Abstract
A cubic Prussian blue (PB) with the hollow interior was successfully synthesized by direct dissociation followed by a controlled self-etching process. The etching process also made hollow Prussian blue (HPB) a porous structure. SEM, TEM and XRD were employed to confirm the structure and morphology of the prepared materials. Then HPB and chitosan (CS) were deposited on a glassy carbon electrode (GCE), used to determine H2O2. The amperometric performance of HPB/CS/GCE was investigated. It was found that the special structure of HPB exhibits enhanced performance in the H2O2 sensing.
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Luo X L, Xu J J, Zhao W, et al. A novel glucose ENFET based on the special reactivity of MnO2 nanoparticles. Biosensors & Bioelectronics, 2004, 19(10): 1295–1300
Cui X, Liu G, Lin Y. Biosensors based on carbon nanotubes/nickel hexacyanoferrate/glucose oxidase nanocomposites. Journal of Biomedical Nanotechnology, 2005, 1(3): 320–327
Lian W P, Wang L, Song Y H, et al. A hydrogen peroxide sensor based on electrochemically roughened silver electrodes. Electrochimica Acta, 2009, 54(18): 4334–4339
Wang Q M, Niu H L, Mao C J, et al. Facile synthesis of trilaminar core–shell Ag@C@Ag nanospheres and their application for H2O2 detection. Electrochimica Acta, 2014, 127: 349–354
Shu X, Chen Y, Yuan H, et al. H2O2 sensor based on the roomtemperature phosphorescence of nano TiO2/SiO2 composite. Analytical Chemistry, 2007, 79(10): 3695–3702
Krishnan V, Xidis A L, Neff V D. Prussian blue solid-state films and membranes as potassium ion-selective electrodes. Analytica Chimica Acta, 1990, 239: 7–12
Kulesza P J, Miecznikowski K, Malik M A, et al. Electrochemical preparation and characterization of hybrid films composed of Prussian blue type metal hexacyanoferrate and conducting polymer. Electrochimica Acta, 2001, 46(26–27): 4065–4073
Itaya K, Shoji N, Uchida I. Catalysis of the reduction of molecular oxygen to water at prussian blue modified electrodes. Journal of the American Chemical Society, 1984, 106(12): 3423–3429
Chen W, Cai S, Ren Q Q, et al. Recent advances in electrochemical sensing for hydrogen peroxide: a review. Analyst, 2012, 137(1): 49–58
Pandey P C, Pandey A K, Chauhan D S. Nanocomposite of Prussian blue based sensor for l-cysteine: Synergetic effect of nanostructured gold and palladium on electrocatalysis. Electrochimica Acta, 2012, 74: 23–31
Karyakin A A, Puganova E A, Budashov I A, et al. Prussian blue based nanoelectrode arrays for H2O2 detection. Analytical Chemistry, 2004, 76(2): 474–478
O’Halloran M P, Pravda M, Guilbault G G. Prussian Blue bulk modified screen-printed electrodes for H2O2 detection and for biosensors. Talanta, 2001, 55(3): 605–611
Zhu X, Niu X, Zhao H, et al. Doping ionic liquid into Prussian blue-multiwalled carbon nanotubes modified screen-printed electrode to enhance the nonenzymatic H2O2 sensing performance. Sensors and Actuators B: Chemical, 2014, 195(5): 274–280
Karyakin A A, Gitelmacher V O, Karyakina E E. A high-sensitive glucose amperometric biosensor based on Prussian blue modified electrodes. Analytical Letters, 1994, 27(15): 2861–2869
Jin E, Lu X, Cui L, et al. Fabrication of graphene/prussian blue composite nanosheets and their electrocatalytic reduction of H2O2. Electrochimica Acta, 2010, 55(24): 7230–7234
Zhang W, Wang L, Zhang N, et al. Functionalization of singlewalled carbon nanotubes with cubic prussian blue and its application for amperometric sensing. Electroanalysis, 2009, 21(21): 2325–2330
Ameloot R, Vermoortele F, Vanhove W, et al. Interfacial synthesis of hollow metal-organic framework capsules demonstrating selective permeability. Nature Chemistry, 2011, 3(5): 382–387
Liang G, Xu J, Wang X. Synthesis and characterization of organometallic coordination polymer nanoshells of Prussian blue using miniemulsion periphery polymerization (MEPP). Journal of the American Chemical Society, 2009, 131(15): 5378–5379
Wei C, Cheng C, Zhao J, et al. NiS hollow spheres for highperformance supercapacitors and non-enzymatic glucose sensors. Chemistry — An Asian Journal, 2015, 10(3): 679–686
Meek S T, Greathouse J A, Allendorf M D. Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials. Advanced Materials, 2011, 23(2): 249–267
Yang J, Cho M, Lee Y. Synthesis of hierarchical NiCO2O4 hollow nanorods via sacrificial-template accelerate hydrolysis for electrochemical glucose oxidation. Biosensors & Bioelectronics, 2016, 75: 15–22
Chen D L, Cao Y, Chen Y, et al. Rapid synthesis of hollow Ni(OH)2 with low-crystallinity for the electrochemical detection of ascorbic acid with high sensitivity. RSC Advances, 2016, 6(49): 43598–43604
Yang Y, Du J J, Luo L M, et al. Facile aqueous-phase synthesis and electrochemical properties of novel PtPd hollow nanocatalysts. Electrochimica Acta, 2016, 212: 966–972
Zhang L, Wu H B, Lou X W. Metal-organic-frameworks-derived general formation of hollow structures with high complexity. Journal of the American Chemical Society, 2013, 135(29): 10664–10672
Tang X, Liu Y, Hou H, et al. Electrochemical determination of LTryptophan, L-Tyrosine and L-Cysteine using electrospun carbon nanofibers modified electrode. Talanta, 2010, 80(5): 2182–2186
Zhang J, Li J, Yang F, et al. Preparation of Prussian blue@Pt nanoparticles/carbon nanotubes composite material for efficient determination of H2O2. Sensors and Actuators B: Chemical, 2009, 143(1): 373–380
Wang Y T, Yu L, Zhu Z Q, et al. Improved enzyme immobilization for enhanced bioelectrocatalytic activity of glucose sensor. Sensors and Actuators B: Chemical, 2009, 136(2): 332–337
Shen Q, Jiang J, Fan M, et al. Prussian blue hollow nanostructures: Sacrificial template synthesis and application in hydrogen peroxide sensing. Journal of Electroanalytical Chemistry, 2014, 712(2): 132–138
Keihan A H, Sajjadi S. Improvement of the electrochemical and electrocatalytic behavior of Prussian blue/carbon nanotubes composite via ionic liquid treatment. Electrochimica Acta, 2013, 113: 803–809
Wang L, Ye Y, Zhu H, et al. Controllable growth of Prussian blue nanostructures on carboxylic group-functionalized carbon nanofibers and its application for glucose biosensing. Nanotechnology, 2012, 23(45): 455502
Li Y, Zheng J B, Sheng Q L, et al. Synthesis of Ag@AgCl nanoboxes, and their application to electrochemical sensing of hydrogen peroxide at very low potential. Microchimica Acta, 2015, 182(1–2): 61–68
Wang J P, Gao H, Sun F L, et al. Nanoporous PtAu alloy as an electrochemical sensor for glucose and hydrogen peroxide. Sensors and Actuators B: Chemical, 2014, 191(2): 612–618
Zhang B, Zhang X, Huang D, et al. Co9S8 hollow spheres for enhanced electrochemical detection of hydrogen peroxide. Talanta, 2015, 141: 73–79
Liu S, Yu B, Li F, et al. Coaxial electrospinning route to prepare Au-loading SnO2 hollow microtubes for non-enzymatic detection of H2O2. Electrochimica Acta, 2014, 141: 161–166
Nie G D, Lu X F, Lei J Y, et al. Sacrificial template-assisted fabrication of palladium hollow nanocubes and their application in electrochemical detection toward hydrogen peroxide. Electrochimica Acta, 2013, 99: 145–151
Acknowledgements
The authors gratefully acknowledge the financial support of this project by the National Natural Science Foundation of China (Grant No. 21575113), the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20126101110013), the Natural Science Fund of Shaanxi Province in China (Grant No. 2013KJXX-25), and the Scientific Research Foundation of Shaanxi Provincial Key Laboratory (Grant Nos. 15JS100 and 16JS099).
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Sheng, Q., Zhang, D., Shen, Y. et al. Synthesis of hollow Prussian blue cubes as an electrocatalyst for the reduction of hydrogen peroxide. Front. Mater. Sci. 11, 147–154 (2017). https://doi.org/10.1007/s11706-017-0382-z
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DOI: https://doi.org/10.1007/s11706-017-0382-z