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Sorption and desorption characteristics of cadmium by four different soils in northeast China

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Abstract

Four soils, phaeozem (PM), saline-alkali soil (SA), meadow albic bleached soil (MA) and dark brown forest soil (DB) from Northeast China were used to examine the sorption and desorption characteristics of Cd and pH influence on it. According to sorption experiment without pH control, the order of amount of absorbed Cd by soils was: SA>PM>DB>MA. The results from non-linear fitting method showed that Langmuir and Freundrich models were more adaptable than Temkin model in describing the sorption data. The maximum sorption amounts from Langmuir model were: PM>SA>MA>DB. Exponential equation for PM and SA and quadratic equation for MA and DB were suitable to fit the desorption data. The order of average desorption percentage was: MA>DB>PM>SA. The amounts of sorption by PM, DB and MA reached the maximum in pH 9.0, while sorption by SA was linearly increased in the experimental range of pH 3.3–11.4. In uniform pH, however, Cd sorption by SA was the minimum among four soils, which indicated that the more amounts of Cd absorbed by SA in isotherm sorption were ascribed to the higher soil pH. The higher sorption of Cd in PM resulted from the higher percentage of organic matter and clay components.

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References

  • ABOLLINO O, ACETO M, MALANDRINO M, 2003. Adsorption of heavy metals on Na-montmorillonite, effect of pH and organic substances [J]. Water Research, 37(7): 1619–1627.

    Article  Google Scholar 

  • ALTIN O, OZBELGE O H, DOGU T, 1999. Effect of pH, flow rate and concentration on the sorption of Pb and Cd on montmorillonite I. Experimental [J]. Journal of Chemical Technology and Biotechnology, 74(12): 1131–1138.

    Article  Google Scholar 

  • ANDERSON P R, CHRISTENSEN T H, 1988. Distribution coefficients of Cd, Co, Ni and Zn in soils [J]. Journal of Soil Science, 39: 15–22.

    Article  Google Scholar 

  • AUTIER V, WHITE D, 2004. Examination of cadmium sorption characteristics for a boreal soil near Fairbanks, Alaska [J]. Journal of Hazard Materials, 106(2–3): 149–155.

    Article  Google Scholar 

  • CHEN Huai-man, 1988. Adsorption and desorption of cadmium in soils. I. the influence of soil components on Cd adsorption and desorption [J]. Acta Pedologica Sinica, 25(1): 66–74. (in Chinese)

    Google Scholar 

  • CHRISTENSEN T H, 1989. Cadmium soil sorption at low concentrations: VII. Correlation with soil parameters [J]. Water Air Soil Pollution, 44: 71–82.

    Article  Google Scholar 

  • CHU Zhao-sheng, LIU Wen-xin, TANG Hong-xiao, 2003. The sorption of isotherms of neodymium (III) and cerium (III) on loess at different pH values [J]. Acta Scientiae Circumstantiae, 23(2): 211–215. (in Chinese)

    Google Scholar 

  • GUO Guan-lin, ZHOU Qi-xing, 2004. Contaminative trends of heavy metals in phaiozem of Northeast China [J]. Journal of the Graduate School of the Chinese Academy of Sciences, 21(3): 386–392. (in Chinese)

    Google Scholar 

  • GUO Ping, XIE Zhong-lei, LI Jun et al., 2005. Relationships between fractionations of Pb, Cd, Cu, Zn and Ni and soil properties in urban soils of Changchun, China [J]. Chinese Geographical Science, 15(2): 179–185.

    Article  Google Scholar 

  • HOLM P E, ANDERSEN B B H, CHRISTENSEN T H, 1996. Cadmium solubility in aerobic soils [J]. Soil Science Society of America Journal, 60: 775–780.

    Article  Google Scholar 

  • KOOPAL W C, RIEMSDIJK VAN W, KINNIBURGH D, 2001. Humic matter and contaminants. General aspects and modeling metal ion binding [J]. Pure and Applied Chemistry, 73(12): 2005–2016.

    Article  Google Scholar 

  • LIN Yu-suo, XUE Jia-hua, 1991. Using of Freundlich equation for studying mechanism and movement of Zn added in calcareous soil [J]. Acta Pedologica Sinica, 28(4): 390–395. (in Chinese)

    Google Scholar 

  • LU Ru-kun, 1999. Analysis Methods for Soils and Agricultural Chemistry [M]. Beijing: China Agricultural Science and Technology Press.

    Google Scholar 

  • NAIDU R, KOOKANA R S, SUMNER M E, 1997. Cadmium sorption and transport in variable charge soils: a review [J]. Journal of Environmental Quality, 26: 602–617.

    Article  Google Scholar 

  • SATARUG S, BAKER J R, URBENJAPOL S, 2003. A global perspective on cadmium pollution and toxicity in non-occupationally exposed population [J]. Toxicology Letters, 137(1–2): 65–83.

    Article  Google Scholar 

  • SAUVÉ W, HENDERSHOT W, ALLEN H E, 2000. Solid-solution partitioning of metals in contaminated soils: dependence on pH, total metal burden and organic matter [J]. Critical Reviews in Environmental Science and Technology, 34(7): 1125–1131.

    Article  Google Scholar 

  • WANG Hong, ZHOU Wei, LIN Bao, 2001. Effect of calcium carbonate on adsorption and desorption of cadmium in soils [J]. Acta Ecologica Sinica, 21(6): 932–937. (in Chinese)

    Google Scholar 

  • WEBER J H, 1988. Binding and transport of metals by humic materials [A]. In: FRIMMEL F H, CHRISTMAN R F (eds.). Humic Substances and Their Role in the Environment [C]. New York: John Wiley and Sons Inc. 165–178.

    Google Scholar 

  • WU Mei-ling, 1985. Specific adsorption of heavy metal ions on soil mineral colloid surface with variable electric charge [J]. Chinese Journal of Soil Science, 16(2): 89–94; 16(3): 138–141. (in Chinese)

    Google Scholar 

  • YU Jun-bao, LIU Jing-shuang, WANG Jin-da et al., 2002. Spatial-temporal variation of heavy metal elements content in covering soil of reclamation area in Fushun Coal Mine [J]. Chinese Geographical Science, 12(3): 268–272.

    Article  Google Scholar 

  • ZHANG De-jian, WEI Xian-xun, ZENG Guang-ming, 2004. The sorption isotherms of lead ion by sludge ramification adsorbent on the basis of non-linear fit [J]. Ion Exchange and Adsorption, 20(1): 1–6. (in Chinese)

    Google Scholar 

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Foundation item: Under the auspices of the Key Project of Knowledge Innovation Program of Chinese Academy of Sciences (No. KZCX1-SW-19)

Biography: ZHANG Lei (1978-), male, a native of Laiwu of Shandong Province, Ph.D. candidate, specialized in soil contamination and prevention. E-mail: zhanglei@neigae.ac.cn

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Zhang, L., Song, Fb. Sorption and desorption characteristics of cadmium by four different soils in northeast China. Chin. Geograph.Sc. 15, 343–347 (2005). https://doi.org/10.1007/s11769-005-0023-9

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  • DOI: https://doi.org/10.1007/s11769-005-0023-9

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