Skip to main content
SpringerLink
Log in

Zeolitic imidazolate framework-67 derivative/TiO2 composite coating as an integrated anode for lithium-ion batteries

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

In this study, Cu-supported ZIF-67 derivative/TiO2 composite coating was synthesized to increase the conductivity and capacity of TiO2 and apply the ZIF-67 derivative with excellent electrochemical performance to the integrated anode for lithium-ion batteries (LIBs). The hydrolysis of tetrabutyl titanate in air will produce TiO2; while the sintering of ZIF-67 in an inert atmosphere will form CoO/C composite. The Cu-supported ZIF-67 derivative/TiO2 composite coating can be directly employed as an integrated anode for LIBs. It delivers a capacity of 649 mAh g−1 after 500 cycles at a high current density of 1000 mA g−1. Even at a high current density of 2000 mA g−1, it still maintains a capacity of 445 mAh g−1. The good electrochemical performance of the Cu-supported ZIF-67 derivative/TiO2 composite coating is mainly attributed to the good conductivity and excellent electrochemical properties of ZIF-67, the inhibition of TiO2 on reduction of CoO, and the steric hindrance effect of TiO2 on ZIF-67 particles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8

Similar content being viewed by others

References

  1. Armand M and Tarascon J M 2008 Nature 451 652

    Article  CAS  Google Scholar 

  2. Tang Y, Zhang Y, Li W, Ma B and Chen X 2015 Chem. Soc. Rev. 44 5926

    Article  CAS  Google Scholar 

  3. Xia W, Mahmood A, Zou R and Xu Q 2015 Energy Environ. Sci. 8 1837

    Article  CAS  Google Scholar 

  4. Tang Y, Hong L, Li J, Hou G, Cao H, Wu L et al 2017 Chem. Comm. 53 5298

    Article  CAS  Google Scholar 

  5. Tang Y, Hong L, Wu Q, Li J, Hou G, Cao H et al 2016 Electrochim. Acta 195 27

    Article  CAS  Google Scholar 

  6. Zhang M, Wang C, Li H, Wang J, Li M and Chen X 2019 Electrochim. Acta 326 134972

    Article  CAS  Google Scholar 

  7. Wang L, Gu X, Zhao L, Wang B, Jia C, Xu J et al 2019 Electrochim. Acta 295 107

    Article  CAS  Google Scholar 

  8. Balogun M S, Li C, Zeng Y, Yu M, Wu Q, Wu M et al 2014 J. Power Sources 272 946

    Article  CAS  Google Scholar 

  9. Cao M, Bu Y, Lv X, Jiang X, Wang L, Dai S et al 2018 Appl. Surf. Sci. 435 641

    Article  CAS  Google Scholar 

  10. Yi Z, Han Q, Zan P, Cheng Y, Wu Y and Wang L 2016 J. Mater. Chem. A 4 12850

    Article  CAS  Google Scholar 

  11. Liu T, Wang W, Yi M, Chen Q, Xu C, Cai D et al 2018 Chem. Eng. J. 354 454

    Article  CAS  Google Scholar 

  12. Zheng G, Chen M, Zhang H, Zhang J, Liang X, Qi M et al 2019 Surf. Coat. Tech. 359 384

    Article  CAS  Google Scholar 

  13. Cai D, Zhan H and Wang T 2017 Mater. Lett. 197 241

    Article  CAS  Google Scholar 

  14. Zheng F and Wei L 2019 J. Alloys Compd. 790 955

    Article  CAS  Google Scholar 

  15. Yin D, Huang G, Sun Q, Li Q, Wang X, Yuan D et al 2016 Electrochim. Acta 215 410

    Article  CAS  Google Scholar 

  16. Wang Z, Su F, Madhavi S and Lou X 2011 Nanoscale 3 1618

    Article  CAS  Google Scholar 

  17. Zhang X, Yu L, Wang L, Ji R, Wang G and Geng B 2013 Phys. Chem. Chem. Phys. 15 521

    Article  Google Scholar 

  18. Zhang Z, Wang Y, Tan Q, Li D, Chen Y, Zhong Z et al 2014 Nanoscale 6 371

    Article  CAS  Google Scholar 

  19. Zhao G, Tang L, Zhang L, Chen X, Mao Y and Sun K 2018 J. Alloys Compd. 746 277

    Article  CAS  Google Scholar 

  20. Zhao G, Sun X, Zhang L, Chen X, Mao Y and Sun K 2018 J. Power Sources 389 8

    Article  CAS  Google Scholar 

  21. Li B, Igawa K, Chai J, Chen Y, Wang Y, Fam D W et al 2020 Energy Storage Mater. 25 137

    Article  Google Scholar 

  22. Park S K, Kim J K, Kim J H and Kang Y C 2017 Mater. Charact. 132 320

    Article  CAS  Google Scholar 

  23. Sun X, Xu W, Zhang X, Lei T, Lee S and Wu Q 2021 J. Energy Chem. 52 170

    Article  CAS  Google Scholar 

  24. Liu M, Li Y, Wang K, Luo Y, Hou S, Wang P et al 2018 Ceram. Int. 44 19631

    Article  CAS  Google Scholar 

  25. Yao Y, Zhu Y, Shen J, Yang X and Li C 2016 Electrochim. Acta 222 1300

    Article  CAS  Google Scholar 

  26. Deng X, Zhu S, He F, Liu E, He C, Shi C et al 2018 Electrochim. Acta 283 1269

    Article  CAS  Google Scholar 

  27. Ren W, Zhou W, Zhang H and Cheng C 2017 ACS Appl. Mater. Interfaces 9 487

    Article  CAS  Google Scholar 

  28. Pan J, Yu K, Mao H, Li L, Zhang Y and Li Y 2020 Chem. Eng. J. 380 122624

    Article  CAS  Google Scholar 

  29. Li J, Huang J, Li J, Cao L, Qi H, Cheng Y et al 2017 J. Alloys Compd. 727 998

    Article  CAS  Google Scholar 

  30. Guo L, Ding Y, Qin C, Li W, Du J, Fu Z et al 2016 Electrochim. Acta 187 234

    Article  CAS  Google Scholar 

  31. Yang Z, Meng Q, Guo Z, Yu X, Guo T and Zeng R 2013 J. Mater. Chem. A 1 10395

    Article  CAS  Google Scholar 

  32. Yang Z, Du G, Guo Z, Yu X, Li S, Chen Z et al 2010 Nanoscale 2 1011

    Article  CAS  Google Scholar 

  33. Ma K, Liu F, Yuan Y, Liu X, Wang J, Xie J et al 2018 Phys. Chem. Chem. Phys. 20 595

    Article  CAS  Google Scholar 

  34. Tang Y, Bi C, Zhang D, Hou G, Cao H, Wu L et al 2019 Micropor. Mesopor. Mater. 274 76

    Article  CAS  Google Scholar 

  35. Liu B, Zhang J, Wang X, Chen G, Chen D, Zhou C et al 2012 Nano Lett. 12 3005

    Article  CAS  Google Scholar 

  36. Shao J, Zhou H, Zhu M, Feng J and Yuan A 2019 J. Nanopart. Res. 21 79

    Article  Google Scholar 

  37. Wang G, Sun Z, Huang F, Gong C, Liu H, Zheng G et al 2016 Mater. Lett. 171 150

    Article  CAS  Google Scholar 

  38. Lan T, Tu J, Zou Q, Zeng X, Zou J, Huang H et al 2019 Electrochim. Acta 319 101

    Article  CAS  Google Scholar 

  39. Cao M, Bu Y, Lv X, Jiang X, Wang L, Dai S et al 2018 Appl. Surface Sci. 435 641

    Article  CAS  Google Scholar 

  40. Zeng J, Peng C, Wang R, Liu Y, Cao C, Wang X et al 2019 Ceram. Int. 45 19404

    Article  CAS  Google Scholar 

  41. Tjandra R, Li G, Wang X, Yan J, Li M and Yu A 2016 RSC Adv. 6 35479

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This study was financially supported by Class III Peak Discipline of Shanghai-Materials Science and Engineering (High-Energy Beam Intelligent Processing and Green Manufacturing).

Author information

Authors and Affiliations

  1. School of Materials Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China

    Qi Yang & Yujiao Xu

Authors
  1. Qi Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yujiao Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Qi Yang.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 1485 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, Q., Xu, Y. Zeolitic imidazolate framework-67 derivative/TiO2 composite coating as an integrated anode for lithium-ion batteries. Bull Mater Sci 46, 102 (2023). https://doi.org/10.1007/s12034-023-02942-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12034-023-02942-2

Keywords

Search

Navigation