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Synthesis, characterization and supercapacitor application of nanourchin-like VO2

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Abstract

Nanourchin VO2 nanostructures have been effectively synthesized by hydrothermal method. The synthesized hierarchical nanostructure has been characterized by various characterization techniques and electrochemical behaviour has been studied. X-ray diffraction analysis revealed the monoclinic phase and morphological analysis (FESEM) of VO2 showed nanourchin-like structure with arrangement of various nanorods in radial fashion. Over these nanorods, formation of secondary growth of asterisk-shape structure was observed. The width and length of nanorods were ~ 50 and ~ 75 nm, respectively. For the electrochemical measurements, 2032 type coin cells were fabricated using VO2 as electrode material. The electrochemical study of VO2 exhibited the pseudocapacitive behaviour with specific capacitance of 44 F g−1 in organic electrolyte with symmetric capacitor of two electrode system. The maximum energy density and power density were 44 and 8635 Wh kg−1, respectively. Cycling performance exhibited symmetric charge–discharge curves, and also specific capacitance was maintained up to 82% of initial value.

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Acknowledgement

SB thanks Bharatratna JRD Tata Gunwant Sanshodhak Shishyavruti Yojana, for providing the research fellowship.

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Authors and Affiliations

  1. Centre for Materials for Electronics Technology (C-MET), Panchwati, Off Pashan Road, Pune, 411008, India

    Shobha N Birajdar, Prashant S Misal, Bharat B Kale & Parag V Adhyapak

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  1. Shobha N Birajdar
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  2. Prashant S Misal
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Correspondence to Parag V Adhyapak.

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Birajdar, S.N., Misal, P.S., Kale, B.B. et al. Synthesis, characterization and supercapacitor application of nanourchin-like VO2. Bull Mater Sci 47, 65 (2024). https://doi.org/10.1007/s12034-024-03165-9

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