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Breakthrough analysis of carbon dioxide adsorption on zeolite synthesized from fly ash

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Abstract

Zeolite (FAZ) was synthesized by the fusion method using coal fly ash to adsorb carbon dioxide. The experimental adsorption was operated batchwise in a laboratory-scale packed-bed adsorber to obtain the breakthrough curves of CO2 under conditions such as adsorption temperatures (20–80 °C), flow rates of gaseous mixture of carbon dioxide and nitrogen (40–100 cm3/min), and concentration of CO2 (3000–10000 ppmv) at atmospheric pressure of 101.3 kPa. The influence of the experimental conditions, such as the gas flow rate, concentration of CO2 and adsorption temperature on adsorption behavior, was discussed. The deactivation model, combined the adsorption with the deactivation of adsorbent, was used to analyze the physicochemical properties, such as the adsorption kinetics, capacity and heat of adsorption, by fitting the experimental data of the breakthrough curves to this model. The adsorptive activity and capacity of FAZ were as almost same as those of the commercial zeolite of Wako 4A.

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Authors and Affiliations

  1. Department of Environmental Administration, Catholic University of Pusan, Busan, 609-757, Korea

    Chang-Han Lee & Seong-Soo Kim

  2. School of Chemical and Biomolecular Engineering, Pusan National University, Busan, 609-735, Korea

    Sang-Wook Park

Authors
  1. Chang-Han Lee
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  2. Sang-Wook Park
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  3. Seong-Soo Kim
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Correspondence to Seong-Soo Kim.

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Lee, CH., Park, SW. & Kim, SS. Breakthrough analysis of carbon dioxide adsorption on zeolite synthesized from fly ash. Korean J. Chem. Eng. 31, 179–187 (2014). https://doi.org/10.1007/s11814-013-0281-7

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  • DOI: https://doi.org/10.1007/s11814-013-0281-7

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