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Sustainable vortex assisted liquid phase microextraction based on fatty acid switchable solvent for selective and accurate analysis of manganese in food samples

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Abstract

In this research article, a sustainable fatty acids switchable solvent based vortex assisted liquid phase microextraction (SS-VA-LPME) method coupled with flame atomic absorption spectrometry (FAAS) was developed for the selective and accurate analysis of manganese (Mn) in food samples. Five fatty acid-SS were prepared for the selective extraction of Mn(II) ions. Microextraction conditions of the SS-VA-LPME /FAAS method were systematically optimized to maximize the extraction recovery of Mn. Under optimum conditions, linear range, limit of detection and preconcentration factor were calculated as 1–200, 0.3 ng mL−1 and 150, respectively. Also, the calibration equation of the SS-VA-LPME/FAAS method was A = 0.054 [Mn(II), ng mL−1] + 0.0026 with 0.9986 of correlation coefficient. Validation of the SS-VA-LPME/FAAS was investigated by analysis of three reference materials. The SS-VA-LPME/FAAS method was validated with good inter and intra-day precision (3.9 ≤ %), and quantitative recoveries (92.7–98.6%). The applicability of the SS-VA-LPME/FAAS method was tested by spiking food samples prepared by microwave digestion with Mn(II) solution and the recoveries were from 89 ± 8 to 98 ± 4%.

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Funding

No funding was received for this study.

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Authors and Affiliations

  1. Faculty of Science, Department of Chemistry, Sivas Cumhuriyet University, Sivas, Türkiye

    Adil Elik & Nail Altunay

  2. Nanotechnology Engineering, Sivas Cumhuriyet University, Sivas, Türkiye

    Nevcihan Gürsoy

Authors
  1. Adil Elik
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  2. Nevcihan Gürsoy
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  3. Nail Altunay
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Contributions

Adil Elik involved in supervision, writing—review & editing. Nevcihan Gürsoy involved in sampling, sample preparation. Nail Altunay involved in investigation, validation, writing—original draft.

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Correspondence to Nail Altunay.

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Elik, A., Gürsoy, N. & Altunay, N. Sustainable vortex assisted liquid phase microextraction based on fatty acid switchable solvent for selective and accurate analysis of manganese in food samples. Chem. Pap. 78, 3261–3272 (2024). https://doi.org/10.1007/s11696-024-03310-y

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  • DOI: https://doi.org/10.1007/s11696-024-03310-y

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