Abstract
In this study, calcium titanate (CaTiO3) doped (0, 15, 25 and 35%) polyaniline (PANI) composites in the presence of dodecylbenzene sulphonic acid (DBSA) were successfully synthesized by the means of in-situ emulsion polymerization of aniline monomer. The structural, morphological and optical characterization of as-prepared composites were determined using X-ray diffraction (XRD), field effect scanning electron microscopy, Fourier-transform infrared spectroscopy, UV–vis analysis, and electronic conductivity was determined using two-point probe method. The structural analysis confirms that PANI–DBSA is amorphous, but sharp peaks present in XRD patterns in composites are of crystalline nature. The morphological study reveals efficacious integration of CaTiO3 particles into the PANI–DBSA matrix. Further, the integration of CaTiO3 remarkably reduced the optical bandgap (2.7–2.2 eV) by making composites with PANI–DBSA. Room temperature alternating current conductivity was found to obey universal power law and correlated barrier hopping was found most appropriate model to describe the sample’s charge transport mechanism. With the increasing wt% of CaTiO3, the dielectric permittivity and loss both varied according to the interfacial polarization law of Maxwell–Wagner. Moreover, the I–V graphs showed augmented electrical conductivity of composites with an increase in CaTiO3 particle content than that of pure PANI–DBSA. This is a simple way by which PANI–DBSA/CaTiO3 composites having low optical bandgap, high electrical conductivity and permittivity may be fabricated for a widespread technological application.
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Saad G R, Ezz A A and Ahmed H A 2015 Thermochim. Acta. 599 84
Xiong S, Zhang X, Wang R, Lu Y, Li H, Liu J et al 2019 J. Polym. Res. 26 1
Chahal P, Tummala R R, Allen M G and Swaminathan M A 1998 Comput. Pack. Manuf. Technol. Part. B Adv. Pack. 21 184
Zhang Q, Jiang Y, Yu E and Yang H 2019 Surf. Coat. Technol. 358 293
Sharma B K, Khare N, Dhawan S K and Gupta H C 2009 J. Alloys Compd. 477 370
Manjunatha S, Machappa T, Sunilkumar A and Ravikiran Y T 2018 J. Mater. Sci. Mater. Electron. 29 11581
Park D, Ju H and Kim J 2020 Polymers 12 777
Ahmed K, Kanwal F, Ramay S M, Atiq S, Rehman R, Ali S M et al 2018 Polymers 10 1273
Almadhoun M N, Bhansali U S and Alshareef H N 2012 J. Mater. Chem. 22 11196
Xie L, Huang X, Wu C and Jiang P 2011 J. Mater. Chem. 21 5897
Yang C, Hao S J, Dai S L and Zhang X Y 2017 Carbon 117 301
Rajappa S, Shivarathri P G, Kumari M L A, Swamygowda D K, Devendrachari M C and Kotresh H M N 2022 Surf. Interfaces 29 101720
Yarmohamadi-Vasel M, Modarresi-Alam A R, Noroozifar M and Hadavi M S 2019 Synth. Met. 252 50
Wu K, Gui T, Dong J, Luo J and Liu R 2022 Prog. Org. Coat. 162 106592
Ugraskan V and Karaman F 2021 J. Electron. Mater. 50 3455
Kenry and Liu B 2018 Biomacromolecules 19 1783
Das M, Akbar A and Sarkar D 2019 Synth. Met. 249 69
Liao G, Li Q and Xu Z 2019 Prog. Org. Coat. 126 35
Hu C, Li T, Yin H, Hu L, Tang J and Ren K 2021 Colloids. Surf. A Physicochem. Eng. Asp. 612 126069
Najafi M, Ansari R and Darvizeh A 2019 Polym. Compos. 40 2523
Afilipoaei C and Teodorescu-Draghicescu H 2020 Proceedings 63 23
Reddy K R, Sin B C, Ryu K S, Kim J C, Chung H and Lee Y 2009 Synth. Met. 159 595
Hassan M, Reddy K R, Haque E, Faisal S N, Ghasemi S, Minett A I et al 2014 Compos. Sci. Technol. 98 1
Shahabuddin S, Numan A, Shahid M M, Khanam R, Saidur R, Pandey A K et al 2019 Ceram. Int. 45 11428
Maruthi N, Faisal M, Raghavendra N, Prasanna B P, Nandan K R, Kumar K Y et al 2021 Mater. Chem. Phys. 259 124059
Li J, Wang Y, Yang X, Kang H, Cao Z, Jiang X et al 2022 Chem. Eng. J. 428 131121
Tian X, Lian S, Ji C, Huang Z, Wen J, Chen Z et al 2019 J. Alloys Compd. 784 628
Ahmad K, Kumar P and Mobin S M 2020 Mater. Adv. 1 2003
Parveen A, Kumar K A, Revanasidappa M, Ekhilikar S and Ambika Prasad M N 2008 Ferroelectrics 377 63
Roy A S, Hegde S G and Parveen A 2014 Polym. Adv. Technol. 25 130
Parveen A, Koppalkar A R and Roy A S 2012 IEEE Sens. J. 12 2817
Bibi A, Shakoor A and Niaz N A 2022 Polym. Polym. Compos. 30 1
Bibi A, Shakoor A, Niaz N A, Haider S and Akhtar M S 2022 Polym. Bull. 10 1
Han C, Liu J, Yang W, Wu Q, Yang H and Xue X 2017 J. Sol-Gel Sci. Technol. 81 806
Misoon O and Seok K 2012 Electrochim. Acta 59 196
Ravikiran Y T, Lagare M T, Sairam M, Mallikarjuna N N, Sreedhar B, Manohar S et al 2006 Synth. Met. 156 1139
Zilberman M, Titelman G I, Siegmann A, Haba Y, Narkis M and Alperstein D 1997 J. Appl. Polym. Sci. 66 243
Blinova N V, Stejskal J, Trchová M, Prokeš J and Omastová M 2007 Eur. Polym. J. 43 2331
Stejskal J 2013 Chem. Pap. 67 814
Babazadeh M 2009 J. Appl. Polym. Sci. 113 3980
Saini P, Choudhary V, Sood K N and Dhawan S K 2009 J. Appl. Polym. Sci. 113 3146
Marie E, Rothe R, Antonietti M and Landfester K 2003 Macromolecules 36 3967
Milton A J and Monkman A P 1993 J. Phys. D Appl. Phys. 26 1468
Suthar V, Pratap A and Raval H 2000 Bull. Mater. Sci. 23 215
Ghosh P, Siddhanta S K, RejaulHaque S and Chakrabarti A 2001 Synth. Met. 123 83
Som S, Kunti A K, Kumar V, Kumar V, Dutta S, Chowdhury M et al C 2014 J. Appl. Phys. 115 193101
Anju V P and Narayanankutty S K 2019Polym. Bull. 76 5253
Tauc J 1969 Optical properties of solids (Boston, MA: Springer) p 123
Khan M D A, Akhtar A and Nabi S A 2015 New J. Chem. 39 3728
Debnath T, Chakraborty T, Bandyopadhyay A, Sharma S, Mahapatra A S, Das S et al 2022 Mater. Sci. Eng. B 280 115688
Saravanan S, Mathai C J, Anantharaman M R, Venkatachalam S and Prabhakaran P V 2006 J. Phys. Chem. Solids 67 1496
Xiang J and Drzal L T 2012 Polymer 53 4202
Manjunatha S, Megha R, Chethan B, Prashantkumar M, Ravikiran Y T and Machappa T 2021 JMEPEG 30 1885
Vijayalakshmi S, Kumar E and Nithya S 2020 Ionics 26 839
Sampreeth T, Al-Maghrabi M A, Bahuleyan B K and Ramesan M T 2018 J. Mater. Sci. 53 591
Jonscher A K 1981 J. Mater. Sci. 16 2037
Jebli M, Rayssi C, Dhahri J and Khirouni K 2020 Appl. Phys. A 126 109
Baruah S, Kumar S, Nayak B and Puzari A 2021 Polym. Bull. 78 1703
Ruokolainen J, Torkkeli M, Serimaa R, Vahvaselkä S, Saariaho M, Ten Brinke G et al 1996 Macromolecules 29 6621
Dhole S G, Dake S A, Prajapati T A and Helambe S N 2018 Proc. Manufact. 20 127
Vijayalakshmi S, Kumar E, Ganeshbabu M, Venkatesh P S and Rathnakumar K 2021 Ionics 27 2967
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Bibi, A., Shakoor, A., Niaz, N.A. et al. Enhanced optical, electronic and dielectric properties of DBSA-doped polyaniline–calcium titanate composites. Bull Mater Sci 46, 185 (2023). https://doi.org/10.1007/s12034-023-03022-1
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DOI: https://doi.org/10.1007/s12034-023-03022-1