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Synthesis and characterization of hybrid latexes from soybean oil-based polyurethane and poly(2,2,2-trifluoroethyl methacrylate)

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Abstract

A class of novel fluorine containing core-shell hybrid latexes were obtained from soybean oil-based polyurethanes and poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA) by two-step synthesis under mild reaction conditions. Structural and morphology properties of the resulting hybrid latexs have been characterized by FT-IR and TEM. In addition, thermal properties (DSC, TGA) and coating performance (contact angle, stress-strain curve, and surface free energy) were investigated and discussed. The hybrid latexes exhibit outstanding thermal stability and coating performance. More importantly, through this method, low-valued foods are successfully transformed into high-valued functional materials which bring new solutions for preparing materials from renewable sources.

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Authors and Affiliations

  1. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, P.R. China

    Dan Yu, Le Wang, Jiafu Wang & Wei Wang

  2. The Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai, 201620, P.R. China

    Dan Yu & Wei Wang

  3. College of Materials Science and Engineering, Donghua University, Shanghai, 201620, P.R. China

    Bin Sun

Authors
  1. Dan Yu
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  2. Le Wang
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  3. Bin Sun
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  4. Jiafu Wang
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  5. Wei Wang
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Correspondence to Dan Yu.

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Yu, D., Wang, L., Sun, B. et al. Synthesis and characterization of hybrid latexes from soybean oil-based polyurethane and poly(2,2,2-trifluoroethyl methacrylate). Fibers Polym 15, 208–214 (2014). https://doi.org/10.1007/s12221-014-0208-x

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  • DOI: https://doi.org/10.1007/s12221-014-0208-x

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