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Preparation of pectin-based dual-crosslinked network as a binder for high performance Si/C anode for LIBs

  • Materials (Organic, Inorganic, Electronic, Thin Films)
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Abstract

The modification of pectin polysaccharide through grafting with polyacrylamide and crosslinking is newly proposed as a powerful candidate for a water-soluble binder of high-capacity Si anodes in lithium ion batteries. The grafting of pectin with polyacrylamide enhances adhesion in the electrode and contributes to the good wettability of the carbonate electrolyte. Herein, dual-crosslinking of pectin-g-polyacrylamide was achieved by the ionic crosslinking of pectin with divalent calcium ions and the chemical crosslinking of polyacrylamide with a bisacrylamide. As a result, the dual-crosslinked binder improves further the cycling performance of the Si/C composite anode with a 1.2 mg cm−2 loading, which retains a specific capacity of 729 mAh g−1 after 300 cycles. In contrast, the Si/C electrode containing dual-crosslinked alginate with polyacrylamide shows a specific capacity of 515 mAh g−1 after 300 cycles.

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Acknowledgements

The study was supported by the 2018 research fund of the University of Ulsan.

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Authors and Affiliations

  1. School of Chemical Engineering, University of Ulsan, 93 Daehak-ro, Nam-gu, Ulsan, 44610, Korea

    Bolormaa Gendensuren, Chengxiang He & Eun-Suok Oh

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  1. Bolormaa Gendensuren
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  2. Chengxiang He
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  3. Eun-Suok Oh
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Correspondence to Eun-Suok Oh.

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Gendensuren, B., He, C. & Oh, ES. Preparation of pectin-based dual-crosslinked network as a binder for high performance Si/C anode for LIBs. Korean J. Chem. Eng. 37, 366–373 (2020). https://doi.org/10.1007/s11814-019-0438-0

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