Abstract
Remelted NiCrBSi coatings were examined using optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, x-ray diffraction analysis, microhardness and wear testing. After wear tests, the surfaces of the worn samples were examined by 3D profilometry and scanning electron microscopy to investigate the effects of load and temperature on the coefficient of friction and wear resistance. In all the wear experiments, there was a momentary increase in the wear volume and a momentary decrease in the average coefficient of friction values at the elevated test temperatures. This behavior was caused by the stable oxide layer formed on the surface as a consequence of the elevated test temperature. Three dominant wear mechanisms were observed with the NiCrBSi coatings: delamination at room temperature, spalling and adhesion at 250°C, and oxidation at 450°C, whereas in the uncoated samples there was delamination at room temperature, and micro-cracking and oxidation, both at 250°C and 450°C. Remelted NiCrBSi coatings provided better wear resistance and lower coefficient of friction than uncoated STKM-13A steel, especially at higher temperatures.
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References
W.L. Roberts, Hot rolling of steel (New York: Marcel Dekker, 1983), pp. 1–3.
R. Colás, J. Ramírez, I. Sandoval, J.C. Morales, and L.A. Leduc, Wear (1999). https://doi.org/10.1016/S0043-1648(99)00081-2.
C. Ould, X. Badiche, P. Montmitonnet, and Y. Gachon, Wear (2013). https://doi.org/10.1016/j.wear.2013.07.007.
J.D.B. De Mello, J.L. Gonçalves, and H.L. Costa, Wear (2013). https://doi.org/10.1016/j.wear.2013.02.006.
C. Ould, Y. Gachon, P. Montmitonnet, and X. Badiche, in 14th International Conference on Material Forming Esaform, Proceedings, Book Series: AIP Conference Proceedings, (2011). https://doi.org/10.1063/1.3589768.
A. Günen, E. Kanca, M.S. Karakaş, V. Koç, M.S. Gök, A. Çürük, and M. Demir, Application of different coating methods to external cooling roller and characterization of applied coatings. in 3rd Iron and Steel Symposium (UDCS’17), (2017), ISBN 978-605-9554-0-60.
V. Mayor, Applying traction coating to steel mill rolls, thermal spray: practical solutions for engineering problems. in 9th National Thermal Spray Conference & Exposition, (1996) pp. 61–64.
C. Ould, X. Badiche, P. Montmitonnet, and Y. Gachon, J. Manuf. Process. (2013). https://doi.org/10.1016/j.jmapro.2012.09.011.
A. Ray, K.S. Arora, S. Lester, and M. Shome, J. Mater. Process. Technol. (2014). https://doi.org/10.1016/j.jmatprotec.2014.02.027.
G. Walmag and G. Esser, Work roll manufactured by laser cladding and method therefor, Patent, PCT/EP2015/073189, WO2016055545 A1 (2016).
S. Abraham, J.T. Ok, and K.H. Kim, J. Mater. Process. Technol. (2007). https://doi.org/10.1016/j.jmatprotec.2006.11.091.
H. Liang, F. Ma, X. Wang, T. Zhang, H. Zhu, X. Wu, and H. Zhang, Surf. Coat. Technol. (2000). https://doi.org/10.1016/S0257-8972(00)00625-3.
S. Matthews and B. James, J. Therm. Spray Technol. (2010). https://doi.org/10.1007/s11666-010-9518-8.
R. González, M.A. García, I. Peñuelas, M. Cadenas, M.D.R. Fernández, A.H. Battez, and D. Felgueroso, Wear (2007). https://doi.org/10.1016/j.wear.2007.01.094.
X.C. Zhang, B.S. Xu, S.T. Tu, F.Z. Xuan, Y.K. Zhang, H.D. Wang, and Y.X. Wu, Fatigue Fract. Eng. Mater. (2009). https://doi.org/10.1111/j.1460-2695.2008.01305.x.
J.R. Davis, Handbook of Thermal Spray Technology (Materials Park, OH: ASM International, 2004), pp. 41–82.
R.C. Tucker, eds., Thermal Spray Technology, Vol. 5A (Materials Park: ASM Handbook, 2013), pp. 75–125.
T. Gómez-del Río, M.A. Garrido, J.E. Fernández, M. Cadenas, and J. Rodríguez, J. Mater. Process. Technol. (2008). https://doi.org/10.1016/j.jmatprotec.2007.11.042.
M.A. Garrido, A. Rico, M.T. Gómez, M. Cadenas, J.E. Fernández-Rico, and J. Rodríguez, J. Therm. Spray Technol. (2017). https://doi.org/10.1007/s11666-016-0521-6.
B. Liang, Z. Zhang, and H. Guo, Trans. Indian Inst. Met. (2017). https://doi.org/10.1007/s12666-016-1014-5.
J. Rodríguez, A. Martín, R. Fernández, and J.E. Fernández, Wear (2003). https://doi.org/10.1016/S0043-1648(03)00162-5.
R. González, M. Cadenas, R. Fernández, J.L. Cortizo, and E. Rodríguez, Wear (2007). https://doi.org/10.1016/j.wear.2006.05.009.
Š. Houdková, E. Smazalová, M. Vostřák, and J. Schubert, Surf. Coat. Technol. (2014). https://doi.org/10.1016/j.surfcoat.2014.05.009.
J.M. Miguel, J.M. Guilemany, and S. Vizcaino, Tribol. Int. (2003). https://doi.org/10.1016/S0301-679X(02)00144-5.
Z. Bergant and J. Grum, J. Therm. Spray Technol. (2009). https://doi.org/10.1007/s11666-009-9304-7.
M.R. Karimi, H.R. Salimijazi, and M.A. Golozar, Surf. Eng. (2016). https://doi.org/10.1179/1743294415Y.0000000107.
K. Simunovic, L. Slokar, and S. Havrlisan, Philos. Mag. (2017). https://doi.org/10.1080/14786435.2016.1257167.
E.E. Kornienko, A.A. Nikulina, N.S. Belousova, D.V. Lazurenko, A.S. Ivashutenko, and V.I. Kuz’min, in IOP Conference Series: Materials Science and Engineering (2016). https://doi.org/10.1088/1757-899X/156/1/012020.
D. Chaliampalias, G. Vourlias, E. Pavlidou, S. Skolianos, K. Chrissafis, and G. Stergioudis, Appl. Surf. Sci. (2009). https://doi.org/10.1016/j.apsusc.2008.10.006.
A. Martín, J. Rodríguez, J.E. Fernández, and R. Vijande, Wear (2001). https://doi.org/10.1016/S0043-1648(01)00703-7.
K. Dejun and Z. Benguo, Surf. Rev. Lett. (2017). https://doi.org/10.1142/S0218625X17500573.
C. Guo, J. Zhou, J. Chen, J. Zhao, Y. Yu, and H. Zhou, Wear (2011). https://doi.org/10.1016/j.wear.2011.01.003.
A. Günen, E. Kanca, M.S. Karakaş, V. Koç, M.S. Gök, Y. Kanca, A. Çürük, and M. Demir, Surf Coat. Technol. (2018). https://doi.org/10.1016/j.surfcoat.2018.04.071.
A. Günen, B. Kurt, P. Milner, and M.S. Gök, Int. J. Refract. Met. Hard (2019). https://doi.org/10.1016/j.ijrmhm.2019.03.019.
J.R. Jiang, F.H. Stott, and M.M. Stack, Wear (1995). https://doi.org/10.1016/0043-1648(95)90004-7.
P.W. Stott, A.C. Williams, and B.W. Barry, J. Control. Release (1998). https://doi.org/10.1016/S0168-3659(97)00153-3.
L.C. Betancourt-Dougherty and R.W. Smith, Wear (1998). https://doi.org/10.1016/S0043-1648(97)00212-3.
R. Tyagi, D. Xionga, and J. Li, Wear (2011). https://doi.org/10.1016/j.wear.2010.08.013.
J.F. Archard, J. Appl. Phys. (1953). https://doi.org/10.1063/1.1721448.
M. Woydt and K.H. Habig, Tribol. Int. (1989). https://doi.org/10.1016/0301-679X(89)90168-0.
H. Engqvist, H. Högberg, G.A. Botton, S. Ederyd, and N. Axén, Wear (2000). https://doi.org/10.1016/S0043-1648(00)00315-X.
N.P. Suh, Wear (1973). https://doi.org/10.1016/0043-1648(73)90125-7.
K. Kato, Tribol. Int. (1997). https://doi.org/10.1016/S0301-679X(96)00063-1.
H.A. Sodano, J.M. Lloyd, and D.J. Inman, Adv Mater Res-Switz. (2006). https://doi.org/10.1088/0964-1726/15/5/007.
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The authors wish to thank Turgut Halamoğlu for the sharing his knowledge on flame spray coating and externally cooled rolls.
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Günen, A., Çürük, A. Properties and High-Temperature Wear Behavior of Remelted NiCrBSi Coatings. JOM 72, 673–683 (2020). https://doi.org/10.1007/s11837-019-03950-6
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DOI: https://doi.org/10.1007/s11837-019-03950-6