Abstract
The thermodynamic properties of the solid and liquid phases and gaseous species in the Se-As system were optimized based on the available experimental data. A polynomial model was used for the liquid phase. A good description of the experimental data was obtained, but further experimental studies are needed to resolve unambiguously certain contradictions among the experimental data.
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Cited References
S. Horiba, Z. Phys. Chem., 106, 295–302 (1923).
S.A. Dembovskii and N.P. Luzhnaya, Russ. J. Inorganic Chem., 9(3), 365–367 (1964).
S.I. Gorbov and A.N. Krestovnikov, Izv. V.U.Z. Tsvetn. Metall., (6),26–35(1966).
O.V. Pelevin, M.G. Mil'vidskii, A.I. Belyaev, and B.A. Khotin, Izv. Akad. Nauk SSSR, Neorg. Mater., 2(5), 942–943 (1966).
A. Vaipolin, Sov. Phys. Crystallogr, 10, 509 (1966).
M.B. Myers and E.J. Felty, Mater. Res. Bull., 2(7), 535–546 (1967).
G.P. Ustyugov, A. V. Vanyukov, A.D. Gerasimov, et al., Elektronnaya Tekhn., 14(8), 111 (1967).
S.I. Gorbov and A.N. Krestovnikov, Russ. J. Inorganic Chem., 75(6), 779–782 (1968).
B.E. Knoxand VS. Ban, Mater. Res. Bull., 3, 885–894 (1968).
U.E. Schnaus, C.T. Moynihan, R.W. Gammon, and P.B. Macedo, Tech. Rep. No. 6, AD 698 842, Vitreous State Lab., Catholic Univ. of America, Washington D.C. (1969).
G.P. Ustyugov, A.A. Kudryavtsev, B.M. Kuadzhe, and E.N. Vigdorovich, Izv. Akad. Nauk SSSR, Neorg. Mater., 5(2), 378–379 (1969).
R. Blachnik and A. Schneider, Z Anorg, Allg. Chem., 372, 314–324 (1970).
M.B. Myers and E.J. Felty, J. Electrochem. Soc., 117(6), 818–820 (1970).
T.J. Bastow, J.D. Campbell, and H.J. Whitfield, Aust. J. Chem., 25, 2291 (1972).
G.G. Gospodinov and A.S. Pashinkin, C.R. Acad. Bulg. Sci., 26(6), 785–786 (1973).
R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, K.K. Kelley, and D.D. Wagman, Thermodynamic Properties of Elements, American Society for Metals, Metals Park, OH (1973).
Yu.G. Poltavtsev, V.P. Zaharov, I.M. Protas, T. V. Remizovich, and V.N. Chugaev, Ukr. Fiz. Zh, 18(5), 752–755 (1973).
G. Gospodinov, A.D. Molodyk, A.S. Pashinkin, and S.S. Strel'chenko, Izv. Akad. Nauk SSSR, Neorg. Mater., 10(6), 1125–1126 (1974).
K.C. Mills, Thermodynamic Data for Inorganic Sulphides, Selenides and Tellurides, Butterworth, London (1974).
Yu.F. Orlov and E.O. Kurchevskaya, J. Appl. Chem. USSR., 47(10), 2255–2257 (1974).
E.H. Baker, J. Chem. Soc. Dalton Trans., 15, 1589–1591 (1975).
H. Rau, J. Chem. Thermodyn., 7, 27–32 (1975).
D.D. Thomburg and R.I. Johnson, J. Non-Cryst. Solids, 17(1), 2–8 (1975).
V.V. Zigel, G.M. Orlova, and G.N. Dyakova, Fiz. Khim. Stekla, 7(6), 558–561 (1975).
J. Ederova, THERMANAL '76, Celostatna Konf. Term. Anal., Proc. 7th, s/15-s/19 (1976).
A. J. Easteal, J. A. Wilder, R.K. Mohr, and C.T. Moynihan, J. Am. Ceram. Soc, 60(3/4), 134–138 (1977).
S.M. Rasulov and R. A. Medzhidov, Russ. J. Phys. Chem., 57(7), 969–970 (1977).
R. Blachnik and A. Hoppe, J. Non-Cryst. Solids, 34, 191–201 (1979).
G.M. Orlova and V.A. Muromtsev, Fiz, Khim. Stekla, 5(3), 361–366 (1979).
R. Blachnik, A. Hoppe, and U. Wickel, Z. Anorg. Allg. Chem., 465, 78–90 (1980).
U. Gaur, H.-C. Shu, A. Mehta, and B. Wunderlich, J. Phys. Chem. Ref. Data, 10(1), 89–117 (1981).
V.A. Muromtsev, M.D. Bal'makov, and G.M. Orlova, Fiz. Khim.Stekla, 7(2), 228–232 (1981).
R. Blachnik and U. Wickel, Thermochim. Acta, 81, 185–196 (1984).
J. Drowart, S. Smoes, A.M.V Auwera-Mahieu, and E. Trio, Prvc. Third Int. Symp. on Industrial Uses of Selenium and Tellurium, 15–17 Oct., Saltsjobaden, Stockholm, Sweden, 323 (1984).
L.V Gurvich et al., IVTAN-THERMO Thermodynamic Database (1986).
A.V Steblevskii, Russ. J. Inorganic Chem., 57(4), 474–476 (1986).
J.C. Rouland, C. Souleau, and R.J. Ceolin, Thermal Anal, 32, 547–558 (1987).
A. V. Steblevskii, Ph.D. thesis, Institute of General and Inorganic Chemistry of the USSR Academy of Sciences, Moscow (1987).
L. V. Gurvich, High Temp. Sci., 26, 197 (1989).
V.G. Neverov, G.A. Rybakova, and V.R. Panus, Izv. Akad. Nauk SSSR, Neorg. Mater, 25(2), 225–227 (1989).
L.A. Niselson, A.A. Gasanov, and A.G. Yaroshevskii, Dokl. Akad. Nauk SSSR, 314(5), 1166–1168 (1990).
P.A.G. O'Hare, B.M. Lewis, S. Susman, and K.J. Volin.J. Chem. Thermodyn., 22, 1191–1206 (1990).
A. Hamou, J.M. Saiter, J. Bayard, J. Grenet, andC. Vautier, Calorim. Anal. Therm., 23, 175–182 (1992).
R.A. Medzhidov, High Temp.—High Press., 24, 363–366 (1992).
L.A. Niselson, A.A. Gasanov, and A.G. Yaroshevskii, Vysokochistye Veshchestva, (4), 56–61 (1993).
C. W. Bale, A.D. Pelton, and W.T. Thompson, F*A*C*T (Facility for the Analysis of Chemical Thermodynamics), Ecole Polytechnique, Montreal (1996).
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Degterov, S.A., Pelton, A.D. & L'Ecuyer, J.D. Thermodynamic optimization of the selenium-arsenic (Se-As) system. JPE 18, 357–368 (1997). https://doi.org/10.1007/s11669-997-0062-2
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DOI: https://doi.org/10.1007/s11669-997-0062-2