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Development of combustion strategy for the internal combustion engine fueled by ammonia and its operating characteristics

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Abstract

Focusing on the possibility of using ammonia as a hydrogen carrier, a combustion strategy for pure ammonia as an engine fuel to convert the stored energy into a usable form has been proposed, which uses ammonia itself as a combustion promotor. Under this strategy, the conditions of sufficiently high temperature and pressure to cause the spray combustion of ammonia are obtained by the auto-ignition of a mixture of pilot-injected ammonia and air. To confirm the feasibility and the operating characteristics of an engine with the proposed ammonia combustion strategy, engine modeling has been conducted, the combustion strategy has been simulated, and a parametric study has been performed. To analyze the NO production mechanisms in an engine with the proposed combustion strategy, the NO production process has been classified into four phases, and the NO production in each phase has been analyzed under various start of injection timing and fuel amounts.

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References

  1. T. Mogi, D. Kim, H. Shiina and S. Horiguchi, Self-ignition and explosion during discharge of high-pressure hydrogen, Journal of Loss Prevention in the Process Industries, 21 (2008) 199–204.

    Article  Google Scholar 

  2. J. J. Reilly and G. D. Sandrock, Hydrogen storage in metal hydrides, Scientific American, 242 (1980) 118–131.

    Article  Google Scholar 

  3. B. Sakintuna, F. Lamari-Darkrim and M. Hirscher, Metal hydride materials for solid hydrogen storage: A review, International Journal of Hydrogen Energy, 32 (2007) 1121–1140.

    Article  Google Scholar 

  4. F. Schüth, B. Bogdanović and M. Felderhoff, Light metal hydrides and complex hydrides for hydrogen storage, Chemical Communications (2004) 2249–2258.

    Google Scholar 

  5. J. Zheng, X. Liu, P. Xu, P. Liu, Y. Zhao and J. Yang, Development of high pressure gaseous hydrogen storage technologies, International Journal of Hydrogen Energy, 37 (2012) 1048–1057.

    Article  Google Scholar 

  6. S. O. Akansu, Z. Dulger, N. Kahraman and T. N. Veziroǧlu Internal combustion engines fueled by natural gas— hydrogen mixtures, International Journal of Hydrogen Energy, 29 (2004) 1527–1539.

    Article  Google Scholar 

  7. L. Das, R. Gulati and P. K. Gupta, A comparative evaluation of the performance characteristics of a spark ignition engine using hydrogen and compressed natural gas as alternative fuels, International Journal of Hydrogen Energy, 25 (2000) 783–793.

    Article  Google Scholar 

  8. J. W. Heffel, NOx emission reduction in a hydrogen fueled internal combustion engine at 3000 rpm using exhaust gas recirculation, International Journal of Hydrogen Energy, 28 (2003) 1285–1292.

    Article  Google Scholar 

  9. G. A. Karim, Hydrogen as a spark ignition engine fuel, International Journal of Hydrogen Energy, 28 (2003) 569–577.

    Article  Google Scholar 

  10. S. Lee, H. Yi and E. Kim, Combustion characteristics of intake port injection type hydrogen fueled engine, International Journal of Hydrogen Energy, 20 (1995) 317–322.

    Article  Google Scholar 

  11. R. K. Ahluwalia and X. Wang, Direct hydrogen fuel cell systems for hybrid vehicles, Journal of Power Sources, 139 (2005) 152–164.

    Article  Google Scholar 

  12. P. Corbo, F. Migliardini and O. Veneri, Experimental analysis and management issues of a hydrogen fuel cell system for stationary and mobile application, Energy Conversion and Management, 48 (2007) 2365–2374.

    Article  Google Scholar 

  13. B. Xing and O. Savadogo, Hydrogen/oxygen polymer electrolyte membrane fuel cells (PEMFCs) based on alkalinedoped polybenzimidazole (PBI), Electrochemistry Communications, 2 (2000) 697–702.

    Article  Google Scholar 

  14. J. R. Bartels, A feasibility study of implementing an ammonia economy, Iowa State University (2008).

    Google Scholar 

  15. M. Comotti and S. Frigo, Hydrogen generation system for ammonia-hydrogen fuelled internal combustion engines, International Journal of Hydrogen Energy, 40 (2015) 10673–10686.

    Article  Google Scholar 

  16. S. El-Emam and A. Desoky, A study on the combustion of alternative fuels in spark-ignition engines, International Journal of Hydrogen Energy, 10 (1985) 497–504.

    Article  Google Scholar 

  17. S. Frigo and R. Gentili, Analysis of the behaviour of a 4- stroke Si engine fuelled with ammonia and hydrogen, International Journal of Hydrogen Energy, 38 (2013) 1607–1615.

    Article  Google Scholar 

  18. S. Gill, G. Chatha, A. Tsolakis, S. Golunski and A. York, Assessing the effects of partially decarbonising a diesel engine by co-fuelling with dissociated ammonia, International Journal of Hydrogen Energy, 37 (2012) 6074–6083.

    Article  Google Scholar 

  19. S. M. Grannell, D. N. Assanis, S. V. Bohac and D. E. Gillespie, The fuel mix limits and efficiency of a stoichiometric, ammonia, and gasoline dual fueled spark ignition engine, Journal of Engineering for Gas Turbines and Power, 130 (2008) 042802.

    Article  Google Scholar 

  20. J. T. Gray, E. Dimitroff, N. T. Meckel and R. Quillian, Ammonia fuel-engine compatibility and combustion, SAE Technical Paper (1966).

    Google Scholar 

  21. C. W. Gross and S.-C. Kong, Performance characteristics of a compression-ignition engine using direct-injection ammonia-DME mixtures, Fuel, 103 (2013) 1069–1079.

    Article  Google Scholar 

  22. S. O. Haputhanthri, T. T. Maxwell, J. Fleming and C. Austin, Ammonia and gasoline fuel blends for spark ignited internal combustion engines, Journal of Energy Resources Technology, 137 (2015) 062201.

    Article  Google Scholar 

  23. C. S. Mørch, A. Bjerre, M. P. Gøttrup, S. C. Sorenson and J. Schramm, Ammonia/hydrogen mixtures in an SI-engine: Engine performance and analysis of a proposed fuel system, Fuel, 90 (2011) 854–864.

    Article  Google Scholar 

  24. A. J. Reiter and S.-C. Kong, Demonstration of compression- ignition engine combustion using ammonia in reducing greenhouse gas emissions, Energy & Fuels, 22 (2008) 2963–2971.

    Article  Google Scholar 

  25. A. J. Reiter and S.-C. Kong, Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel, Fuel, 90 (2011) 87–97.

    Article  Google Scholar 

  26. K. Ryu, G. E. Zacharakis-Jutz and S.-C. Kong, Performance characteristics of compression-ignition engine using high concentration of ammonia mixed with dimethyl ether, Applied Energy, 113 (2014) 488–499.

    Article  Google Scholar 

  27. K. Ryu, G. E. Zacharakis-Jutz and S.-C. Kong, Performance enhancement of ammonia-fueled engine by using dissociation catalyst for hydrogen generation, International Journal of Hydrogen Energy, 39 (2014) 2390–2398.

    Article  Google Scholar 

  28. K. Ryu, G. E. Zacharakis-Jutz and S.-C. Kong, Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine, Applied Energy, 116 (2014) 206–215.

    Article  Google Scholar 

  29. F. R. Westlye, A. Ivarsson and J. Schramm, Experimental investigation of nitrogen based emissions from an ammonia fueled SI-engine, Fuel, 111 (2013) 239–247.

    Article  Google Scholar 

  30. O. Mathieu and E. L. Petersen, Experimental and modeling study on the high-temperature oxidation of Ammonia and related NOx chemistry, Combustion and Flame, 162 (2015) 554–570.

    Article  Google Scholar 

  31. H. Hiroyasu, T. Kadota and M. Arai, Development and use of a spray combustion modeling to predict diesel engine efficiency and pollutant emissions: Part 1 combustion modeling, Bulletin of JSME, 26 (1983) 569–575.

    Article  Google Scholar 

  32. P. Dagaut, P. Glarborg and M. U. Alzueta, The oxidation of hydrogen cyanide and related chemistry, Progress in Energy and Combustion Science, 34 (2008) 1–46.

    Article  Google Scholar 

  33. S. J. Klippenstein, L. B. Harding, P. Glarborg and J. A. Miller, The role of NNH in NO formation and control, Combustion and Flame, 158 (2011) 774–789.

    Article  Google Scholar 

  34. J. A. Miller and C. T. Bowman, Mechanism and modeling of nitrogen chemistry in combustion, Progress in Energy and Combustion Science, 15 (1989) 287–338.

    Article  Google Scholar 

  35. F. Kasuya, P. Glarborg, J. E. Johnsson and K. DamJohansen, The thermal DeNOx process: Influence of partial pressures and temperature, Chemical Engineering Science, 50 (1995) 1455–1466.

    Article  Google Scholar 

  36. G. F. Hohenberg, Advanced approaches for heat transfer calculations, SAE Technical Paper (1979).

    Google Scholar 

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Correspondence to Han Ho Song.

Additional information

Recommended by Editor Yong Tae Kang

Donggeun Lee received the B.S. (2011) from POSTECH. He is a Ph.D candidate of Dept. of Mech., Seoul Nat’l Univ. His current interests include the use of ammonia in an internal combustion engine, engine modeling and analysis of chemical reaction process based on chemical kinetics.

Han Ho Song received the B.S. (2003) from Seoul Nat’l Univ., and M.Sc. (2005) and Ph.D. (2009) in Mech. Eng. from Stanford Univ. He is an Associate Prof. of Dept. of Mech. and Aerospace Eng., Seoul Nat’l Univ. His current interests include internal combustion engines, energy systems, and combustion.

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Lee, D., Song, H.H. Development of combustion strategy for the internal combustion engine fueled by ammonia and its operating characteristics. J Mech Sci Technol 32, 1905–1925 (2018). https://doi.org/10.1007/s12206-018-0347-x

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  • DOI: https://doi.org/10.1007/s12206-018-0347-x

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