Skip to main content
SpringerLink
Log in

Study on synthesis and properties of Na+–La3+ co-doped γ-Ce2S3 pigment by low-temperature self-propagating combustion method

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Na+–La3+ co-doped γ-Ce2S3 (abbreviated as γ-Na0.5Ce2.5 − xLaxS4) pigments with a fixed Na/(Ce1 − xLax) molar ratio of 0.2 (x = 0, 0.1, 0.5, 0.9, 1.3, 1.7, 2.1 and 2.5) were synthesized by low-temperature self-propagating combustion method. By adjusting the La3+ doping ratio, a series of γ-Na0.5Ce2.5 − xLaxS4 pigments with different colors were obtained by sulfurizing at 900°C for 2 h using CS2 as the sulfur source. The effects of La3+ doping amount on the synthesis of γ-Ce2S3, crystal structure, color performance, and temperature stability were systematically studied. The results show that the pigments exhibited a single cubic γ-Ce2S3 phase throughout the range of x increasing from 0 to 2.5. Compared with the co-precipitation method, the particle size of the pigment obtained by the low-temperature self-propagating combustion method decreased from 620 to 310 nm. Furthermore, as La3+ content increased, the band gap of the sample gradually increased from 2.06 to 2.90 eV, causing the color to change from red (L* = 39.42, a* = 40.35, b* = 30.28) to orange-red (L* = 49.15, a* = 35.51, b* = 40.64), then to orange-yellow (L* = 54.85, a* = 28.53, b* = 37.30), and finally to white-blue (L* = 66.66, a* = − 1.42, b* = 11.25). In addition, the thermal stability of γ-Na0.5Ce2.5 − xLaxS4 was evaluated by TG-DSC and its thermal stability increased from 350 to 480°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Data availability

All data generated or analyzed during this study are included in this published article. The data incorporated in this study are available upon request from the corresponding author.

References

  1. Xuan, ZK, Meng, LJ, Meng, SL, “Preparation of Cadmium Sulfoselenide Big Red Pigment.” J. Hebei Norm. Univ. Natl., 33 40 (2013)

    Google Scholar 

  2. Li, H, Preparation and Thermal Stability of Cd(SxSe(1–x)) Encapsulated Pigment. South China University of Technology, Guangzhou (2010)

    Google Scholar 

  3. Zhu, ZF, Chen, HG, Liu, H, “Research Progress of γ-Ce2S3.” J. Funct. Mater., 44 1825 (2013)

    CAS  Google Scholar 

  4. Airey, AC, Spiller, A, “Method of Protecting Pigments with Transparent Crystalline Zircon.” US Patent, 4482, 390, 1984

  5. Chen, GH, Zhu, ZF, Liu, H, Wu, YF, Zhu, CK, “Preparation of SiO2 Coated Ce2S3 Red Pigment with Improved Thermal Stability.” J. Rare Earths, 31 891 (2013)

    Article  Google Scholar 

  6. Deng, RP, Song, SY, Pang, R, Li, CY, Zhang, HJ, “Research Progress of Rare Earth Sulfides.” Sci. Sinica. Chim., 42 1337 (2012)

    Article  CAS  Google Scholar 

  7. Trombe, JC, Verelst, M, “Stabilization of the γ-Ce2S3 Phase.” J. Alloys Compd., 323 66 (2001)

    Article  Google Scholar 

  8. Roméro, S, Mosset, A, Trombe, JC, Macaudière, P, “Low-Temperature Process of the Cubic Lanthanide Sesquisul-Fides: Remarkable Stabilization of the γ-Ce2S3 Phase.” J. Mater. Chem., 7 1541 (1997)

    Article  Google Scholar 

  9. Zachariasen, WH, “Crystal Chemical Studies of the 5f-Series of Elements X. Sulfides and Oxysulfides.” Acta Cryst., 2 291 (2007)

    Article  Google Scholar 

  10. Perrin, MA, Wimmer, E, “Color of Pure and Alkali-Doped Cerium Sulfide: A Local-Density-Functional Study.” Phys. Rev. B, 54 2428 (1996)

    Article  CAS  ADS  Google Scholar 

  11. Mauricot, R, Gressier, P, Evain, M, Brec, R, “Comparative Study of Some Rare Earth Sulfides: Doped γ-[A]M2S3 (M = La, Ce and Nd, A = Na, K and Ca) and Undoped γ-M2S3 (M = La, Ce and Nd).” J. Alloys Compd., 223 130 (1995)

    Article  CAS  Google Scholar 

  12. Forster, CM, White, WB, “Optical Absorption Edge in Rare Earth Sesquisulfides.” Mater. Res. Bull., 41 448 (2005)

    Article  Google Scholar 

  13. Li, X, Li, YM, Song, FS, Wang, ZM, Yan, H, Li, ZK, “Study of K+ Doping on Structure and Properties of γ-Ce2S3.” J. Rare Earths, 38 776 (2020)

    Article  CAS  Google Scholar 

  14. Lin, HD, Li, K, Li, YM, Song, FS, Sun, Y, Wan, DT, “Preparation and Color Tuning of Ba2+-Sr2+ Co-doped γ-Ce2S3 Pigments.” Solid State Sci., 136 107098 (2023)

    Article  CAS  Google Scholar 

  15. Luo, XX, Zhang, M, Ma, LB, Yong, P, “Preparation and Stabilization of γ-La2S3 at Low Temperature.” J. Rare Earths, 29 313 (2011)

    Article  CAS  Google Scholar 

  16. Marrot, F, Mosset, A, Trombe, JC, Macaudiere, P, Maestro, P, “The Stabilization of γ-Ce2S3 at Low Temperature by Heavy Rare Earths.” J. Alloys Compd., 259 145 (1997)

    Article  CAS  Google Scholar 

  17. Guo, JM, Ye, MQ, Han, AJ, Liao, J, Chen, CL, “Studies on the Preparation and Characterization of Composite La-Doped γ-Ce2S3 Mica Cool Pigments.” Appl. Phys. A, 126 17 (2020)

    Article  Google Scholar 

  18. Indrawirawan, S, Sun, HQ, Duan, XG, Wang, SB, “Low Temperature Combustion Synthesis of Nitrogen-Doped Graphene for Metal-Free Catalytic Oxidation.” J. Mater. Chem. A, 3 3432 (2014)

    Article  Google Scholar 

  19. Kashinath, CP, Singanahally, TA, Sambandan, E, “Combustion Synthesis.” Curr. Opin. Solid State Mater. Sci., 2 158 (1997)

    Article  Google Scholar 

  20. Andreol, S, Deorsola, FA, Pirone, R, “MnOx-CeO2 Catalysts Synthesized by Solution Combustion Synthesis for the Low-Temperature NH3-SCR.” Catal. Today, 253 199 (2015)

    Article  Google Scholar 

  21. Barbato, PS, Colussi, S, Benedetto, AD, Landi, G, Lisi, L, Llorca, J, Trovarelli, A, “Origin of High Activity and Selectivity of CuO/CeO2 Catalysts Prepared by Solution Combustion Synthesis in CO-PROX Reaction.” J. Phys. Chem. C, 120 13039 (2016)

    Article  CAS  Google Scholar 

  22. Sun, ZQ, Wang, H, Ren, XG, “Study on the Performance of La-Na-Co-Mn-O Based Perovskite Catalysts for Simultaneous Removal of Diesel Engine Carbon Particles and NOx.” Envron. Prot. Sci., 142 4 (2007)

    Google Scholar 

  23. Li, X, Li, YM, Li, ZK, Wang, ZM, Hong, Y, Song, FS, “Preparation and Properties of Ba2+-Y3+ Co-doped γ-Ce2S3 Red Pigment.” Ceram. Mater., 71 378 (2019)

    CAS  Google Scholar 

  24. Sotelo, P, Orr, M, Galante, MT, Hossain, MK, Firouzan, F, Vali, A, Li, J, Subramanian, M, Longo, C, Rajeshwar, K, Macaluso, RT, “Ternary Rare Earth Sulfide CaCe2S4: Synthesis and Characterization of Stability, Structure, and Photoelectrochemical Properties in Aqueous Media.” J. Solid State Chem., 262 149 (2018)

    Article  CAS  ADS  Google Scholar 

  25. Zhang, DJ, Kawada, T, Yoshioka, F, Machida, M, “Oxygen Gateway Effect of CeO2/La2O2SO4 Composite Oxygen Storage Materials.” ACS Omega, 1 789 (2016)

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  26. Shen, WH, Naito, S, “Easy Precipitation Method for Preparation of Cerium Added La2O2SO4 Used for Oxygen Storage.” Adv. Mater. Res., 2986 196 (2014)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Project supported by National Natural Science Foundation of China (51462010), Natural Science Foundation of Jiangxi, China (Nos. 20212BAB203024, 20202BABL204015, 20171ACB20022), and the “JBGS” Foundation of Inner Mongolia Autonomous Region Science and Technology Department (No. 2022JBGS0001).

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Jingdezhen Ceramic University; China National Light Industry Key Laboratory of Functional Ceramic Materials, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, Jingdezhen, 333403, People’s Republic of China

    Boyuan Wu, Yueming Li, Fusheng Song, Kai Li, Yi Sun & Zhumei Wang

Authors
  1. Boyuan Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yueming Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fusheng Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kai Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yi Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Zhumei Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

BW contributed to conceptualization, methodology, and writing–original draft. YL contributed to supervision, resources, and data curation. FS contributed to writing–review and editing. KL contributed to visualization. YS contributed to investigation. ZW contributed to methodology and investigation. All authors read and approved the manuscript.

Corresponding author

Correspondence to Yueming Li.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wu, B., Li, Y., Song, F. et al. Study on synthesis and properties of Na+–La3+ co-doped γ-Ce2S3 pigment by low-temperature self-propagating combustion method. J Coat Technol Res (2024). https://doi.org/10.1007/s11998-023-00904-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11998-023-00904-1

Keywords

Search

Navigation