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Surface-engineered mesoporous carbon-based material for the electrochemical detection of hexavalent chromium

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Abstract

Detection of toxic hexavalent chromium in soil, groundwater, industrial effluent, etc., is of significant interest. We demonstrate the electrochemical detection of Cr(VI) using a surface-engineered mesoporous carbon-based material. The mesoporous carbon-based material is obtained by the controlled pyrolysis of a homogenous mixture of Fe and Co complexes of hydrolyzed collagen. The as-synthesized material is subjected to surface engineering by acid treatment. The surface-engineered mesoporous carbon-based material has a surface area as large as 443.28 m2 g−1 with interconnected mesopores. Detection of Cr(VI) was achieved at parts per billion level by electrochemical reduction using the surface-engineered carbon-based electrode at the potential of 0.65 V (Ag/AgCl). The modified electrode has excellent sensitivity (7.75 ± 0.03 × 10−4 µA/ppb) and selectivity, low detection limit (8 ppb), and wide linear range (40–800 ppb). The coexisting other metal ions do not interfere with the amperometric measurement of Cr(VI). The electrode is highly stable and it retains >65% of the initial current during the long-term durability test for an hour. The highly porous nature of the material favors facile mass transport and facilitate electron transfer kinetics. The trace amount of CoFe alloy present in the carbon-based material catalyses the reduction of Cr(VI) at a favourable potential.

Graphical Abstract

Electrochemical sensing of Cr(VI) at parts-per-billion level is demonstrated with mesoporous carbon derived from iron- and cobalt-hydrolysed collagen complexes

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References

  1. Pantsar Kallio M and Manninen P K G 1996 Speciation of chromium in aquatic samples by coupled column ion chromatography-inductively coupled plasma-mass spectrometry Anal. Chim. Acta 318 335

    Article  CAS  Google Scholar 

  2. Kieber R J, Willey J D and Zvalaren S D 2002 Chromium speciation in rainwater: temporal variability and atmospheric deposition Environ. Sci. Technol. 36 5321

    Article  CAS  Google Scholar 

  3. Biswas P, Karn A K, Balasubramanian P and Kale P G 2017 Biosensor for detection of dissolved chromium in potable water: a review Biosens. Bioelectron. 15 589

    Article  Google Scholar 

  4. International Agency for Research on Cancer 1990 IARC monographs on the evaluation of carcinogenic risks to humans IARC Scientific Publications, IARC, Lyon 49 198

    Google Scholar 

  5. Smith A H and Steinmaus C M 2009 Health effects of arsenic and chromium in drinking water: recent human findings Annu. Rev. Public Health 30 107

    Article  Google Scholar 

  6. Costa M 2003 Potential hazards of hexavalent chromate in our drinking water Toxicol. Appl. Pharmacol. 1 1

    Article  Google Scholar 

  7. Paustenbach D J, Rinehart W E and Sheehan P J 1991 The health hazards posed by chromium-contaminated soils in residential and industrial areas: conclusions of an expert panel Regul. Toxicol. Pharmacol. 13 195

    Article  CAS  Google Scholar 

  8. Sharma P, Bihari V, Agarwal S K, Verma V, Kesavachandran C N, Pangtey B S, et al. 2012 Groundwater contaminated with hexavalent chromium [Cr (VI)]: a health survey and clinical examination of community inhabitants PLoS One 7 47877

    Article  Google Scholar 

  9. Willems G J, Blaton N M, Peeters O M and De Ranter C J 1977 The interaction of chromium(VI), chromium(III) and chromium(II) with diphenylcarbazide, diphenylcarbazone and diphenylcarbadiazone Anal. Chim. Acta 88 345

    Article  CAS  Google Scholar 

  10. Tahmasebi Z and Davarani S S H 2016 Selective and sensitive speciation analysis of Cr(VI) and Cr(III), at sub-µg L−1 levels in water samples by electrothermal atomic absorption spectrometry after electromembrane extraction Talanta 161 640

    Article  CAS  Google Scholar 

  11. Malakhova N A, Chernysheva A V and Brainina K Z 1999 Adsorptive stripping voltammettry of chromium 15-diphenylcarbazoate Electroanalysis 3 803

    Article  Google Scholar 

  12. Yang Y J and Huang H J 2001 A polyaniline-modified electrode-based FIA system for sub-ppb-level chromium(VI) analysis Anal. Chem. 73 1377

    Article  CAS  Google Scholar 

  13. Welch C M, Nekrassova O and Compton R G 2005 Reduction of hexavalent chromium at solid electrodes in acidic media: reaction mechanism and analytical applications Talanta 65 74

    CAS  PubMed  Google Scholar 

  14. Carrington N A, Yong L and Xue Z L 2006 Electrochemical deposition of sol-gel films for enhanced chromium(VI) determination in aqueous solutions Anal. Chim. Acta 572 17

    Article  CAS  Google Scholar 

  15. Michel C, Ouerd A, Battaglia-Brunet F, Guigues N, Grasa J P, Bruschi M and Ignatiadis I 2006 Cr(VI) quantification uing an amperometric enzyme-based sensor: interference and physical and chemical factors controlling the biosensor response in ground waters Biosens. Bioelectron. 22 285

    Article  CAS  Google Scholar 

  16. Jena B K and Raj C R 2008 Highly sensitive and selective electrochemical detection of sub-ppb level chromium(VI) using nano-sized gold particle Talanta 76 161

    Article  CAS  Google Scholar 

  17. Asadiana E, Ghalkhanib M and Shahrokhiana S 2019 Electrochemical sensing based on carbon nanoparticles: a review Sens. Actuat. B 293 183

    Article  Google Scholar 

  18. Jin W and Yan K 2015 Recent advances in electrochemical detection of toxic Cr(VI) RSC Adv. 5 37440

    Article  CAS  Google Scholar 

  19. Golub D and Oren Y 1989 Removal of chromium from aqueous solutions by treatment with porous carbon electrodes: electrochemical principles J. Appl. Electrochem. 19 311

    Article  CAS  Google Scholar 

  20. Hallam P M, Kampouris D K, Kadara R O and Banks C E 2010 Graphite screen printed electrodes for the electrochemical sensing of chromium(VI) Analyst 135 1947

    Article  CAS  Google Scholar 

  21. Kowsalya B, Anusha Thampi V V, Sivakumar V and Subramanian B 2019 Electrochemical detection of chromium(VI) using NiO nanoparticles J. Mater. Sci. Mater. Electron. 30 14755

    Article  CAS  Google Scholar 

  22. Samanta A and Raj C R 2020 Bifunctional nitrogen-doped hybrid catalyst based on onion-like carbon and graphitic carbon encapsulated transition metal alloy nanostructure for rechargeable zinc-air battery J. Power Sources 455 227975

    Article  CAS  Google Scholar 

  23. Wen Y, Rufford T E, Hulicova-Jurcakova D, Zhu X and Wang L 2016 Structure control of nitrogen-rich graphene nanosheets using hydrothermal treatment and formaldehyde polymerization for supercapacitors ACS Appl. Mater. Interfaces 8 18051

    Article  CAS  Google Scholar 

  24. Fuertes A B and Sevilla M 2015 Structure control of nitrogen-rich graphene nanosheets using hydrothermal treatment and formaldehyde polymerization for supercapacitors ACS Appl. Mater. Interfaces 7 4344

    Article  CAS  Google Scholar 

  25. Schmidt T J 1998 Characterization of high-surface-area electrocatalysts using a rotating disk electrode configuration J. Electrochem. Soc. 145 2354

    Article  CAS  Google Scholar 

  26. Liu G, Lin Y Y, Wu H and Lin Y 2007 Voltammetric detection of Cr(VI) with disposable screen-printed electrode modified with gold nanoparticles Environ. Sci. Technol. 41 8129

    Article  CAS  Google Scholar 

  27. Hussein M A, Ganash A A and Alqarni S A 2019 Electrochemical sensor-based gold nanoparticle/poly(aniline-co-o-toluidine)/graphene oxide nanocomposite modified electrode for hexavalent chromium detection: a real test sample Polym. Technol. Mater. 58 1423

    CAS  Google Scholar 

  28. Choi Y W, Minoura N and Moon S H 2005 Potentiometric Cr(VI) selective electrode based on novel ionophore-immobilized PVC membranes Talanta 66 1254

    Article  CAS  Google Scholar 

  29. Ansari R, Delavar A F and Mohammad-khah A A 2012 Solid state Cr(VI) ion-selective electrode based on polypyrrole Microchim. Acta 178 71

    Article  CAS  Google Scholar 

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Acknowledgement

This work was funded by Science and Engineering Research Board (SERB) (CRG/2019/001332), and CSIR (Grant No. 01(2888)/17/EMR-II) India. The authors acknowledge DST-FIST of Materials Science Centre, IIT Kharagpur for EDX analysis. Dr. Aniruddha Kundu likes to acknowledge the National Postdoctoral Fellowship from SERB (PDF/2018/003346). Mr. Abhirup Bhadra would like to acknowledge the INSPIRE Scholarship for Higher Education (SHE) (201500019759).

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Authors and Affiliations

  1. Functional Materials and Electrochemistry Lab, Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, 721302, India

    Abhirup Bhadra, Aniruddha Kundu & C Retna Raj

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  1. Abhirup Bhadra
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  2. Aniruddha Kundu
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  3. C Retna Raj
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Correspondence to C Retna Raj.

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Bhadra, A., Kundu, A. & Retna Raj, C. Surface-engineered mesoporous carbon-based material for the electrochemical detection of hexavalent chromium. J Chem Sci 133, 125 (2021). https://doi.org/10.1007/s12039-021-01979-2

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  • DOI: https://doi.org/10.1007/s12039-021-01979-2

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