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Preparation of Clay/Biochar Composite Adsorption Particle and Performance for Ammonia Nitrogen Removal from Aqueous Solution

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Abstract

This study aimed to present a novel clay/biochar composite adsorption particle, which made from abandoned reed straw and clay to remove ammonia nitrogen (NH4+-N) from micro-contaminated water. The removal performance of NH4+-N by composite adsorption particle was monitored under different raw material proportions and initial NH4+-N concentration. Besides, adsorption kinetics and adsorption isotherms were investigated to reveal the adsorption mechanisms. The results showed that NH4+-N was effectively removed under optimal proportion of biochar, foaming agent and crosslinker with 20%, 3%, and 3%, respectively. The optimal contact time was 150 min and the best removal efficiency was 88.6% at initial NH4+-N concentration of 20 mg L−1. The adsorption performance was well described by the second order kinetic model and Freundlich model. The novel clay/biochar composite adsorption particle in this study demonstrated a high potential for NH4+-N removal from surface water.

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Acknowledgements

This work was supported by the National Major Project of Water Pollution Control and Management Technology in China (No. 2013ZX07202-007), the Shenzhen Science and Technology Project (No. GRCK2017042116092660), and the National Natural Science Foundation of China (No. 51308066).

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Authors and Affiliations

  1. College of Environmental Science and Engineering, Ocean University of China, Qingdao, 266100, China

    Xiao Huang, Jie Bai, Yangguo Zhao, Weijun Tian & Chunhui Hu

  2. College of Marine Life Science, Ocean University of China, Qingdao, 266003, China

    Kuiran Li

  3. Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing, 210044, China

    Xiao Huang

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  1. Xiao Huang
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  2. Jie Bai
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  3. Kuiran Li
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  5. Weijun Tian
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  6. Chunhui Hu
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Correspondence to Kuiran Li.

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Huang, X., Bai, J., Li, K. et al. Preparation of Clay/Biochar Composite Adsorption Particle and Performance for Ammonia Nitrogen Removal from Aqueous Solution. J. Ocean Univ. China 19, 729–739 (2020). https://doi.org/10.1007/s11802-020-4150-9

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  • DOI: https://doi.org/10.1007/s11802-020-4150-9

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