for Na-ion batteries with controlled phase transition by regulating distribution of Na+. Angew. Chem., Int. Ed. 2021, 60, 20960–20969.

    Article  CAS  Google Scholar 

  82. Somerville, J. W.; Sobkowiak, A.; Tapia-Ruiz, N.; Billaud, J.; Lozano, J. G.; House, R. A.; Gallington, L. C.; Ericsson, T.; Häggström, L.; Roberts, M. R. et al. Nature of the “Z”-phase in layered Na-ion battery cathodes. Energy Environ. Sci. 2019, 12, 2223–2232.

    Article  CAS  Google Scholar 

  83. Zhang, T.; Ji, H. C.; Hou, X. H.; Ji, W. H.; Fang, H.; Huang, Z. Y.; Chen, G. J.; Yang, T. T.; Chu, M. H.; Xu, S. Y. et al. Promoting the performances of P2-type sodium layered cathode by inducing Na site rearrangement. Nano Energy 2022, 100, 107482.

    Article  CAS  Google Scholar 

  84. Jin, T.; Wang, P. F.; Wang, Q. C.; Zhu, K. J.; Deng, T.; Zhang, J. X.; Zhang, W.; Yang, X. Q.; Jiao, L. F.; Wang, C. S. Realizing complete solid-solution reaction in high sodium content P2-type cathode for high-performance sodium-ion batteries. Angew. Chem., Int. Ed. 2020, 59, 14511–14516.

    Article  CAS  Google Scholar 

  85. Yu, T. Y.; Ryu, H. H.; Han, G.; Sun, Y. K. Understanding the capacity fading mechanisms of O3-type Na[Ni0.5Mn0.5]O2 cathode for sodium-ion batteries. Adv. Energy Mater. 2020, 10, 2001609.

    Article  CAS  Google Scholar 

  86. Xie, Y. Y.; Gao, H.; Harder, R.; Li, L. S.; Gim, J.; Che, H. Y.; Wang, H.; Ren, Y.; Zhang, X. Y.; Li, L. X. et al. Revealing the structural evolution and phase transformation of O3-type NaNi1/3Fe1/3Mn1/3O2 cathode material on sintering and cycling processes. ACS Appl. Energy Mater. 2020, 3, 6107–6114.

    Article  CAS  Google Scholar 

  87. Yu, T. Y.; Kim, J.; Hwang, J. Y.; Kim, H.; Han, G.; Jung, H. G.; Sun, Y. K. High-energy O3-Na1−2xCax[Ni0.5Mn0.5]O2 cathodes for long-life sodium-ion batteries. J. Mater. Chem. A 2020, 8, 13776–13786.

    Article  CAS  Google Scholar 

  88. Xia, F. J.; Zeng, W. H.; Peng, H. Y.; Wang, H.; Sun, C. L.; Zou, J.; Wu, J. S. Revealing structural degradation in layered structure oxides cathode of lithium ion batteries via in-situ tansmission electron microscopy. J. Mater. Sci. Technol. 2023, 154, 189–201.

    Article  CAS  Google Scholar 

  89. Xu, C.; Märker, K.; Lee, J.; Mahadevegowda, A.; Reeves, P. J.; Day, S. J.; Groh, M. F.; Emge, S. P.; Ducati, C.; Layla Mehdi, B. et al. Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries. Nat. Mater. 2021, 20, 84–92.

    Article  CAS  PubMed  ADS  Google Scholar 

  90. Kim, H.; Kim, M.; Park, S.; Cho, M.; Kim, D. Chemomechanics in Ni-Mn binary cathode for advanced sodium-ion batteries. J. Mater. Chem. A 2021, 9, 24290–24298.

    Article  CAS  Google Scholar 

  91. Xu, C. L.; Cai, H. R.; Chen, Q. L.; Kong, X. Q.; Pan, H. L.; Hu, Y. S. Origin of air-stability for transition metal oxide cathodes in sodium-ion batteries. ACS Appl. Mater. Interfaces 2022, 14, 5338–5345.

    Article  CAS  PubMed  Google Scholar 

  92. You, Y.; Dolocan, A.; Li, W. D.; Manthiram, A. Understanding the air-exposure degradation chemistry at a nanoscale of layered oxide cathodes for sodium-ion batteries. Nano Lett. 2019, 19, 182–188.

    Article  CAS  PubMed  ADS  Google Scholar 

  93. Sun, Y.; Wang, H.; Meng, D. C.; Li, X. Q.; Liao, X. Z.; Che, H. Y.; Cui, G. J.; Yu, F. P.; Yang, W. M.; Li, L. S. et al. Degradation mechanism of O3-type NaNi1/3Fe1/3Mn1/3O2 cathode materials during ambient storage and their in situ regeneration. ACS Appl. Energy Mater. 2021, 4, 2061–2067.

    Article  CAS  Google Scholar 

  94. Lee, S.; Doo, S. W.; Jung, M. S.; Lim, S. G.; Kim, K.; Lee, K. T. Direct observation of the in-plane crack formation of O3-Na0.8Mg0.2Fe0.4Mn0.4O2 due to oxygen gas evolution for Na-ion batteries. J. Mater. Chem. A 2021, 9, 14074–14084.

    Article  CAS  Google Scholar 

  95. Singer, A.; Zhang, M.; Hy, S.; Cela, D.; Fang, C.; Wynn, T. A.; Qiu, B.; Xia, Y.; Liu, Z.; Ulvestad, A. et al. Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging. Nat. Energy 2018, 3, 641–647.

    Article  CAS  ADS  Google Scholar 

  96. Lu, X.; Wang, Y. S.; Liu, P.; Gu, L.; Hu, Y. S.; Li, H.; Demopoulos, G. P.; Chen, L. Q. Direct imaging of layered O3- and P2-NaxFe1/2Mn1/2O2 structures at the atomic scale. Phys. Chem. Chem. Phys. 2014, 16, 21946–21952.

    Article  CAS  PubMed  Google Scholar 

  97. Mu, L. Q.; Feng, X.; Kou, R. H.; Zhang, Y.; Guo, H.; Tian, C. X.; Sun, C. J.; Du, X. W.; Nordlund, D.; Xin, H. L. et al. Deciphering the cathode-electrolyte interfacial chemistry in sodium layered cathode materials. Adv. Energy Mater. 2018, 8, 1801975.

    Article  Google Scholar 

  98. You, Y.; Xin, S.; Asl, H. Y.; Li, W. D.; Wang, P. F.; Guo, Y. G.; Manthiram, A. Insights into the improved high-voltage performance of Li-incorporated layered oxide cathodes for sodium-ion batteries. Chem 2018, 4, 2124–2139.

    Article  CAS  Google Scholar 

  99. Ji, H. C.; Zhai, J. J.; Chen, G. J.; Qiu, X.; Fang, H.; Zhang, T.; Huang, Z. Y.; Zhao, W. G.; Wang, Z. H.; Chu, M. H. et al. Surface engineering suppresses the failure of biphasic sodium layered cathode for high performance sodium-ion batteries. Adv. Funct. Mater. 2022, 32, 2109319.

    Article  CAS  Google Scholar 

  100. Feng, J.; Luo, S. H.; Sun, M. Y.; Cong, J.; Yan, S. X.; Wang, Q.; Zhang, Y. H.; Liu, X.; Mu, W. N.; Hou, P. Q. Investigation of Tisubstitution and MnPO4 coating effects on structural and electrochemical properties of P2-Na0.67TixNi0.33Mn067−xO2 cathode materials. Appl. Surf. Sci. 2022, 600, 154147.

    Article  CAS  Google Scholar 

  101. Sun, H. H.; Hwang, J. Y.; Yoon, C. S.; Heller, A.; Mullins, C. B. Capacity degradation mechanism and cycling stability enhancement of AlF3-coated nanorod gradient Na[Ni0.65Co0.08Mn0.27]O2 cathode for sodium-ion batteries. ACS Nano 2018, 12, 12912–12922.

    Article  CAS  PubMed  Google Scholar 

  102. Yuan, T.; Sun, Y. Y.; Li, S. Q.; Che, H. Y.; Zheng, Q. F.; Ni, Y. J.; Zhang, Y. X.; Zou, J.; Zang, X. X.; Wei, S. H. et al. Moisture stable and ultrahigh-rate Ni/Mn-based sodium-ion battery cathodes via K+ decoration. Nano Res. 2023, 16, 6890–6902.

    Article  CAS  ADS  Google Scholar 

  103. Kim, H. G.; Lee, H. B. R. Atomic layer deposition on 2D materials. Chem. Mater. 2017, 29, 3809–3826.

    Article  CAS  Google Scholar 

  104. Alvarado, J.; Ma, C. Z.; Wang, S.; Nguyen, K.; Kodur, M.; Meng, Y. S. Improvement of the cathode electrolyte interphase on P2-Na2/3Ni1/3Mn2/3O2 by atomic layer deposition. ACS Appl. Mater. Interfaces 2017, 9, 26518–26530.

    Article  CAS  PubMed  Google Scholar 

  105. Kaliyappan, K.; Liu, J.; Lushington, A.; Li, R. Y.; Sun, X. L. Highly stable Na2/3(Mn0.54Ni0.13Co0.13)O2 cathode modified by atomic layer deposition for sodium-ion batteries. ChemSusChem 2015, 8, 2537–2543.

    Article  CAS  PubMed  Google Scholar 

  106. Kaliyappan, K.; Liu, J.; Xiao, B. W.; Lushington, A.; Li, R. Y.; Sham, T. K.; Sun, X. L. Enhanced performance of P2-Na0.66(Mn0.54Co0.13Ni0.13)O2 cathode for sodium-ion batteries by ultrathin metal oxide coatings via atomic layer deposition. Adv. Funct. Mater. 2017, 27, 1701870.

    Article  Google Scholar 

  107. Lee, B. H.; Yoon, B.; Anderson, V. R.; George, S. M. Alucone alloys with tunable properties using alucone molecular layer deposition and Al2O3 atomic layer deposition. J. Phys. Chem. C 2012, 116, 3250–3257.

    Article  CAS  Google Scholar 

  108. Lee, B. H.; Yoon, B.; Abdulagatov, A. I.; Hall, R. A.; George, S. M. Growth and properties of hybrid organic-inorganic metalcone films using molecular layer deposition techniques. Adv. Funct. Mater. 2013, 23, 532–546.

    Article  CAS  Google Scholar 

  109. Kaliyappan, K.; Or, T.; Deng, Y. P.; Hu, Y. F.; Bai, Z. Y.; Chen, Z. W. Constructing safe and durable high-voltage P2 layered cathodes for sodium ion batteries enabled by molecular layer deposition of alucone. Adv. Funct. Mater. 2020, 30, 1910251.

    Article  CAS  Google Scholar 

  110. Zhang, Y.; Pei, Y.; Liu, W.; Zhang, S.; Xie, J. J.; Xia, J.; Nie, S.; Liu, L.; Wang, X. Y. AlPO4-coated P2-type hexagonal Na0.7MnO2.05 as high stability cathode for sodium ion battery. Chem. Eng. J. 2020, 382, 122697.

    Article  CAS  Google Scholar 

  111. Wang, Y.; Tang, K.; Li, X. L.; Yu, R. Z.; Zhang, X. H.; Huang, Y.; Chen, G. R.; Jamil, S.; Cao, S.; Xie, X. et al. Improved cycle and air stability of P3-Na0.65Mn0.75Ni0.25 O2 electrode for sodium-ion batteries coated with metal phosphates. Chem. Eng. J. 2019, 372, 1066–1076.

    Article  CAS  Google Scholar 

  112. Shao, Y. Q.; Wang, X. X.; Li, B. C.; Ma, H. R.; Chen, J. J.; Wang, D. J.; Dong, C. L.; Mao, Z. Y. Functional surface modification of P2-type layered Mn-based oxide cathode by thin layer of NASICON for sodium-ion batteries. Electrochim. Acta 2023, 442, 141915.

    Article  CAS  Google Scholar 

  113. Deng, Q.; Zheng, F. H.; Zhong, W. T.; Pan, Q. C.; Liu, Y. Z.; Li, Y. P.; Li, Y. J.; Hu, J. H.; Yang, C. H.; Liu, M. L. Nanoscale surface modification of P2-type Na0.65[Mn0.70Ni0.16Co0.14]O2 cathode material for high-performance sodium-ion batteries. Chem. Eng. J. 2021, 404, 126446.

    Article  CAS  Google Scholar 

  114. Tang, K.; Huang, Y.; Xie, X.; Cao, S.; Liu, L.; Liu, M.; Huang, Y. H.; Chang, B. B.; Luo, Z. G.; Wang, X. Y. The effects of dual modification on structure and performance of P2-type layered oxide cathode for sodium-ion batteries. Chem. Eng. J. 2020, 384, 123234.

    Article  CAS  Google Scholar 

  115. Quyen, N. Q.; Van Nguyen, T.; Thang, H. H.; Thao, P. M.; Van Nghia, N. Carbon coated NaLi0.2Mn0.8O2 as a superb cathode material for sodium ion batteries. J. Alloys Compd. 2021, 866, 158950.

    Article  CAS  Google Scholar 

  116. Lin, J. L.; Huang, Q.; Dai, K.; Feng, Y. M.; Luo, X.; Zhou, L. J.; Chen, L. B.; Liang, C. P.; Zhang, C. X.; Wei, W. F. Mitigating interfacial instability of high-voltage sodium layered oxide cathodes with coordinative polymeric structure. J. Power Sources 2022, 552, 232235.

    Article  CAS  Google Scholar 

  117. Jayachitra, J.; Richards Joshua, J.; Balamurugan, A.; Sivakumar, N.; Sharmila, V.; Shanavas, S.; Abu Haija, M.; Waqas Alam, M.; BaQais, A. High electrode performance of hydrothermally developed activated C coated O3-NaFeO2 electrode for Na-ion batteries applications. Ceram. Int. 2023, 49, 48–56.

    Article  CAS  Google Scholar 

  118. Lu, D.; Yao, Z. J.; Zhong, Y.; Wang, X. L.; Xia, X. H.; Gu, C. D.; Wu, J. B.; Tu, J. P. Polypyrrole-coated sodium manganate hollow microspheres as a superior cathode for sodium ion batteries. ACS Appl. Mater. Interfaces 2019, 11, 15630–15637.

    Article  CAS  PubMed  Google Scholar 

  119. Lu, D.; Yao, Z. J.; Li, Y. Q.; Zhong, Y.; Wang, X. L.; Xie, D.; Xia, X. H.; Gu, C. D.; Tu, J. P. Sodium-rich manganese oxide porous microcubes with polypyrrole coating as a superior cathode for sodium ion full batteries. J. Colloid Interface Sci. 2020, 565, 218–226.

    Article  CAS  PubMed  ADS  Google Scholar 

  120. Su, K.; Chen, J.; Zhang, X.; Feng, J. Z.; Xu, Y. T.; Pu, Y. X.; Wang, C. S.; Ma, P. J.; Wang, Y.; Lang, J. W. Inhibition of zinc dendrites by dopamine modified hexagonal boron nitride electrolyte additive for zinc-ion batteries. J. Power Sources 2022, 548, 232074.

    Article  CAS  Google Scholar 

  121. Hailu Mengesha, T.; Lemma Beshahwured, S.; Wu, Y. S.; Wu, S. H.; Jose, R.; Yang, C. C. A polydopamine-modified garnet-based polymer-in-ceramic hybrid solid electrolyte membrane for high-safety lithium metal batteries. Chem. Eng. J. 2023, 452, 139340.

    Article  CAS  Google Scholar 

  122. Qian, H. M.; Ren, H. Q.; Zhang, Y.; He, X. F.; Li, W. B.; Wang, J. J.; Hu, J. H.; Yang, H.; Sari, H. M. K.; Chen, Y. et al. Surface doping vs. bulk doping of cathode materials for lithium-ion batteries: A review. Electrochem. Energy Rev. 2022, 5, 2.

    Article  CAS  Google Scholar 

  123. Du, X. Y.; Meng, Y.; Yuan, H. Y.; Xiao, D. High-entropy substitution: A strategy for advanced sodium-ion cathodes with high structural stability and superior mechanical properties. Energy Storage Mater. 2023, 56, 132–140.

    Article  Google Scholar 

  124. Zhou, Y. N.; Xiao, Z. C.; Han, D. Z.; Wang, S. N.; Chen, J. N.; Tang, W.; Yang, M. Y.; Shao, L.; Shu, C. Y.; Hua, W. B. et al. Inhibition of the P3-O3 phase transition via local symmetry tuning in P3-type layered cathodes for ultra-stable sodium storage. J. Mater. Chem. A 2023, 11, 2618–2626.

    Article  CAS  Google Scholar 

  125. Shen, M. Y.; Wang, J. S.; Ren, Z. H.; Wu, T.; Liu, X.; Chen, L. W.; Li, W. C.; Lu, A. H. Quasi-zero volume strain cathode materials for sodium ion battery through synergetic substitution effect of Li and Mg. Adv. Funct. Mater., in press, DOI: https://doi.org/10.1002/adfm.202303812.

  126. Zhao, Q. Q.; Butt, F. K.; Guo, Z. F.; Wang, L. Q.; Zhu, Y. Q.; Xu, X. Y.; Ma, X. L.; Cao, C. B. High-voltage P2-type manganese oxide cathode induced by titanium gradient modification for sodium ion batteries. Chem. Eng. J. 2021, 403, 126308.

    Article  CAS  Google Scholar 

  127. Jiao, J. Y.; Wu, K.; Li, N.; Zhao, E. Y.; Yin, W.; Hu, Z. B.; Wang, F. W.; Zhao, J. K.; Xiao, X. L. Tuning anionic redox activity to boost high-performance sodium-storage in low-cost Na0.67Fe0.5Mn0.5O2 cathode. J. Energy Chem. 2022, 73, 214–222.

    Article  CAS  Google Scholar 

  128. Shi, Q. H.; Qi, R. J.; Feng, X. C.; Wang, J.; Li, Y.; Yao, Z. P.; Wang, X.; Li, Q. Q.; Lu, X. G.; Zhang, J. J. et al. Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries. Nat. Commun. 2022, 13, 3205.

    Article  PubMed  PubMed Central  ADS  Google Scholar 

  129. Wang, L. J.; Zhang, X.; Yang, X. H.; Wang, J. L.; Deng, J. Y.; Wang, Y. Z. Co3O4-modified P2-Na2/3Mn0.75Co0.25 O2 cathode for Na-ion batteries with high capacity and excellent cyclability. J. Alloys Compd. 2020, 832, 154960.

    Article  CAS  Google Scholar 

  130. Yu, H.; Walsh, M.; Liang, X. H. Improving the comprehensive performance of Na0.7MnO2 for sodium ion batteries by ZrO2 atomic layer deposition. ACS Appl. Mater. Interfaces 2021, 13, 54884–54893.

    Article  CAS  PubMed  Google Scholar 

  131. Ma, Z. L.; Xu, H. X.; Liu, Y. X.; Zhang, Q.; Wang, M. T.; Lin, Y. C.; Li, Z.; He, X. X.; Sun, J.; Jiang, R. B. et al. Defect-type AlOx nanointerface boosting layered Mn-based oxide cathode for wide-temperature sodium-ion battery. J. Mater. Chem. A 2022, 10, 24216–24225.

    Article  CAS  Google Scholar 

  132. Li, N.; Wang, S. F.; Zhao, E. Y.; Yin, W.; Zhang, Z. G.; Wu, K.; Xu, J. P.; Kuroiwa, Y.; Hu, Z. B.; Wang, F. W. et al. Tailoring interphase structure to enable high-rate, durable sodium-ion battery cathode. J. Energy Chem. 2022, 68, 564–571.

    Article  CAS  Google Scholar 

  133. Hwang, J. Y.; Yu, T. Y.; Sun, Y. K. Simultaneous MgO coating and Mg doping of Na[Ni0.5Mn0.5]O2 cathode: Facile and customizable approach to high-voltage sodium-ion batteries. J. Mater. Chem. A 2018, 6, 16854–16862.

    Article  CAS  Google Scholar 

  134. Zhang, J. L.; Yu, D. Y. W. Stabilizing Na0.7MnO2 cathode for Na-ion battery via a single-step surface coating and doping process. J. Power Sources 2018, 391, 106–112.

    Article  CAS  ADS  Google Scholar 

  135. Dang, R. B.; Li, Q.; Chen, M. M.; Hu, Z. B.; Xiao, X. L. CuO-coated and Cu2+-doped Co-modified P2-type Na2/3[Ni1/3Mn2/3]O2 for sodium-ion batteries. Phys. Chem. Chem. Phys. 2019, 21, 314–321.

    Article  CAS  Google Scholar 

  136. Yu, Y.; Ning, D.; Li, Q. Y.; Franz, A.; Zheng, L. R.; Zhang, N.; Ren, G. X.; Schumacher, G.; Liu, X. F. Revealing the anionic redox chemistry in O3-type layered oxide cathode for sodium-ion batteries. Energy Storage Mater. 2021, 38, 130–140.

    Article  Google Scholar 

  137. Kong, W. J.; Yang, W. Y.; Ning, D.; Li, Q. Y.; Zheng, L. R.; Yang, J. B.; Sun, K.; Chen, D. F.; Liu, X. F. Tuning anionic/cationic redox chemistry in a P2-type Na0.67Mn0.5Fe0.5O2 cathode material via a synergic strategy. Sci. China Mater. 2020, 63, 1703–1718.

    Article  CAS  Google Scholar 

  138. Li, Z. R.; Kong, W. J.; Yu, Y.; Zhang, J. C.; Wong, D.; Xu, Z. J.; Chen, Z. H.; Schulz, C.; Bartkowiak, M.; Liu, X. F. Tuning bulk O2 and nonbonding oxygen state for reversible anionic redox chemistry in P2-layered cathodes. Angew. Chem., Int. Ed. 2022, 61, e202115552.

    Article  CAS  ADS  Google Scholar 

  139. Zhang, W.; Sun, Y. G.; Deng, H. Q.; Ma, J. M.; Zeng, Y.; Zhu, Z. Q.; Lv, Z. S.; Xia, H. R.; Ge, X.; Cao, S. K. et al. Dielectric polarization in inverse spinel-structured Mg2TiO4 coating to suppress oxygen evolution of Li-rich cathode materials. Adv. Mater. 2020, 32, 2000496.

    Article  CAS  Google Scholar 

  140. Jiao, J. Y.; Wu, K.; Dang, R. B.; Li, N.; Deng, X.; Liu, X. F.; Hu, Z. B.; Xiao, X. L. A collaborative strategy with ionic conductive Na2SiO3 coating and Si doping of P2-Na0.67Fe0.5Mn0.5O2 cathode: An effective solution to capacity attenuation. Electrochim. Acta 2021, 384, 138362.

    Article  CAS  Google Scholar 

  141. Hu, S. J.; Li, Y.; Chen, Y. H.; Peng, J. M.; Zhou, T. F.; Pang, W. K.; Didier, C.; Peterson, V. K.; Wang, H. Q.; Li, Q. Y. et al. Insight of a phase compatible surface coating for long-durable Li-rich layered oxide cathode. Adv. Energy Mater. 2019, 9, 1901795.

    Article  Google Scholar 

  142. Xia, F.; Tie, D.; Wang, J.; Song, H. L.; Wen, W.; Ye, X. X.; Wu, J. S.; Hou, Y. L.; Lu, X. G.; Zhao, Y. F. Ultrahigh rate and durable sodium-ion storage at a wide potential window via lanthanide doping and perovskite surface decoration on layered manganese oxides. Energy Storage Mater. 2021, 42, 209–218.

    Article  Google Scholar 

  143. Xia, X.; Liu, T.; Cheng, C.; Li, H. T.; Yan, T. R.; Hu, H. L.; Shen, Y. H.; Ju, H. X.; Chan, T. S.; Wu, Z. W. et al. Suppressing the dynamic oxygen evolution of sodium layered cathodes through synergistic surface dielectric polarization and bulk site-selective Co-doping. Adv. Mater. 2023, 35, 2209556.

    Article  CAS  Google Scholar 

  144. Hwang, J. Y.; Oh, S. M.; Myung, S. T.; Chung, K. Y.; Belharouak, I.; Sun, Y. K. Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries. Nat. Commun. 2015, 6, 6865.

    Article  CAS  PubMed  ADS  Google Scholar 

  145. Li, X. Y.; Liang, L. W.; Su, M. S.; Wang, L. X.; Zhang, Y. M.; Sun, J. F.; Liu, Y.; Hou, L. R.; Yuan, C. Z. Multi-level modifications enabling chemomechanically stable Ni-rich O3-layered cathode toward wide-temperature-tolerance quasi-solid-state Na-ion batteries. Adv. Energy Mater. 2023, 13, 2203701.

    Article  CAS  Google Scholar 

  146. Bao, S.; Luo, S. H.; Wang, Z. Y.; Yan, S. X.; Wang, Q.; Li, J. Y. Novel P2-type concentration-gradient Na0.67Ni0.167Co0.167Mn0.67O2 modified by Mn-rich surface as cathode material for sodium ion batteries. J. Power Sources 2018, 396, 404–411.

    Article  CAS  ADS  Google Scholar 

  147. Wu, T. H.; Zhang, X.; Wang, Y. Z.; Zhang, N.; Li, H. F.; Guan, Y.; Xiao, D. D.; Liu, S. Q.; Yu, H. J. Gradient “single-crystal” Li-rich cathode materials for high-stable lithium-ion batteries. Adv. Funct. Mater. 2023, 33, 2210154.

    Article  CAS  Google Scholar 

  148. Wang, D.; Deng, Y. P.; Liu, Y. H.; Jiang, Y.; Zhong, B. H.; Wu, Z. G.; Guo, X. D.; Chen, Z. W. Sodium-ion batteries towards practical application through gradient Mn-based layer-tunnel cathode. Nano Energy 2023, 110, 108340.

    Article  CAS  Google Scholar 

  149. Wu, K.; Li, N.; Hao, K. R.; Yin, W.; Wang, M.; Jia, G. F.; Lee, Y. L.; Dang, R. B.; Deng, X.; Xiao, X. L. et al. Multiple influences of nickel concentration gradient structure and yttrium element substitution on the structural and electrochemical performances of the NaNi0.25Mn0.25Fe0.5O2 cathode material. J. Phys. Chem. C 2021, 125, 20171–20183.

    Article  CAS  Google Scholar 

  150. Chen, C.; Han, Z.; Chen, S. Q.; Qi, S.; Lan, X. Y.; Zhang, C. C.; Chen, L.; Wang, P.; Wei, W. F. Core-shell layered oxide cathode for high-performance sodium-ion batteries. ACS Appl. Mater. Interfaces 2020, 12, 7144–7152.

    Article  CAS  PubMed  Google Scholar 

  151. Liang, X. H.; Yu, T. Y.; Ryu, H. H.; Sun, Y. K. Hierarchical O3/P2 heterostructured cathode materials for advanced sodium-ion batteries. Energy Storage Mater. 2022, 47, 515–525.

    Article  Google Scholar 

  152. Lin, Z. H.; Xia, Q. B.; Wang, W. L.; Li, W. S.; Chou, S. L. Recent research progresses in ether- and ester-based electrolytes for sodium-ion batteries. InfoMat 2019, 1, 376–389.

    Article  CAS  Google Scholar 

  153. Wang, E. H.; Niu, Y. B.; Yin, Y. X.; Guo, Y. G. Manipulating electrode/electrolyte interphases of sodium-ion batteries: Strategies and perspectives. ACS Mater. Lett. 2021, 3, 18–41.

    Article  CAS  Google Scholar 

  154. Eshetu, G. G.; Martinez-Ibañez, M.; Sánchez-Diez, E.; Gracia, I.; Li, C. M.; Rodriguez-Martinez, L. M.; Rojo, T.; Zhang, H.; Armand, M. Electrolyte additives for room-temperature, sodium-based, rechargeable batteries. Chem.—Asian J. 2018, 13, 2770–2780.

    Article  CAS  PubMed  Google Scholar 

  155. Song, J. H.; Xiao, B. W.; Lin, Y. H.; Xu, K.; Li, X. L. Interphases in sodium-ion batteries. Adv. Energy Mater. 2018, 8, 1703082.

    Article  Google Scholar 

  156. Liu, Q.; Wu, F.; Mu, D. B.; Wu, B. R. A theoretical study on Na+ solvation in carbonate ester and ether solvents for sodium-ion batteries. Phys. Chem. Chem. Phys. 2020, 22, 2164–2175.

    Article  CAS  PubMed  ADS  Google Scholar 

  157. Mosallanejad, B.; Malek, S. S.; Ershadi, M.; Daryakenari, A. A.; Cao, Q.; Boorboor Ajdari, F.; Ramakrishna, S. Cycling degradation and safety issues in sodium-ion batteries: Promises of electrolyte additives. J. Electroanal. Chem. 2021, 895, 115505.

    Article  CAS  Google Scholar 

  158. Zhu, C. L.; Wu, D. X.; Wang, Z. S.; Wang, H. P.; Liu, J. D.; Guo, K. L.; Liu, Q. H.; Ma, J. M. Optimizing NaF-rich solid electrolyte interphase for stabilizing sodium metal batteries by electrolyte additive. Adv. Funct. Mater., in press, DOI: https://doi.org/10.1002/adfm.202214195.

  159. von Aspern, N.; Röschenthaler, G. V.; Winter, M.; Cekic-Laskovic, I. Fluorine and lithium: Ideal partners for high-performance rechargeable battery electrolytes. Angew. Chem., Int. Ed. 2019, 58, 15978–16000.

    Article  CAS  Google Scholar 

  160. Pahari, D.; Chowdhury, A.; Das, D.; Paul, T.; Puravankara, S. The evolution of structure–property relationship of P2-type Na0.67Ni0.33Mn0.67O2 by vanadium substitution and organic electrolyte combinations for sodium-ion batteries. J. Solid State Electrochem. 2023, 27, 2067–2082.

    Article  CAS  Google Scholar 

  161. Zhao, X. X.; Gu, Z. Y.; Guo, J. Z.; Wang, X. T.; Liang, H. J.; Xie, D.; Li, W. H.; Jia, W. Q.; Wu, X. L. Constructing bidirectional fluorine-rich electrode/electrolyte interphase via solvent redistribution toward long-term sodium battery. Energy Environ. Mater., in press, DOI: https://doi.org/10.1002/eem2.12474.

  162. Zhang, Z. C.; Hu, L. B.; Wu, H. M.; Weng, W.; Koh, M.; Redfern, P. C.; Curtiss, L. A.; Amine, K. Fluorinated electrolytes for 5 V lithium-ion battery chemistry. Energy Environ. Sci. 2013, 6, 1806–1810.

    Article  CAS  Google Scholar 

  163. Fan, X. L.; Chen, L.; Ji, X.; Deng, T.; Hou, S.; Chen, J.; Zheng, J.; Wang, F.; Jiang, J. J.; Xu, K. et al. Highly fluorinated interphases enable high-voltage Li-metal batteries. Chem 2018, 4, 174–185.

    Article  CAS  Google Scholar 

  164. Kumar, H.; Detsi, E.; Abraham, D. P.; Shenoy, V. B. Fundamental mechanisms of solvent decomposition involved in solid–electrolyte interphase formation in sodium ion batteries. Chem. Mater. 2016, 28, 8930–8941.

    Article  CAS  Google Scholar 

  165. Wu, S. L.; Su, B. Z.; Ni, K.; Pan, F.; Wang, C. L.; Zhang, K. L.; Yu, D. Y. W.; Zhu, Y. W.; Zhang, W. J. Fluorinated carbonate electrolyte with superior oxidative stability enables long-term cycle stability of Na2/3Ni1/3Mn2/3O2 cathodes in sodium-ion batteries. Adv. Energy Mater. 2021, 11, 2002737.

    Article  CAS  Google Scholar 

  166. Zeng, Z. Q.; Jiang, X. Y.; Li, R.; Yuan, D. D.; Ai, X. P.; Yang, H. X.; Cao, Y. L. A safer sodium-ion battery based on nonflammable organic phosphate electrolyte. Adv. Sci. 2016, 3, 1600066.

    Article  Google Scholar 

  167. Shi, C. G.; Shen, C. H.; Peng, X. X.; Luo, C. X.; Shen, L. F.; Sheng, W. J.; Fan, J. J.; Wang, Q.; Zhang, S. J.; Xu, B. B. et al. A special enabler for boosting cyclic life and rate capability of LiNi0.8Co0.1Mn0.1O2: Green and simple additive. Nano Energy 2019, 65, 104084.

    Article  CAS  Google Scholar 

  168. Han, G. B.; Lee, J. N.; Lee, D. J.; Lee, H.; Song, J.; Lee, H.; Ryou, M. H.; Park, J. K.; Lee, Y. M. Enhanced cycling performance of lithium metal secondary batteries with succinic anhydride as an electrolyte additive. Electrochim. Acta 2014, 115, 525–530.

    Article  CAS  Google Scholar 

  169. Fan, J. J.; Dai, P.; Shi, C. G.; Wen, Y. F.; Luo, C. X.; Yang, J.; Song, C.; Huang, L.; Sun, S. G. Synergistic dual-additive electrolyte for interphase modification to boost cyclability of layered cathode for sodium ion batteries. Adv. Funct. Mater. 2021, 31, 2010500.

    Article  CAS  Google Scholar 

  170. Che, H. Y.; Yang, X. R.; Wang, H.; Liao, X. Z.; Zhang, S. S.; Wang, C. S.; Ma, Z. F. Long cycle life of sodium-ion pouch cell achieved by using multiple electrolyte additives. J. Power Sources 2018, 407, 173–179.

    Article  CAS  ADS  Google Scholar 

  171. Chen, J. E.; Huang, Z. G.; Wang, C. Y.; Porter, S.; Wang, B. F.; Lie, W.; Liu, H. K. Sodium-difluoro(oxalato)borate (NaDFOB): A new electrolyte salt for Na-ion batteries. Chem. Commun. 2015, 51, 9809–9812.

    Article  CAS  Google Scholar 

  172. Huang, Y. X.; Zhao, L. Z.; Li, L.; Xie, M.; Wu, F.; Chen, R. J. Electrolytes and electrolyte/electrode interfaces in sodium-ion batteries: From scientific research to practical application. Adv. Mater. 2019, 31, 1808393.

    Article  Google Scholar 

  173. Wang, S. M.; Li, C. L.; Fan, X. Q.; Wen, S. X.; Lu, H. L.; Dong, H.; Wang, J.; Quan, Y.; Li, S. Y. Selection of sodium salt electrolyte compatible with Na0.67Ni0.15Fe0.2Mn0.65O2 cathode for sodium-ion batteries. Energy Technol. 2021, 9, 2100190.

    Article  CAS  Google Scholar 

  174. Wang, J. H.; Yamada, Y.; Sodeyama, K.; Chiang, C. H.; Tateyama, Y.; Yamada, A. Superconcentrated electrolytes for a high-voltage lithium-ion battery. Nat. Commun. 2016, 7, 12032.

    Article  CAS  PubMed  PubMed Central  ADS  Google Scholar 

  175. Wang, J. H.; Yamada, Y.; Sodeyama, K.; Watanabe, E.; Takada, K.; Tateyama, Y.; Yamada, A. Fire-extinguishing organic electrolytes for safe batteries. Nat. Energy 2018, 3, 22–29.

    Article  CAS  ADS  Google Scholar 

  176. Chen, C.; Wu, M. Q.; Liu, J. H.; Xu, Z. Q.; Zaghib, K.; Wang, Y. S. Effects of ester-based electrolyte composition and salt concentration on the Na-storage stability of hard carbon anodes. J. Power Sources 2020, 471, 228455.

    Article  CAS  Google Scholar 

  177. Jia, H.; Kim, J. M.; Gao, P. Y.; Xu, Y. B.; Engelhard, M. H.; Matthews, B. E.; Wang, C. M.; Xu, W. A systematic study on the effects of solvating solvents and additives in localized high-concentration electrolytes over electrochemical performance of lithium-ion batteries. Angew. Chem., Int. Ed. 2023, 62, e202218005.

    Article  CAS  Google Scholar 

  178. Jin, Y.; Xu, Y. B.; Xiao, B. W.; Engelhard, M. H.; Yi, R.; Vo, T. D.; Matthews, B. E.; Li, X. L.; Wang, C. M.; Le, P. M. L. et al. Stabilizing interfacial reactions for stable cycling of high-voltage sodium batteries. Adv. Funct. Mater. 2022, 32, 2204995.

    Article  CAS  Google Scholar 

  179. Jin, Y.; Le, P. M. L.; Gao, P. Y.; Xu, Y. B.; Xiao, B. W.; Engelhard, M. H.; Cao, X.; Vo, T. D.; Hu, J. T.; Zhong, L. R. et al. Low-solvation electrolytes for high-voltage sodium-ion batteries. Nat. Energy 2022, 7, 718–725.

    Article  CAS  Google Scholar 

  180. Hou, B. H.; Wang, Y. Y.; Ning, Q. L.; Li, W. H.; Xi, X. T.; Yang, X.; Liang, H. J.; Feng, X.; Wu, X. L. Self-supporting, flexible, additive-free, and scalable hard carbon paper self-interwoven by 1D microbelts: Superb room/low-temperature sodium storage and working mechanism. Adv. Mater. 2019, 31, 1903125.

    Article  CAS  Google Scholar 

  181. Dong, R. Q.; Zheng, L. M.; Bai, Y.; Ni, Q.; Li, Y.; Wu, F.; Ren, H. X.; Wu, C. Elucidating the mechanism of fast Na storage kinetics in ether electrolytes for hard carbon anodes. Adv. Mater. 2021, 33, 2008810.

    Article  CAS  Google Scholar 

  182. Hirsh, H. S.; Sayahpour, B.; Shen, A.; Li, W. K.; Lu, B. Y.; Zhao, E. Y.; Zhang, M. H.; Meng, Y. S. Role of electrolyte in stabilizing hard carbon as an anode for rechargeable sodium-ion batteries with long cycle life. Energy Storage Mater. 2021, 42, 78–87.

    Article  Google Scholar 

  183. Hasa, I.; Dou, X. W.; Buchholz, D.; Shao-Horn, Y.; Hassoun, J.; Passerini, S.; Scrosati, B. A sodium-ion battery exploiting layered oxide cathode, graphite anode and glyme-based electrolyte. J. Power Sources 2016, 310, 26–31.

    Article  CAS  ADS  Google Scholar 

  184. Li, Y.; Wu, F.; Li, Y.; Liu, M. Q.; Feng, X.; Bai, Y.; Wu, C. Ether-based electrolytes for sodium ion batteries. Chem. Soc. Rev. 2022, 51, 4484–4536.

    Article  CAS  PubMed  Google Scholar 

  185. Liang, H. J.; Gu, Z. Y.; Zhao, X. X.; Guo, J. Z.; Yang, J. L.; Li, W. H.; Li, B.; Liu, Z. M.; Li, W. L.; Wu, X. L. Ether-based electrolyte chemistry towards high-voltage and long-life Na-ion full batteries. Angew. Chem., Int. Ed. 2021, 60, 26837–26846.

    Article  CAS  Google Scholar 

  186. Zheng, J. M.; Chen, S. R.; Zhao, W. G.; Song, J. H.; Engelhard, M. H.; Zhang, J. G. Extremely stable sodium metal batteries enabled by localized high-concentration electrolytes. ACS Energy Lett. 2018, 3, 315–321.

    Article  CAS  Google Scholar 

  187. Wang, Y. D.; Jiang, R.; Liu, Y. C.; Zheng, H.; Fang, W.; Liang, X.; Sun, Y.; Zhou, R. L.; Xiang, H. F. Enhanced sodium metal/electrolyte interface by a localized high-concentration electrolyte for sodium metal batteries: First-principles calculations and experimental studies. ACS Appl. Energy Mater. 2021, 4, 7376–7384.

    Article  CAS  Google Scholar 

  188. Song, J. H.; Wang, K.; Zheng, J. M.; Engelhard, M. H.; Xiao, B. W.; Hu, E. Y.; Zhu, Z. H.; Wang, C. M.; Sui, M. L.; Lin, Y. H. et al. Controlling surface phase transition and chemical reactivity of O3-layered metal oxide cathodes for high-performance Na-ion batteries. ACS Energy Lett. 2020, 5, 1718–1725.

    Article  CAS  Google Scholar 

  189. Yamada, Y.; Wang, J. H.; Ko, S.; Watanabe, E.; Yamada, A. Advances and issues in developing salt-concentrated battery electrolytes. Nat. Energy 2019, 4, 269–280.

    Article  CAS  ADS  Google Scholar 

  190. Cui, C. Y.; Fan, X. L.; Zhou, X. Q.; Chen, J.; Wang, Q. C.; Ma, L.; Yang, C. Y.; Hu, E. Y.; Yang, X. Q.; Wang, C. S. Structure and interface design enable stable Li-rich cathode. J. Am. Chem. Soc. 2020, 142, 8918–8927.

    Article  CAS  PubMed  Google Scholar 

  191. Zhao, C.; Li, C.; Liu, H.; Qiu, Q.; Geng, F. S.; Shen, M.; Tong, W.; Li, J. X.; Hu, B. W. Coexistence of (O2)n− and trapped molecular O2 as the oxidized species in P2-type sodium 3d layered oxide and stable interface enabled by highly fluorinated electrolyte. J. Am. Chem. Soc. 2021, 143, 18652–18664.

    Article  CAS  PubMed  Google Scholar 

  192. Lamb, J.; Manthiram, A. Stable sodium-based batteries with advanced electrolytes and layered-oxide cathodes. ACS Appl. Mater. Interfaces 2022, 14, 28865–28872.

    Article  CAS  PubMed  Google Scholar 

  193. Feng, J. K.; Zhang, Z.; Li, L. F.; Yang, J.; Xiong, S. L.; Qian, Y. T. Ether-based nonflammable electrolyte for room temperature sodium battery. J. Power Sources 2015, 284, 222–226.

    Article  CAS  ADS  Google Scholar 

  194. Liu, X. W.; Jiang, X. Y.; Zhong, F. P.; Feng, X. M.; Chen, W. H.; Ai, X. P.; Yang, H. X.; Cao, Y. L. High-safety symmetric sodium-ion batteries based on nonflammable phosphate electrolyte and double Na3V2(PO4)3 electrodes. ACS Appl. Mater. Interfaces 2019, 11, 27833–27838.

    Article  CAS  PubMed  Google Scholar 

  195. Yu, Y.; Che, H. Y.; Yang, X. R.; Deng, Y. H.; Li, L. S.; Ma, Z. F. Non-flammable organic electrolyte for sodium-ion batteries. Electrochem. Commun. 2020, 110, 106635.

    Article  CAS  Google Scholar 

  196. Jin, Y.; Xu, Y. B.; Le, P. M. L.; Vo, T. D.; Zhou, Q.; Qi, X. G.; Engelhard, M. H.; Matthews, B. E.; Jia, H.; Nie, Z. M. et al. Highly reversible sodium ion batteries enabled by stable electrolyte-electrode interphases. ACS Energy Lett. 2020, 5, 3212–3220.

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 52173273), Fundamental Research Funds for the Central Universities (No. 2022CX11013), Shanxi Province Science Foundation for Youths (No. 202203021212391), the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (No. 2022L253), and Institute Foundation Project of China Academy of Railway Sciences Corporation Limited Metals and Chemistry Research Institute (No. 2023SJ02).

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  1. Quanqing Zhao and Ruru Wang contributed equally to this work.

Authors and Affiliations

  1. Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education, School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan, 030032, China

    Quanqing Zhao, Ruru Wang, Jianfeng Jia & Haishun Wu

  2. Metals and Chemistry Research Institute, China Academy of Railway Sciences Corporation Limited, Beijing, 100081, China

    Ming Gao

  3. Department of Physics, Division of Science and Technology, University of Education, Lahore, 54770, Pakistan

    Faheem K. Butt

  4. Research Center of Materials Science, Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, Beijing Institute of Technology, Beijing, 100081, China

    Youqi Zhu

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Zhao, Q., Wang, R., Gao, M. et al. Interfacial engineering of the layered oxide cathode materials for sodium-ion battery. Nano Res. 17, 1441–1464 (2024). https://doi.org/10.1007/s12274-023-6133-9

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