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Synthesis of four-component acrylic-modified water-reducible alkyd resin: investigation of dilution ratio effect on film properties and thermal behaviors

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Abstract

This study investigated the effect of the dilution ratio on film properties of acrylic-modified water-reducible alkyd resins. First, new four-component acrylic-modified alkyd resins based on 1,3-propanediol containing 40% of the equivalent amount of acrylic copolymer to alkyd resin were synthesized using the fatty acid method. The synthesized acrylic-modified alkyd resin was then dissolved in isopropyl alcohol (IPA) at various ratios and further diluted using distilled water at various ratios to obtain by-weight percentages of 70/50, 70/60, and 80/60 of solid content to IPA and water, respectively. Films of the modified alkyd resins were prepared, and cured at 150°C for 1 h, then their physical and chemical surface coating properties and thermal behaviors were investigated. The best results were obtained for the by-weight percentages of 80/60.

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Acknowledgments

This work is supported by TUBITAK (The Scientific and Technological Research Council of Turkey) with Project Number 214M660. The authors wish to thank Assoc. Prof. M. A. Faruk Öksüzömer and Res. Assist. Vedat Sarıboğa from Istanbul University, Chemical Engineering Department for thermogravimetric analysis.

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  1. Chemical Engineering Department, Engineering Faculty, Istanbul University, Avcilar Campus, Avcilar, 34320, Istanbul, Turkey

    Özge Naz Büyükyonga, Nagihan Akgün, Işıl Acar & Gamze Güçlü

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  1. Özge Naz Büyükyonga
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  2. Nagihan Akgün
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  3. Işıl Acar
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  4. Gamze Güçlü
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Correspondence to Işıl Acar.

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Büyükyonga, Ö.N., Akgün, N., Acar, I. et al. Synthesis of four-component acrylic-modified water-reducible alkyd resin: investigation of dilution ratio effect on film properties and thermal behaviors. J Coat Technol Res 14, 117–128 (2017). https://doi.org/10.1007/s11998-016-9835-z

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