Skip to main content
SpringerLink
Log in

Effect of surfactants in synthesis of CsH2PO4 as protonic conductive membrane

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

Cesium dihydrogen phosphate (CDP) powders were synthesized by cetyltrimethylammoniumbromide (CTAB), polyoxyethylene-polyoxypropylene (F-68) and mixture of both surfactants F-68: CTAB with two molar ratios 0.06 and 0.12 as surfactant solutions at room temperature. The synthesized CsH2PO4 is characterized by ICP, XRD, TEM, SEM, FT-IR, BET and IS techniques. Based on the width of the (011) XRD diffraction peak and BET measurement, the average size of nanoparticles was ∼ 10 nm in diameter, while the TEM images indicate smaller size than both techniques. The analysis reveals existence of P and Cs with mole ratio 1.02 ± 0.03 which is compatible to molar ratio CsH2PO4 formula. The experimental results show that the conductivities increase in the order of CDPCTAB > CDP(F-68: CTAB)0.12 > CDP(F-68:CTAB)0.06 > CDPF-68. The sequence of increasing conductivity is in accordance with the ion exchange capacities of the samples that has direct proportional effect on the proton mobility of samples. Indeed CTAB as cationic surfactant shows the highest proton mobility in the as-obtained samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Baranov A I 2003 Cryst. Rep. 46 1012

    Article  Google Scholar 

  • Baranov A I, Shuvalov L A and Shchagina N M 1982 JETP Lett. 36 459

    Google Scholar 

  • Boysen D A, Haile S M, Liu H and Secco R A 2003 Chem. Mat. 15 727

    Article  CAS  Google Scholar 

  • Bronowska W 2001 J. Chem. Phys. 114 611

    Article  CAS  Google Scholar 

  • Burton A W, Ong K, Rea Th and Chan I Y 2009 Micro. Meso. Mat. 117 75

    Article  CAS  Google Scholar 

  • Daiko Y, Katagiri K, Ogura K, Sakai M and Matsuda A 2007 Solid State Ionic 178 601

    Article  CAS  Google Scholar 

  • Deguchi K, Nakamura E and Okaue E 1982 J Phys. Soc. 51 3569

    Article  CAS  Google Scholar 

  • Dongli Xu, Dongfeng X and Henryk R 2005 J. Mol. Struct. 740 37

    Article  Google Scholar 

  • Jun Y and Ki Zh 2009 Technology Application DOI CNKI:SUN:HCSY.0.2009-03-009

  • Haile S A, Boysen D A, Chisholm C R I and Merie R B 2001 Nature 410 910

    Article  CAS  Google Scholar 

  • Hammes K, Smernik R J, Skjemstad J O and Schmidtt W 2008 Appl. Geoch. 23 2113

    Article  CAS  Google Scholar 

  • Hosseini S, Mohamad A B, Khadum A H and Wan Doud W R 2009 J. Therm. Anal. Cal. Doi: 10.1007/s10973-009-0132-2

  • Hosseini S, Homaeei M, Mohamad A B, Malekbala M R and Khadhum A A H 2011 Phys. B: Condens. Matter 406 1689

    Article  CAS  Google Scholar 

  • Hubert J, Jayakumar V S and Aruldhas G 1995 J. Solid State Chem. 120 343

    Article  Google Scholar 

  • JCPDS-ICDD 1995 Database 35 746

    Google Scholar 

  • Kalevich N I, Maljarevich A M and Posledovich M R 1993 Bull. Russ. Chem. Phys. 12 1015

    CAS  Google Scholar 

  • Kalevich N I, Posledovich M R and Rodin S V 1993 Bull. Russ. Acad. Sci. Phys. 57 385

    Google Scholar 

  • Kalevitchayb N I, Arnscheidtb B, Pelzlb J and Rodina S V 1995 J. Mol. Struct. 348 361

    Article  Google Scholar 

  • Kennedy N S J and Nelmes R J 1980 J. Phys. C13 4841

    Google Scholar 

  • Kim J, Ahn Y S, Ruth M I and Park C W 2006 J. Power Sources 163 107

    Article  Google Scholar 

  • Kojitani H, Kido M and Akaogi M 2005 Phys. Chem. Miner. 32 290

    Article  CAS  Google Scholar 

  • Koleva V, Stefov V, Cahil A, Najdoski M, Šoptrajanov B, Engelen B and Lutz H D 2009 J. Mol. Struct. 917 117

    Article  CAS  Google Scholar 

  • Larson A C and Von Dreele R B 2000 Los Alamos National Laboratory Report LAUR 86-748, USA

  • Larson A C and Von Dreele R B 2006 General structure analysis system technical manual LANSCE, MS-H805 2000 (LAUR: Los Almos National University) Vol. 86 p. 66

    Google Scholar 

  • Le Calve N, Romain F, Limage M H and Novak A 1989 J. Mol. Struct. 200 131

    Google Scholar 

  • Manna L, Scher E C and Alvisatos A P 2000 J. Am. Chem. Soc. 122 12700

    Article  CAS  Google Scholar 

  • Matsunaga H, Itoh K and Nakamura E 1980 J. Phys. Soc. Jpn. 48 2011

    Article  CAS  Google Scholar 

  • McCall R P, Ginder J M, Roe M G, Asturias G E, Scherr E M, Macdiarmid A G and Epstein A J 1989 Phys. Rev. B39 10174

    Google Scholar 

  • Olivera C, Jankovicb I, Comorb M and Vladimirova S 2006 J. Collo. Inter. Sci. 301 692

    Article  Google Scholar 

  • Ortiz E, Vargas R and Mellander B 1999a J. Chem. Phys. 110 4847

    Article  CAS  Google Scholar 

  • Ortiz E, Vargas R and Mellander B 1999b Solid State Ionics 125 177

    Article  CAS  Google Scholar 

  • Otomo J, Minagawa N, Wen C, Eguchi K and Takahashi H 2003 Solid State Ionic 156 357

    Article  CAS  Google Scholar 

  • Rashkovich L N 1991 KDP-family single crystals (IOP Publishing)

  • Rietveld H M 1969 Acta Crystall. 2 65

    CAS  Google Scholar 

  • Romain F and Novak A 1991 J. Mol. Struct. 263 69

    Article  CAS  Google Scholar 

  • Ross Boyle 2005 Thermo fisher scientific (Madison WI, USA)

  • Toupry N and Poulet H 1981 Postollec MLe J Raman Spect. 11 81

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Fuel Cell, University Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia

    Soraya Hosseini, Wan Ramli Wan Daud, Abdul Amir Hassan Kadhum & Abu Bakar Mohammad

  2. Chemical Engineering Process, University Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia

    Marzieh Badiei

Authors
  1. Soraya Hosseini
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wan Ramli Wan Daud
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marzieh Badiei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Abdul Amir Hassan Kadhum
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Abu Bakar Mohammad
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Soraya Hosseini.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hosseini, S., Daud, W.R.W., Badiei, M. et al. Effect of surfactants in synthesis of CsH2PO4 as protonic conductive membrane. Bull Mater Sci 34, 759 (2011). https://doi.org/10.1007/s12034-011-0192-3

Download citation

  • Received:

  • Revised:

  • Published:

  • DOI: https://doi.org/10.1007/s12034-011-0192-3

Keywords

Search

Navigation