Abstract
A flexible, electrically conductive and low-cost composite sheet has been prepared combining multi-walled carbon nanotubes (MWCNTs) and cellulose pulp using simple solution mixing method. The uniform attachment of MWCNTs on to the cellulose fibres of the composites lead to a gradual decline of the sheet resistance with an enhanced electrical conductivity. The crystallinity of the composites is also found to be increased. The composites remain thermally stable up to 550 K as well as demonstrate improved flame retardancy. The conducting CNT networks of the composites are not disrupted even after 600 bending cycles, indicating almost no loss of conductivity. This conducting and flexible composite sheet can be used in different energy storage devices.
Similar content being viewed by others
References
Saini P 2015 Fundamentals of conjugated polymer blends copolymers and composites (New Jersey: John Wiley & Sons)
Klemn D, Heublein B, Fink H P and Bohn A 2005 Angew. Chem. Int. Ed. 44 3358
Maria K H and Mieno T 2017 J. Nanomater. 2017 Article ID 6745029
Qi H, Liu J, Deng Y, Gao S and Mäder E 2014 J. Mater. Chem. A 2 5541
Han J M, Kim B, Li J and Meyyappan M 2014 RSC Adv. 4 549
Yun S and Kim J 2010 Sens. Actuators B Chem. 150 308
Dichiara A B, Song A, Goodman S M, He D and Bai J 2017 J. Mater. Chem. A 5 20161
Demczyk B G, Wang Y M, Cumings J, Hetman M, Han W, Zettl A et al 2002 Mater. Sci. Eng. A 334 173
Yu M F, Lourie O, Dyer M J, Moloni K, Kelly T F and Ruoff R S 2000 Science 287 637
Seunghun H and Myung S 2007 Nat. Nanotechnol. 2 207
Pop E, Mann D, Wang Q, Goodson K E and Dai H J 2006 Nano Lett. 6 96
Qi H, Liu J and Mäder E 2014 Fibers 2 295
Hilding J, Grulke E A, Zhang Z G and Lockwood F 2003 J. Dispers. Sci. Technol. 24 1
Koga H, Tonomura H, Nogi M, Suganuma K and Nishina Y 2015 Green Chem. 18 1117
Kim J-H, Yun S, Ko H-U and Kim J 2013 Curr. Appl. Phys. 13 897
Kim J and Seo Y B 2002 Smart Mater. Struct. 11 355
Lee T-W and Jeong Y G 2015 Carbohyd. Polym. 133 456
Rahman M J and Mieno T 2014 J. Nanomater. 2014 Article ID 508192
Naseh M V, Khodadadi A A, Mortazavi Y, Pourfayaz F, Alizadeh O and Maghrebi M 2010 Carbon 48 1369
Yeoh W-M, Lee K-Y, Chai S-P, Lee K-T and Mohamed A R 2009 New Carbon Mater. 24 119
Reddy A L M and Ramaprabhu S 2007 Int. J. Hydrog. Energy 32 3998
Tian R, Wang X, Li M, Hu H, Chen R, Liu F et al 2008 Appl. Surf. Sci. 255 3294
Liu L, Gao Z Y, Su X P, Chen X, Jiang L and Yao J M 2015 ACS Sustain Chem. Eng. 3 432
Zhang P, Dong S J, Ma H H, Zhang B X, Wang Y F and Hu X M 2015 Ind. Crops Prod. 76 688
Lamaming J, Hashim R, Sulaiman O, Leh C P, Sugimoto T and Nordin N A 2015 Carbohyd. Polym. 127 202
Gao X and Chorover J 2010 J. Colloid Interface Sci. 348 167
Sturcová A, Eichhorn S J and Jarvis M C 2006 Biomacromol. 7 2688
Lamouroux E and Fort Y 2016 in Spectroscopy of polymer nanocomposites S Thomas, D Rouxel and D Ponnamma (eds) (Amsterdam: William Andrew Publishers) p 15
Oh S Y, Yoo D I, Shin Y and Seo G 2005 Carbohydr. Res. 340 417
Chena W, Yua H, Liua Y, Chen P, Zhang M and Hai Y 2011 Carbohydr. Polym. 83 1804
Dutta D, Hazarika R, Dutta P D, Goswami T, Sengupta P and Dutta D K 2016 RSC Adv. 6 85173
Anilkumar K M, Jinisha B, Manoj M, Pradeep V S and Jayalekshmi S 2018 Appl. Surf. Sci. 442 556
Jiang Z, Chen D, Yu Y, Miao J, Liu Y and Zhang L 2017 RSC Adv. 7 2186
Kim D-Y, Nishiyama Y, Wada M and Kuga S 2001 Cellulose 8 29
Lewin M 2007 Handbook of fiber chemistry (Boca Raton: CRC Press) p 453
Shurong W, Qian L, Zhongyang L, Lihua W and Kefa C 2007 Front Energy Power Eng. China 1 413
Rahman M J and Mieno T 2015 J. Nanomater. 2015 Article ID: 978484
Visakh P M and Arao Y 2015 Flame retardants: polymer blends composites and nanocomposites (Netherlands: Springer) p 357
Beyer G 2002 Fire Mater. 26 291
Kashiwagi T, Du F M, Douglas J F, Winey K I, Harris R H and Shields J R 2005 Nat. Mater. 4 928
Nayak L, Rahaman M, Aldalbahi A, Chaki T K and Khastgir D 2016 Polym. Eng. Sci. 57 291
Einfeldt J, Meißner D and Kwasniewski A 2001 Prog. Polym. Sci. 26 1419
Mohiuddin M and Hoa S V 2011 Nanoscale Res. Lett. 6 419
Ning J, Zhang J, Pan Y and Guo J 2003 Mater. Sci. Eng. A 357 392
Acknowledgements
We would like to acknowledge the financial support from the authority of BUET and Ministry of Science and Technology of Government of Bangladesh for the research work and Shizuoka University, Japan, for providing the CNTs for this research.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mostafa, U., Rahman, M.J., Mieno, T. et al. Carbon nanotube-incorporated cellulose nanocomposite sheet for flexible technology. Bull Mater Sci 43, 142 (2020). https://doi.org/10.1007/s12034-020-02145-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-020-02145-z